无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (9): 17-.

• 论文 • 上一篇    下一篇

铝酸钙粉矿物相红外光谱及铝溶出率分析

黄志刚1,章兴华2,陆 洋3,胡 智4,杨鸿波3,舒海霞3,朱守平2   

  1. 1.贵州省冶金科学研究室,贵州贵阳550002; 2.贵州省黔新企业集团有限公司;
    3.贵州省理化检测研究中心; 4.贵州省复合物改性聚合材料工程技术研究中心
  • 发布日期:2012-09-11

Analysis on infra-red spectrum of mineral phase of calcium aluminate powder and Al2O3 dissolution rate

Huang Zhigang1,Zhang Xinghua2,Lu Yang3,Hu Zhi4,Yang Hongbo3,Shu Haixia3,Zhu Shouping2   

  1. 1.Guizhou Metallurgical Science Research Office,Guiyang 550002,China;2.Guizhou Qian-Xin Enterprise Group
    Limited Company;3.Physics Test and Chemistry Analysis Research Center of Guizhou Province;
    4.Guizhou Engineering Research Center for Modified Polymer Material
  • Published:2012-09-11

摘要: 铝酸钙粉的结构会受到原料变化的强烈影响。对加入活化剂与未加入活化剂生产的铝酸钙粉进行了相关的结构鉴定与溶出率测定。X射线衍射及热重分析证实,加入活化剂的铝酸钙粉矿物相中含有卤化物,其中矿物相CaAl3XO7可能部分水解形成类弗雷德盐的双羟合结构体,这种铝酸钙粉存在2 116 cm-1及1 981 cm-1两个红外光谱特征峰。矿物相不同,铝酸钙粉的三氧化二铝溶出率有较大差异。

关键词: 铝酸钙粉, 中红外光谱, 结构鉴定, 溶出率

Abstract: The structure of calcium aluminate powder will be strongly affected by the changes of raw materials.The structure and dissolution rate of calcium aluminates,which were produced with activator and without activator,were identified and measured.XRD and TGA analysis showed that after adding activator,the mineral phase of calcium aluminate powder contained halide,in which the mineral phase CaAl3XO7 may be partially hydrolyzed to form Friedel′s salt double hydroxide phases.Furthermore,this calcium aluminate powder had two IR spectral feature peaks at 2 116 cm-1 and 1 981 cm-1.Different mineral phases,dissolution rates of Al2O3 in the calcium aluminate powder were quite different.

Key words: calcium aluminate powder, mid-FT-IR, structure identification, dissolution rate

中图分类号: