无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (4): 39-.

• 论文 • 上一篇    下一篇

纳米硫酸钡悬浮液的分散性研究

刘玉敏,刘 悦   

  1. 河北科技大学化学与制药工程学院,河北石家庄 050018
  • 出版日期:2015-04-10 发布日期:2015-04-20

Research on dispersion of nano-sized barium sulfate suspension

 LIU  Yu-Min, LIU   Yue   

  1. College of Chemical and Pharmaceutical Engineering,Hebei University of Science and Technology,Shijiazhuang 050018,China
  • Published:2015-04-10 Online:2015-04-20

摘要: 针对纳米硫酸钡粒径小、比表面积大、易团聚的特点,研究了纳米硫酸钡在液体介质中的分散行为。考察了pH、分散剂种类、分散剂用量、分散介质、超声时间等因素对纳米硫酸钡分散效果的影响。确定了纳米硫酸钡的最佳分散条件,即以水为液体介质、pH为10、加入5%(质量分数)聚丙烯酸钠、超声分散15 min时,纳米硫酸钡的沉降高度为8.9 cm、粒径为61.79 nm、电位为-38.6 mV;或以二甲基亚砜为液体介质、pH为7、超声分散15 min时,纳米硫酸钡的沉降高度为9.7 cm、粒径为89.4 nm、电位为22.3 mV,从而达到较好的分散效果。

关键词: 纳米硫酸钡, 液体介质, 分散

Abstract: Nano-sized barium sulfate has a small particle size,large specific surface area,and is easy to aggregate.So the dispersion behavior of nano-sized barium sulfate in liquid medium has been studied.The influence of pH,dispersant type, dosage of dispersing agent,dispersing medium,and ultrasonic time on the dispersing effect of nano-sized barium sulfate has been investigated.Thus the best dispersion conditions of nano-sized barium sulfate have been determined.Namely,using water as the liquid medium,pH=10,mass fraction of polyacrylic acid sodium is 5%,ultrasonic time is 15 min,the sedimentation height of nano-sized barium sulfate is 8.9 cm,the diameter is 61.79 nm,and the zeta value is -38.6 mV;or using dimethyl sulfoxide as the liquid medium,pH=7,ultrasonic time is 15 min,the precipitation height of the nano-sized barium sulfate is 9.7 cm,the diameter is 89.4 nm,and the zeta value is 22.3 mV.Under those conditions a good dispersion effect can be achieved.

Key words: nano-sized barium sulfate, liquid medium, dispersion

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