无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (1): 49-.

• 论文 • 上一篇    下一篇

富硼渣硫酸浸出实验研究

郁新芸,王 广,薛庆国,王静松   

  1. 北京科技大学钢铁冶金新技术国家重点实验室,北京 100083
  • 出版日期:2015-01-10 发布日期:2015-01-14

Study on leaching boron-rich slag with H2SO4

 YU  Xin-Yun, WANG   Guang, XUE  Qing-Guo, WANG  Jing-Song   

  1. State Key Laboratory of Iron and Steel Metallurgy New Technology,Beijing
    University of Science and Technology,Beijing 100083,China
  • Online:2015-01-10 Published:2015-01-14

摘要: 以硼铁精矿含碳球团还原熔分得到的富硼渣为原料,研究了其物相成分,并进行硫酸浸出实验,探究了硫酸用量、反应温度、反应时间及液固比对硼浸出率的影响。结果表明,该富硼渣中三氧化二硼的质量分数达到20%,主要含遂安石相和橄榄石相。硫酸浸出实验中,硼浸出率随着硫酸用量、反应温度和反应时间的增加而增大,随着液固比的增大而减小。当硫酸用量为理论用量的80%、液固体积质量比为8 mL/g、反应温度为40 ℃、反应时间为60 min时,富硼渣中硼的浸出率达到93.56%。

关键词: 富硼渣, 硫酸浸出, 硼的浸出率

Abstract: Boron-rich slag,obtained by treating boron-bearing iron concentrate based on carbon bearing pellet reduction and melting technology,was taken as the raw material.The composition of boron-rich slag was studied and then leaching experiments on it with H2SO4 were carried on.The influence of amount of sulfuric acid,reaction temperature,reaction time,and ratio of leaching liquid to solid on boron extraction rate was investigated respectively.Results showed that the mass fraction of diboron trioxide of the boron-rich slag reached 20%,and suanite and olivine were the main phases of the slag.In leaching experiments,it was found that boron extraction rates increased with the increasing of sulfuric acid amount,reaction temperature, and reaction time,while the extraction rates decreased with the increasing of ratio of liquid to solid.When the 80% of theoretical amount of sulfuric acid was added to the boron-rich slag,and the ratio of liquid to solid was 8 mL/g,reaction temperature was 40 ℃,and reaction time was 60 min,the boron extraction rate of the slag could reach 93.56%.

Key words: boron-rich slag, sulfuric acid leaching, boron extraction rate

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