Inorganic Chemicals Industry >
Application status and development direction of wet flue gas desulfurization technology
Received date: 2022-03-04
Online published: 2022-12-19
With the accelerating pace of ecological civilization construction，people′s requirements for atmospheric environmental quality are getting higher and higher.SO2 is one of the main pollutants in industrial flue gas，and its control and emission reduction are extremely important to improve environmental quality.The research progress of wet desulfurization technology at home and abroad was summarized，the principle and application status of traditional wet desulfurization technology was introduced，and the main existing problems were puts forward，such as the unsustainability and regional limitation of desulfurization absorbent，the resource utilization and environmental pollution of desulfurization by-products，the reliability of desulfurization system equipment and the operation economy.The principle and research emphasis of new wet desulfurization technology were analyzed，and it was pointed out that the development direction of wet desulfurization technology in the future was to develop and popularize new environmentally friendly and recyclable desulfurization absorbent，vigorously develop the resource utilization technology of traditional wet desulfurization by-products，and accelerate the transformation of new wet desulfurization technology achievements.
Wen HUA , Ruiliang Lü . Application status and development direction of wet flue gas desulfurization technology[J]. Inorganic Chemicals Industry, 2022 , 54(12) : 10 -18 . DOI: 10.19964/j.issn.1006-4990.2022-0057
| 1 | 郝吉明, 马广大. 大气污染控制工程[M]. 2版. 北京：高等教育出版社, 2010. |
| 2 | 中华人民共和国生态环境部. 中国生态环境统计年报?2019[M].北京：中国环境出版集团, 2021. |
| 3 | 马林. 国外烟气脱硫技术应用进展回顾[J]. 化工管理, 2015(31)：119. |
| 3 | MA Lin. Review of application progress of flue gas desulfurization technology abroad[J]. Chemical Enterprise Management, 2015(31)：119 |
| 4 | 金平, 王昊辰, 李磊, 等. 烟气脱硫技术现状及展望[J]. 当代化工, 2019, 48(1)：119-121, 126. |
| 4 | JIN Ping, WANG Haochen, LI Lei, et al. Status and prospect of flue gas desulfurization[J]. Contemporary Chemical Industry, 2019, 48(1)：119-121, 126. |
| 5 | 王文飚, 许月阳, 薛建明, 等. 燃煤电厂脱硫技术研究进展及建议[J]. 电力科技与环保, 2020, 36(3)：1-5. |
| 5 | WANG Wenbiao, XU Yueyang, XUE Jianming, et al. The research progress and suggestions of desulfurization technology in coal-fired power plants[J]. Electric Power Technology and Environmental Protection, 2020, 36(3)：1-5. |
| 6 | 杜家芝, 曹顺安. 湿法烟气脱硫技术的现状与进展[J]. 应用化工, 2019, 48(6)：1495-1500. |
| 6 | DU Jiazhi, CAO Shunan. Research status and progress of wet flue gas desulfurization technology[J]. Applied Chemical Industry, 2019, 48(6)：1495-1500. |
| 7 | 李存杰, 张军, 张涌新, 等. 基于pH值分区控制的湿法烟气脱硫增效研究[J]. 环境科学学报, 2015, 35(12)：4081-4087. |
| 7 | LI Cunjie, ZHANG Jun, ZHANG Yongxin, et al. Removal efficiency of high sulfur dioxide in WFGD based on dual-pH value control[J]. Acta Scientiae Circumstantiae, 2015, 35(12)：4081-4087. |
