无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (6): 27-.

• 论文 • 上一篇    下一篇

西藏结则茶卡和龙木错盐湖卤水协同提锂研究

郝 勇1,张启海1,李广汉1,朱成财2   

  1. 1.西藏国能矿业发展有限公司,西藏拉萨 850000;2.中科院青海盐湖研究所
  • 出版日期:2013-06-10 发布日期:2013-06-09

Synergistic lithium extraction from mixed brines of Jiezechaka and Longmucuo salt lakes in Tibet

Hao Yong1,Zhang Qihai1,Li Guanghan1,Zhu Chengcai2   

  1. 1.Tibet Guoneng Mining Industry Development Co.,Ltd.,Lasa 850000,China;
    2.Qinghai Institute of Salt Lakes,Chinese Academy of Sciences
  • Published:2013-06-10 Online:2013-06-09

摘要: 硫酸镁亚型盐湖提取锂时,由于卤水中镁含量很高,造成镁锂分离困难。碳酸盐型盐湖在锂的开发利用过程中,受到碳酸根浓缩的影响,锂离子不能高度富集。通过把两种类型的卤水进行兑卤,析出大量三水合碳酸镁,基本去除体系内镁离子和碳酸根,卤水体系得到简化,得到锂含量较高的富锂卤水,富锂卤水通过添加碳酸钠析出品位较高的碳酸锂,锂的单次收率在80%以上。该方法既解决了硫酸盐型卤水镁锂分离的问题,也解决了碳酸盐型卤水锂的富集问题。

关键词: 混合兑卤, 碳酸锂, 盐湖开发

Abstract: At present,the separation of magnesium and lithium in sulfate-type salt lakes with high magnesium content is a difficult technical problem.In addition,lithium can′t be highly enriched with the increasing concentration of carbonate ions during exploiting lithium from carbonate-type salt lakes.In this research,the brines from sulfate-type salt lake and carbonate-type salt lake were mixed to separate out large amount of magnesium carbonate trihydrate,so that the magnesium and carbonate ions could be basically removed,and the brine system could be simplified.Therefore,the lithium rich brine could be obtained and high grade lithium carbonate could be separated out by adding sodium carbonate into it.The single lithium yield was over 80%.The method both solved magnesium-lithium separation and lithium enrichment problems of sulfate-type and carbonate-type salt lakes.

Key words: mixed brine, lithium carbonate, salt lake development

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