二氧化氯稳定性相关基本性质及影响因素综述

doi:10.11962/1006-4990.2020-0233

无机盐工业 ›› 2021, Vol. 53 ›› Issue (3): 18-23.doi: 10.11962/1006-4990.2020-0233

二氧化氯稳定性相关基本性质及影响因素综述

刘宇鹤^1,^2,³(),吴明松^1,^2,³,王欣舒^1,^2,³,黄楠楠^1,^2,³,周秀艳^1,^2,³

1.东北大学资源与土木工程学院,辽宁沈阳 110819
2.东北大学秦皇岛分校资源与材料学院
3.秦皇岛市节水治污与生态修复重点实验室

收稿日期:2020-09-12 出版日期:2021-03-10 发布日期:2021-03-11
作者简介:刘宇鹤（1996— ）,女,硕士,主要从事饮用水安全消毒技术研究;E-mail：502383575@qq.com。
基金资助:
江西省重点研发计划(20171BBG70035);中央高校基本科研业务专项资金资助(N2023031)

Review of basic properties and influence factors related to stability of chlorine dioxide

Liu Yuhe^1,^2,³(),Wu Mingsong^1,^2,³,Wang Xinshu^1,^2,³,Huang Nannan^1,^2,³,Zhou Xiuyan^1,^2,³

1. School of Resources and Civil Engineering,Northeastern University,Shenyang,110819,China
2. School of Resourcesand Materials,Northeastern University at Qinhuangdao
3. Qinhuangdao Key Laboratory of Water Conservation and Pollution Control and Ecological restoration

Received:2020-09-12 Online:2021-03-10 Published:2021-03-11

摘要/Abstract

摘要：

二氧化氯作为一种广谱、高效消毒剂已得到广泛应用。但是,其自身活泼的性质难以制备成稳定制剂,对应用推广造成了限制。综述了二氧化氯稳定相关的基本化学性质以及pH、光、温度及其他共存物质的影响。指出二氧化氯无法在水中稳定存在,只能通过调整环境条件减缓分解、歧化过程,也可以利用平衡原理保持浓度稳定。此为高纯即用稳定二氧化氯的产品开发提供理论依据。在此基础上,应进一步进行二氧化氯转化的动力学研究,或尝试络合等方法提高二氧化氯相关产品的稳定性。

关键词: 二氧化氯, 稳定性, 歧化, 消毒剂

Abstract:

Chlorine dioxide has been widely used as a kind of high effective broad-spectrum and disinfectant.However,it is difficult to be prepared to stable formulations because of its active properties,which limits its application and promotion. The chemical properties and effects of pH,light,temperature and chlorinated substance to the stability of chlorine dioxide were reviewed.It is pointed out that ClO₂ cannot exist stably in water.It can only slow down the decomposition and disproportionation process by adjusting the environmental conditions or use the principle of equilibrium to keep the concentration stable,which provides a theoretical basis for the development of high purity and ready-to-use stable ClO₂ products.On this basis,the kinetics of ClO₂ conversion should be further studied,and methods such as complexation should be tried to improve the stability of ClO₂ related products.

Key words: chlorine dioxide, stability, disproportionation, disinfectant

中图分类号:

TQ124.43

刘宇鹤,吴明松,王欣舒,黄楠楠,周秀艳. 二氧化氯稳定性相关基本性质及影响因素综述[J]. 无机盐工业, 2021, 53(3): 18-23.

Liu Yuhe,Wu Mingsong,Wang Xinshu,Huang Nannan,Zhou Xiuyan. Review of basic properties and influence factors related to stability of chlorine dioxide[J]. Inorganic Chemicals Industry, 2021, 53(3): 18-23.

