无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2019, Vol. 51 ›› Issue (11): 20-22.doi: 10.11962/1006-4990.2018-0679

• 无机盐工业 • 上一篇    下一篇

水溶性聚磷酸铵螯合锌的规律研究

梁 文,王辛龙,陈建钧,谢汶级,冷新科,凌浩瀚   

  1. 四川大学化学工程学院,四川成都 610065
  • 出版日期:2019-11-10 发布日期:2020-02-28
  • 作者简介:梁文(1994— ),男,硕士,主要从事水溶性聚磷酸铵肥料的相关研究;E-mail:FD_Liang@163.com。 通讯作者:王辛龙,男,博士,教授,长期从事磷资源开发与利用、磷酸盐与磷复肥的综合利用;E-mail:wangxl@scu.edu.cn。

Study on law of chelated Zn by water?鄄soluble ammonium polyphosphate

Liang Wen,Wang Xinlong,Chen Jianjun,Xie Wenji,Leng Xinke,Ling Haohan   

  1. School of Chemical Engineering,Sichuan University,Chengdu 610065,China
  • Online:2019-11-10 Published:2020-02-28

摘要: 以水溶性聚磷酸铵(APP)和硫酸锌为原料,对聚磷酸铵与锌的螯合规律做了研究。采用傅里叶红外光谱法对聚磷酸铵及其螯合物做了表征,验证了螯合物的生成。采用FBRM在线粒度监测法考察了温度和pH对聚磷酸铵螯合锌性能的影响。结果表明:相同pH下,在5~40 ℃时,聚磷酸铵对于锌的螯合容量随着温度的升高逐渐降低;相同温度下,在pH为 5~8时,聚磷酸铵对于锌的螯合容量随着pH的增大呈现出先减后增的趋势,且在pH=5.5时出现最低值0.024 3 g/g(以每1 g APP含Zn计,下同)。采用无因次方程拟合,建立了螯合容量与温度、pH关系的数学模型。

关键词: 聚磷酸铵;螯合;锌

Abstract: The law of chelated Zn by ammonium polyphosphate was studied,with watersoluble ammonium polyphosphate and zinc sulphate as raw materials.Ammonium polyphosphate and its chelated product were characterized and the preparation of chelated product was tested.The effect of temperature and pH on the capacity of chelated zinc by ammonium polyphosphate by FBRM was investigated.The results indicated that the chelating capacity of ammonium polyphosphate on Zn gradually reduced with the raising of temperature(5~40 ℃) when pH was kept constant.In addition,the chelating capacity showed a trend of de creasing first and the increasing with the increase of pH(5~8) and the chelating capacity reached 0.024 3 g/g(per 1 g APP) when pH=5.5.A dimensionless equation was developed to predict operational conditions of chelating capacity,temperature and pH.

Key words: ammonium polyphosphate;chelation;zinc

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