无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (4): 56-.

• 论文 • 上一篇    下一篇

尾渣十水碳酸钠重结晶法制备一水碳酸钠工艺研究

杨兆娟1,王顺强2,赵艳龙3,王继洋4   

  1. 1.青海大学化工学院,青海西宁810016;2.青海盐湖镁业有限公司;3.青海西部镁业有限公司;4.中国人民武装警察部队学院
  • 出版日期:2014-04-10 发布日期:2014-04-08

Research on preparation process of sodium carbonate  monohydrate from sodium carbonate decahydrate tailings

Yang Zhaojuan1,Wang Shunqiang2,Zhao Yanlong3,Wang Jiyang4   

  1. 1.School of Chemical Engineering,Qinghai University,Xining 810016,China;2.Qinghai Saline Lake Magnesium Co.,Ltd.;
    3.Qinghai West Magnesium Co.,Ltd.;4.The Chinese People′s Armed Police Foreces Academy
  • Online:2014-04-10 Published:2014-04-08

摘要: 以生产偶氮二甲酰胺(ADC发泡剂)的尾渣为原料,用重结晶的方法制备一水碳酸钠。主要考察了结晶温度、结晶时间、母液套用次数等因素对一水碳酸钠的质量和收率的影响。确定了由尾渣回收碳酸钠的工艺条件:蒸发温度为85 ℃,结晶时间为60 min,母液套用两次,可使碳酸钠的收率达到89.28%。该工艺具有产品纯度高、工艺流程简单、操作简便等优点,可实现尾渣的资源化和绿色利用。

关键词: ADC发泡剂, 蒸发结晶, 十水碳酸钠, 收率

Abstract: Sodium carbonate monohydrate was prepared by recrystallization method with tailings from the production of ADC foaming agent as raw material.The influences of crystallization temperature,crystallization time,and use times of the mother liquid on the quality and yield of the sodium carbonate monohydrate were mainly investigated.The optimum process conditions were as follows:evaporation temperature was 85 ℃,crystallization time was 60 min,and use times of the mother liquid was 2. The yield could be up to 89.28% under the optimum coditions.The process has the advantages of high product purity,simple process,and easy operation etc.,which can realize tailings comprehensive utilization,and the green utilization.

Key words: ADC foaming agent, evaporation crystallization, sodium carbonate decahydrate, yield

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