无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (2): 10-.

• 论文 • 上一篇    下一篇

湿法磷酸除镁技术研究进展

邹 密1,明大增2,李志祥2,杨 劲1,张雯雯1   

  1. 1.昆明理工大学化学工程学院,云南昆明 650224;2.云南云天化国际化工股份有限公司
  • 出版日期:2014-02-10 发布日期:2014-01-24

Research progress in removing magnesium ions from wet-process phosphoric acid

Zou Mi1,Ming Dazeng2,Li Zhixiang2,Yang Jin1,Zhang Wenwen1   

  1. 1.Faculty of Chemical Engineering,Kunming University of Science and Technology,Kunming 650224,China;
    2.Yunnan Yuntianhua International Chemical Co.,Ltd.
  • Online:2014-02-10 Published:2014-01-24

摘要: 湿法磷酸中金属离子杂质的净化一直是磷酸净化技术的难点,特别是镁离子的分离。主要介绍了反胶团溶剂萃取法、离子交换法、液膜分离法、化学沉淀法、反渗透法和浓缩法在湿法磷酸净化除镁过程中的研究进展,分析了各种方法的优缺点和工业应用上的局限,展望了湿法磷酸除镁技术研究的发展方向。着重指出了液膜分离法具有选择性强、分离效果好、传质效率高、流程简单、能耗低等特点,和其他方法的结合能有效净化湿法磷酸中的金属阳离子,在工业上有十分广阔的应用前景。

关键词: 湿法磷酸, 镁离子, 净化

Abstract: The difficulty in phosphoric acid purification technology is the purification of metal ion impurities in wet-process phosphoric acid,especially the separation of magnesium ions.The research progress of removing magnesium ions from wet-process phosphoric acid with different methods,such as reverse micelle solvent extraction,ion exchange,liquid membrane separation,chemical precipitation,reverse osmosis,and evaporation,was mainly reviewed.The advantages and disadvantages of those methods and limitations thereof in the industrial applications were analyzed and the development direction of magnesium removing technology for wet-process phosphoric acid was proposed.The liquid membrane separation method has been highlighted because of the good selectivity,strong separation effect,high mass transfer efficiency,simple process,and low energy consumption,and the metal cations can be effectively purified in wet-process phosphoric acid when it combined with other methods.Therefore,it has a very broad application prospect in the industry.

Key words: wet-process phosphoric acid, magnesium ion, purification

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