无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (5): 1-.

• 论文 •    下一篇

盐湖卤水资源锂镁分离的工艺技术

乜贞1,2,3,卜令忠1,2,3,王云生1,2,3,宋彭生2, 4,郑绵平1,2,3   

  1. 1.中国地质科学院矿产资源研究所,北京 100037;2.国土资源部盐湖资源与环境重点实验室;
    3.中国地质科学院盐湖与热水资源研究发展中心;4.中国科学院青海盐湖研究所
  • 发布日期:2013-05-03

Industrial technology for separation of lithium from magnesium rich salt lake brines

Nie Zhen1,2,3,Bu Lingzhong1,2,3,Wang Yunsheng1,2,3,Song Pengsheng2, 4,Zheng Mianping1,2,3   

  1. 1.Institute of Mineral Resources,Chinese Academy of Geological Sciences,Beijing 100037,China;2.Key Laboratory of Saline Lake Resources and Environment,Ministry of Land and Resource;3.R & D Center for Saline Lakes and Epithermal Deposits,
    Chinese Academy of Geological Science;4.Qinghai Institute of Salt Lakes,Chinese Academy of Sciences
  • Online:2013-05-03

摘要: 目前,盐湖卤水提锂是锂盐生产的主导,其各个工艺路线可归纳为制取富锂卤水、锂镁分离、碳酸锂沉淀3个过程,其中锂镁分离步骤最为关键。对自然分离法、碳酸盐沉淀法、煅烧浸取法、离子交换吸附法这4种镁锂分离方法的基本原理和在卤水提锂工业生产中的应用做了详细分析对比,讨论了各方法的使用范围,探讨了高镁锂比卤水分段除镁的通用方法,以期对中国盐湖锂资源开发工艺的选择提供技术借鉴。

关键词: 盐湖卤水, 提锂工艺, 锂镁分离, 镁锂比

Abstract: At present,the lithium extraction from the brine of salt lakes has dominated the lithium production and its processes can be divided into three main steps,i.e.1) preparation of brine with high concentration of Li;2)separation of Li from Mg rich brines;and 3)precipitation of lithium carbonate.In which the second step is the most important. Current separation processes mainly use four different methods:natural separation,carbonate precipitation,roasting-leaching separation,and ion exchange-adsorption process.The principles and industrial applications of these four methods have been compared and analyzed in detail,and their application scope as well as the common method for sectionally removing magnesium from high magnesium-lithium ratio brine was also discussed.It was expected that this study can be used as a technical reference for the selection of proper process in the development of salt lake lithium resources of China.

Key words: salt lake brine, lithium extraction technology, separation of lithium from magnesium, magnesium lithium ratio

中图分类号: