无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (5): 30-.

• 论文 • 上一篇    下一篇

纳米硫酸钡的湿法改性研究

刘玉敏,刘 悦   

  1. 河北科技大学化学与制药工程学院,河北石家庄 050018
  • 出版日期:2015-05-10 发布日期:2015-05-06

Research on wet modification of nano-sized barium sulfate

 LIU  Yu-Min, LIU   Yue   

  1. School of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,China
  • Online:2015-05-10 Published:2015-05-06

摘要: 采用高剪切混合乳化机替代普通搅拌器,湿法反应改性纳米硫酸钡,考察了乳化时间、乳化温度、改性剂用量、纳米硫酸钡悬浮液固含量对改性后纳米硫酸钡活化度的影响。采用红外光谱仪、热重分析仪和扫描电子显微镜对改性后纳米硫酸钡的包覆情况、形貌做了表征。实验结果表明,采用高剪切混合乳化机湿法反应改性纳米硫酸钡,在乳化时间为15 min、乳化温度为65 ℃、改性剂用量为5%(质量分数)、悬浮液固体质量浓度为100 g/L的条件下,可以得到活化度为99.88%、吸油值为0.497 5 g/g的粉末状疏水性纳米硫酸钡。

关键词: 乳化机, 纳米硫酸钡, 改性

Abstract: Using the high shear mixing emulsifying machine to replace the ordinary mixer,nano-sized barium sulfate was modified by means of wet reaction.The effect of emulsifying time,emulsifying temperature,dosage of modifier,and solid content of nano-sized barium sulfate suspension on the activation degree of the modified nano-sized barium sulfate was also investigated.The coating situation and the morphology of the modified nano-sized barium sulfate were characterized by infrared spectrometer,thermogravimetric analyzer,and scanning electron microscope.Experimental results showed that hydrophobic nano-sized barium sulfate powder with activation degree of 99.88% and oil absorption value of 0.497 5 g/g could be obtained with the high shear mixing emulsifying machine,when emulsifying time was 15 min,emulsifying temperature was 65 ℃,dosage of modifier was 5%((mass fraction),and solid mass concentration of suspension was 100 g/L.

Key words: emulsification machine, nano-sized barium sulfate, modification

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