无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (12): 29-.

• 论文 • 上一篇    下一篇

阻燃型氢氧化镁表面改性及与PS复合效果研究

王路明   

  1. 盐城工学院,江苏盐城 224051
  • 发布日期:2011-12-06

Study on modification of fire[WT5.25BZ][JX-*6][KG-*2/3]-[KG-*3][JX*6][WT5HZ]retardant Mg(OH)2 and composite effect with PS

 WANG  Lu-Ming   

  1. Yancheng Institute of Technology,Yancheng 224051,China
  • Published:2011-12-06

摘要: 采用硬脂酸对氢氧化镁\[Mg(OH)2\]施行湿法有机化表面改性,将改性后的氢氧化镁加入到聚苯乙烯(PS)中混炼制备无机阻燃型PS-Mg(OH)2复合功能材料。通过X射线衍射(XRD)、红外光谱(FT-IR)、热分析(TG-DSC)和扫描电镜(SEM)等测试手段对氢氧化镁的表面改性机理进行综合分析,通过SEM以及氧指数、拉伸强度等测试方法对PS-Mg(OH)2复合材料的复合效果及性能进行测定。研究结果表明:硬脂酸对氢氧化镁的表面改性本质上是一个化学吸附过程;改性后的氢氧化镁颗粒与PS基体的相容性得到显著改善,复合材料的氧指数(OI)显著提高。当氢氧化镁添加量为PS质量的40%~60%时,OI达到25%左右,且材料的力学性能变化不大。

关键词: PS-Mg(OH)2复合材料, 表面改性, 氧指数, 力学性能

Abstract: Stearic acid was adopted to modified magnesium hydroxide \[Mg(OH)2\] by way of wet surface organic modification.Mixing the modified magnesium hydroxide into polystyrene (PS) to make inorganic fire-retardant PS-Mg(OH)2 composite.Mechanism about the surface modification on Mg(OH)2 was characterized and analyzed by XRD,FT-IR,TG-DSC,and SEM.And the composite effect and properties of PS-Mg(OH)2 composite were investigated by the tests of SEM,oxygen index,and tensile-strength etc..Results showed that the surface modification of stearic acid was a process of chemical absorption in essence;the compatibility of  Mg(OH)2 and PS base was improved greatly and the oxygen index (OI) of the composite has also been increased obviously;the OI reached about 25% when the dosage of Mg(OH)2 was at 40%~60% of PS,and meanwhile the mechanical properties did not have any change. 

Key words: PS-Mg(OH)2 composites, surface modification, oxygen index, mechanical property

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