无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (12): 54-.

• 论文 • 上一篇    下一篇

黄磷尾气解毒铬渣

李先荣,陈 宁,董明甫,谢友才,黄玉西,袁小超   

  1. 四川省银河化学股份有限公司,四川绵阳 622656
  • 出版日期:2014-12-10 发布日期:2014-12-08

Detoxification of chromium residue by yellow phosphorus tail gas

 LI  Xian-Rong, CHEN   Ning, DONG  Ming-Fu, XIE  You-Cai, HUANG  Yu-Xi, YUAN  Xiao-Chao   

  1. Sichuan Yinhe Chemical Co.,Ltd.,Mianyang 622656,China
  • Online:2014-12-10 Published:2014-12-08

摘要: 研究了黄磷尾气解毒铬渣。实验方法及工艺条件:将六价铬(铬酸钠)质量分数为1%的铬渣粉碎至粒度小于75 μm,取5 g样品加入石英管中,加热到600 ℃,反应20 min,然后在黄磷尾气气氛中冷却至200 ℃以下。实验结果表明,在上述条件下可以将铬渣中六价铬质量分数降至0.3 mg/kg,并且铬渣不会返黄。

关键词: 铬渣, 解毒, 黄磷尾气, 固废, 气废

Abstract: The detoxification of chromium residue using yellow phosphorus tail gas was researched. Experimental approach and process conditions: chromium residue, which contained 1% Cr(Ⅵ)[w(Na2CrO4)],was crashed to 75 μm below.Then, 5 g sample was took into quartz tube,reaction occurred in 600 ℃ for 20 min,and reactants was protected in yellow phosphorus tail gas till to cool below 200 ℃.Experiment results showed that,Cr(Ⅵ) in chromium residue could be reduced to 0.3 mg/kg,and had none brightness reversion phenomenon.

Key words: chromium residue, detoxification, yellow phosphorus tail gas, solid waste, gas waste