图/表 2

参考文献 33

[1]	吴明松, 马仕慈, 刘博. 二氧化氯在医院消毒中的应用[J]. 中国消毒学杂志, 2019,36(1):60-63.
[2]	张晓娜. 二氧化氯消毒在饮用水处理中的应用[J]. 城镇供水, 2019(1):15-17.
[3]	Ran Y, Qingmin C, Maorun F. Chlorine dioxide generation method and its action mechanism for removing harmful substances and maintaining quality attributes of agricultural products[J]. Food and Bioprocess Technology, 2019,12(7):1110-1122.
[4]	张晓娜, 刘清华, 陈卓华, 等. 稳定性二氧化氯活化试验研究[J]. 城镇供水, 2019(2):59-62.
[5]	Pugliese S, Underwood K, Soluri A, et al. Stabilized chlorine dioxide co-mpositions and methods for use as disinfectants:US, 2017202876[P]. 2017-07-20.
[6]	Gordon G. Is all chlorine dioxide created equal?[J]. Journal-Ameri-can Water Works Association, 2001,93(4):163-174.
[7]	Vaida V, Simon J D. The photoreactivity of chlorine dioxide[J]. Sci-ence, 1995,268(5216):1443-1448.
[8]	Vaida V, Goudjil K, Simon J D, et al. Comparisons between the reac-tivity of chlorine dioxide in the gas phase and water solution[J]. Journal of Molecular Liquids, 1994,61(1/2/3):133-152.
[9]	Dunn R C, Anderson J L, Foote C S, et al. Solution photochemistry of chlorine dioxide:mechanisms for the generation of atomic chlo-rine[J]. Journal of the American Chemical Society, 1993,115(12):5307.
[10]	田朝晖, 裴元生. 二氧化氯在水溶液中的歧化反应趋势[J]. 甘肃环境研究与监测, 2003,16(1):92-94.
[11]	Stanbury D M, Figlar J N. Vanishingly slow kinetics of the ClO₂/Cl^-reaction:its questionable significance in nonlinear chlorite reactio-ns [J]. Coordination Chemistry Reviews, 1999,187(1):223-232.
[12]	朱琨, 陈慧. 纯二氧化氯的稳定性及常规条件下储存方法研究[J]. 化工标准·计量·质量, 2005,25(9):35-38.
[13]	崔崇威. 二氧化氯消毒后给水管网中氯酸根和亚氯酸根的转化规律研究[J]. 中国消毒学杂志, 2018,35(12):881-885.
[14]	Marcon J, Mortha G, Marlin N, et al. New insights into the decompo-sition mechanism of chlorine dioxide at alkaline pH[J]. Holzforsc-hung, 2017,71(7/8):599-610.
[15]	Odeh I N, Francisco J S, Margerum D W. New pathways for chlo-rine dioxide decomposition in basic solution[J]. Inorganic Chemi-stry, 2002,41(24):6500-6506.
[16]	裴元生, 栾兆坤, 陈慧. 电子活度和pH对二氧化氯制备和稳定性的影响[J]. 无机化学学报, 2001,17(3):407-413.
[17]	Wu V C H. Chlorine dioxide (ClO₂)[M]. Siddiqui M W.Postharve-st management approaches for maintaining quality of fresh pro-duce. Switzerland:Springer,Cham, 2016: 209-218.
[18]	Bishenden E, Haddock J, Donaldson D J. Resonance-enhanced mu-ltiphoton ionization(REMPI) measurement of atomic chlorine(²P_3/2 and ²P_1/2) produced in the photolysis of chlorine dioxide(OClO) from 355 to 370 nm[J]. The Journal of Physical Chemistry, 1991,95(6):2113-2115.
[19]	候宏卫, 贺启环. 二氧化氯的性质及其相关反应[C]// 成都:全国制浆造纸行业国产二氧化氯装备及节能减排新技术应用推介会论文集,北京:中国造纸学会, 2011: 64-69.
[20]	Vaida V, Richard E C, Jefferson A, et al. Spectroscopy and photo-chemistry of chlorine dioxide[J]. Berichte Der Bunsengesellschaft Für Physikalische Chemie, 1992,96(3):391-394.
[21]	Vaida V, Frost G J, Brown L A, et al. Spectroscopy and photoreacti-vity in complex environments[J]. Berichte Der Bunsengesellschaft Für Physikalische Chemie, 1995,99(3):371-377.
[22]	Pursell C J, Conyers J, Alapat P, et al. Photochemistry of chlorine dioxide in ice[J]. The Journal of Physical Chemistry, 1995,99(26):10433-10437.
[23]	Reid P J. Understanding the phase-dependent reactivity of chlorine dioxide using resonance raman spectroscopy[J]. Accounts of Che-mical Research, 2001,34(9):691-698.
[24]	Chang Y J, Simon J D. Ultrafast dynamics of chlorine dioxide pho-tochemistry in water studied by femtosecond transient absorption spectroscopy[J]. The Journal of Physical Chemistry, 1996,100(16):6406-6411.
[25]	Cosson H, Ernst W R. Photodecomposition of chlorine dioxide and sodium chlorite in aqueous solution by irradiation with ultraviolet light[J]. Industrial & Engineering Chemistry Research, 1994,33(6):1468-1475.
[26]	于玲红, 段浩洁, 李卫平, 等. 二氧化氯在小型给水管网系统中的衰减规律研究[J]. 科学技术与工程, 2016,16(26):291-296.
[27]	袁海涛, 康志娟, 赵海栋, 等. 二氧化氯水溶液的稳定性研究[J]. 河北工业科技, 2010,27(5):302-304.
[28]	Mcwhorter T E, Kazlas P, Anand M, et al. Storage-stable aqueous solutions of chlorine dioxide and methods for preparing and using them:US,9045341B2[P]. 2015-06-02.
[29]	莫正波, 胡松涛, 胡德栋. 低浓度下亚氯酸钠与盐酸制备二氧化氯的试验研究[J]. 山东大学学报:工学版, 2017,47(2):100-105.
[30]	Ahlstrom C, Boyd D W, Epstein I R, et al. Reaction between per-manganate ion and chlorine(Ⅲ):kinetics and mechanism of the initial reaction and the dissociation of chlorous acid[J]. Inorganic Chemistry, 1984,23(14):2185-2188.
[31]	Kieffer R G, Gordon G. Disproportionation of chlorous acid.Ⅰ.stoic-hiometry[J]. Inorganic Chemistry, 1968,7(2):235-239.
[32]	Kieffer R G, Gordon G. Disproportionation of chlorous acid.Ⅱ.kine-tics[J]. Inorganic Chemistry, 1968,7(2):239-244.
[33]	Peintler G, Nagypal I, Epstein I R. Kinetics and mechanism of the reaction between chlorite ion and hypochlorous acid[J]. The Jour-nal of Physical Chemistry, 1990,94(7):2954-2958.

