无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (6): 70-.

• 论文 • 上一篇    下一篇

氧化镁/γ-氧化铝催化蒽醌法工艺 降解物再生过程研究

赵 珒,袁恩先,王 莅   

  1. 天津大学化工学院绿色合成与转化教育部重点实验室,天津化学化工协同创新中心,天津 300072
  • 出版日期:2015-06-10 发布日期:2015-05-22

Regenerations of degradation products in anthraquinone process of hydrogen peroxide production over MgO/γ-Al2O3 catalysts

Zhao Jin,Yuan Enxian,Wang Li   

  1. Key Laboratory for Green Chemical Technology of Education Ministry,School of Chemical Engineering and Technology,Tianjin Universtiy,Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),Tianjin 300072,China
  • Online:2015-06-10 Published:2015-05-22

摘要: 以γ-氧化铝和六水合硝酸镁为原料,采用等体积浸渍法制备了氧化镁/γ-氧化铝催化剂。X射线衍射(XRD)显示,随着氧化铝含量增加,主要衍射峰位置逐渐向低角度方向偏移,表明在γ-氧化铝载体表面形成了MgAl2O4相。在常压、50 ℃下评价了氧化镁/γ-氧化铝催化剂对蒽醌工作液再生和5,6,7,8-四氢-2-乙基-9, 10-蒽醌(H4EAQ)转化性能。结果表明,氧化镁/γ-氧化铝催化剂对蒽醌工作液中降解物再生和H4EAQ转化效果优于未改性γ-氧化铝,并且随着氧化镁负载量增加蒽醌工作液再生和H4EAQ转化效果增加。当氧化镁负载量达到30%(质量分数)时,氧化镁/γ-氧化铝催化剂对蒽醌降解物再生和H4EAQ转化量较γ-氧化铝分别提高54%和231%。

关键词: 蒽醌法, 过氧化氢, 再生, 蒽醌降解物, 氧化镁/&gamma, -氧化铝

Abstract: MgO/γ-Al2O3 catalysts were prepared by incipient wetness impregnation with γ-Al2O3  and Mg(NO3)2·6H2O as raw materials.XRD results showed that the position of characteristic diffraction peaks shifted to the low-angle direction,indica- ting the formation of MgAl2O4 phase on the surface of the γ-Al2O3  support.The regeneration reaction of degradation products (DP) and the transformation property of 2-ethyl-5,6,7,8-tetrahydro-9,10-anthrahydroquinone(H4EAQ) over MgO/γ- Al2O3  catalysts were carried out at atmospheric pressure and 50 ℃.The MgO/γ-Al2O3  catalysts exhibited the higher catalytic activity than γ-Al2O3 .The amounts of DP regeneration and H4EAQ transformation increased with increasing the MgO loading mass in MgO/Al2O3 catalysts and both they reached the maximum at the MgO mass fraction of 30%,together with the improvement in the DP regeneration and H4EAQ transformation of 54% and 231%,respectively,compared with γ-Al2O3 .

Key words: anthraquinone process;hydrogen peroxide;regeneration;degradation products;MgO/&gamma, -Al2O3