无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (4): 47-.

• 论文 • 上一篇    下一篇

由铵盐制备高纯氟化钡的工艺研究

许春晓,刘晓红,柯春兰,章小明   

  1. 南昌大学环境与化学工程学院,江西南昌 330031
  • 发布日期:2011-04-19

Preparation technology of high purity barium fluoride from ammonium salt

 XU  Chun-Xiao, LIU  Xiao-Hong, KE  Chun-Lan, ZHANG  Xiao-Ming   

  1. School of Environmental and Chemical Engineering, Nanchang University, Nanchang 330031,China
  • Published:2011-04-19

摘要: 以氟化铵和氯化钡为原料,采用沉淀法制备了氟化钡。反应温度为25 ℃,反应时间为60 min,氯化钡初始质量分数为10%,氟化铵与氯化钡物质的量比为2.2,m(洗水)∶m(滤饼)=10∶1,可制备出纯度达99%以上的氟化钡。XRD谱图表明,样品氟化钡的所有衍射峰均与标准立方相氟化钡吻合,属立方晶系。该工艺流程简单,经济效益好。

关键词:  , BaF2, 氟化铵, 氯化钡, 直接沉淀法

Abstract: Barium fluoride (BaF2) was prepared by precipitation method with ammonium fluoride and barium chloride as raw materials.BaF2 with purity of more than 99% can be prepared when reaction temperature is 25 ℃,reaction time is 60 min,initial mass fraction of barium chloride is 10%,amount-of-substance ratio of ammonium fluoride to barium chloride is 2.2,and the mass ratio of washing water amount to filter cake amount=10∶1.XRD pattern showed that all the diffraction peaks of barium fluoride sample were consistent with the standard cubic barium fluoride.Therefore it belongs to the cubic crystal system.The technology has short flow route and good economic benefits.

Key words: barium fluoride, ammonium fluoride, barium chloride, direct precipitation method

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