无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (5): 38-.

• 论文 • 上一篇    下一篇

以硝酸处理西藏硼砂矿制备硼酸及硝酸钠的研究

肖景波,胡彩华   

  1. 南阳东方应用化工研究所,河南南阳 473000
  • 出版日期:2014-05-10 发布日期:2014-05-07

Study on synthesis of boric acid and sodium nitrate by using borax mine in Tibet under assistance of nitric acid

 XIAO  Jing-Bo, HU  Cai-Hua   

  1. Nanyang Oriental  Application Chemical Research Institute,Nanyang 473000,China
  • Published:2014-05-10 Online:2014-05-07

摘要: 以硼酸母液浸溶西藏硼砂矿,对所得硼砂溶液进行酸化,生成硼酸和硝酸钠;控制反应浓度和其他相关工艺条件,使硼酸和硝酸钠同时结晶,再利用二者相对密度的不同,采用重力分离法实现了硼酸与硝酸钠的有效分离。实验证明:硼和钠收率分别达到92.0%和91.5%,产品质量符合国家标准。工艺过程不对硼酸母液进行蒸发。

关键词: 硝酸, 硼砂矿, 硼酸, 硝酸钠

Abstract: Boric acid and sodium nitrate were prepared by the leaching of Tibet borax mine with boric acid mother liquor and by the subsequent acidification of the borax solution.By controlling the concentration of the reactants and other related process conditions,the crystallization of boric acid and sodium nitrate can be realized simultaneously.By using the property of difference in relative densities,boric acid and sodium nitrate were isolated with gravity separation.Results showed that the yields of boron and sodium were 92.0% and 91.5%,respectively.The product quality conformed to the state standards.Additionally,boric acid mother liquor did not need to be evaporated during the process.

Key words: nitric acid, borax mine, boric acid, sodium nitrate

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