首页

全国无机盐信息中心

中国化工学会

无机酸碱盐专业委员会

二氧化氯稳定性相关基本性质及影响因素综述

Review of basic properties and influence factors related to stability of chlorine dioxide

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 2

参考文献 33

相关文章 15

Metrics

本文评价

推荐阅读 0

[1]	张彬,肖霄,韩芸娇,张媛媛,于宏伟. 碳酸钙三级红外光谱研究[J]. 无机盐工业, 2021, 53(1): 97-101.
[2]	贺玉刚,王芳,孙强,张晓伟,时庆合,付强. 探究吸附装置安装位置对多晶硅除硼磷的影响[J]. 无机盐工业, 2020, 52(3): 72-74.
[3]	高睿,周张健,张宏博,张笑歌. 二氧化硅气凝胶高温稳定性研究[J]. 无机盐工业, 2019, 51(9): 50-53.
[4]	程龙军,李钧,温炎燊,陈昌铭,安晓英,弓创周. 饲料级碱式氯化铜性质特征分析研究[J]. 无机盐工业, 2019, 51(9): 88-90.
[5]	翟伟，杨波，黄国家，王志刚，李仕平. 混合硝酸熔盐的制备及其性能研究[J]. 无机盐工业, 2019, 51(7): 33-38.
[6]	常峻玮,于名利,郭强. 自组装制备硫化铜空穴传输层用于钙钛矿太阳能电池[J]. 无机盐工业, 2019, 51(3): 25-28.
[7]	吴洁帆, 刘红光, 叶学海, 夏继平, 卢阳, 林超旺, 张晓波. 不同铝源对LiNi1/3Co1/3Mn1/3O2材料的包覆改性研究[J]. 无机盐工业, 2015, 47(7): 71-.
[8]	. 纳米氧化镁在丙二醇中的分散及稳定性研究*[J]. 无机盐工业, 2015, 47(6): 39-.
[9]	杨林, 易德莲, 汪成, 伍林. 硫酸钛液稳定性分析及偏钛酸粒度控制研究[J]. 无机盐工业, 2015, 47(4): 26-.
[10]	李连成, 叶学海, 李星玥. 锂离子二次电池电解液研究进展[J]. 无机盐工业, 2014, 46(9): 7-.
[11]	童孟良, 舒均杰, 王罗强. 镁铝水滑石的制备与性能研究[J]. 无机盐工业, 2014, 46(4): 22-.
[12]	宋伟, 徐雪丽. 高收率高稳定性过碳酸钠的制备[J]. 无机盐工业, 2014, 46(3): 50-.
[13]	韩凤兰, 杨奇星, 吴澜尔, 郭生伟. 皮江法炼镁镁渣的回收处理[J]. 无机盐工业, 2013, 45(7): 52-.
[14]	赵修太, 白英睿, 戚元久, 宫汝祥, 王增宝, 尚校森, 吴洁. 无机盐对乳状液稳定性和转相的影响[J]. 无机盐工业, 2012, 44(9): 25-.
[15]	李建生, 刘炳光, 孙宝丰, 董广前, 王芳. 氯酸钠法制备二氧化氯还原剂研究进展[J]. 无机盐工业, 2012, 44(7): 9-.

首 页

二氧化氯稳定性相关基本性质及影响因素综述

Review of basic properties and influence factors related to stability of chlorine dioxide

RichHTML

PDF (PC)

可视化

引用本文

使用本文

首页