| 8 | QIN Mingchen, DONG Yong, CUI Lin, et al. Pilot-scale experiment and simulation optimization of dual-loop wet flue gas desulfurization spray scrubbers[J]. Chemical Engineering Research and Design, 2019, 148: 280-290. |
| 9 | 张赢丹, 丁俊, 丁宏. 单塔双区脱硫技术在燃煤电厂中的应用[J]. 浙江电力, 2018, 37(3)：73-76. |
| 9 | ZHANG Yingdan, DING Jun, DING Hong. Application of single tower and double zone desulphurization technology in coal-fired power plants[J]. Zhejiang Electric Power, 2018, 37(3)：73-76. |
| 10 | 李乐. 浅析石灰石-石膏湿法烟气脱硫吸收塔选型及设计[J]. 中国设备工程, 2021(22)：146-148. |
| 10 | LI Le. Analysis on selection and design of limestone-gypsum wet flue gas desulfurization absorption tower[J]. China Plant Engineering, 2021(22)：146-148. |
| 11 | 何红博, 刘岩. 浅析浆液冷却系统对湿法脱硫的影响[J]. 化工管理, 2015(20)：54. |
| 11 | HE Hongbo, LIU Yan. Analysis of influence of slurry cooling system on wet desulfurization[J]. Chemical Enterprise Management, 2015(20)：54. |
| 12 | 金侃. 燃煤电站环保装备运行成本效益研究[D].杭州：浙江大学, 2016. |
| 12 | JIN Kan. Study on cost-benefit of envrionmental protection equipment in coal-fired power plants[D].Hangzhou：Zhejiang University, 2016. |
| 13 | 蒋婷, 田浩臣, 蔡琳, 等. 燃煤电厂湿法脱硫故障数据及可靠性分析[J]. 锅炉技术, 2017, 48(4)：68-73. |
| 13 | JIANG Ting, TIAN Haochen, CAI Lin, et al. Analysis on fault data and reliability of wet desulphurization of coal-fired power plants[J]. Boiler Technology, 2017, 48(4)：68-73. |
| 14 | WANG Qunkui, LIU Jing, XUE Fangming. Case analysis and preventive measures of limestone-gypsum wet flue gas desulfurization slurry poisoning for 320 MW unit[J]. IOP Conference Series：Earth and Environmental Science, 2021, 651(2).Doi：10.1088/1755-1315/651/2/022079 . |
| 15 | SONG Da, MA Ying, XUE Fangming, et al. Research on countermeasures against slurry foaming and poisoning of desulphurization system in coal-fired power plants[J]. IOP Conference Series：Earth and Environmental Science, 2021, 651(2).Doi：10.1088/1755-1315/651/2/022069 . |
| 16 | 庞子涛, 黄思齐, 宋永吉, 等. 燃煤烟气同时脱硫脱硝技术研究现状与展望[J]. 现代化工, 2019, 39(1)：56-60. |
| 16 | PANG Zitao, HUANG Siqi, SONG Yongji, et al. Research status and prospect for simultaneous desulfurization and denitrification of coal-fired flue gas[J]. Modern Chemical Industry, 2019, 39(1)：56-60. |
| 17 | 王睿, 王连勇, 崔家新, 等. 燃煤烟气同时脱硫脱硝技术研究现状[C]// 第十一届全国能源与热工学术年会论文集. 沈阳： 中国金属学会能源与热工分会, 2021：26-34. |
| 18 | 沙成豪, 张冬冬, 谭波, 等. 湿法烟气脱硫系统协同脱汞研究进展[C]// 中国环境科学学会2021年科学技术年会——环境工程技术创新与应用分会场论文集（三）. 北京： 中国环境科学学会环境工程分会, 2021：154-158，244. |
| 19 | WU Qirong, GU Min, DU Yungui, et al. Synergistic removal of dust using the wet flue gas desulfurization systems[J]. Royal Society Open Science, 2019, 6(7).Doi：10.1098/rsos.181696 . |
| 20 | ZHANG Shanshan, WU Qiaoling, JIN Yinjia, et al. Study on biological treatment of limestone-gypsum wet desulfurization wastewater[J]. IOP Conference Series：Materials Science and Engineering, 2019, 563(2).Doi：10.1088/1757-899X/563/2/022007 . |
| 21 | 项飞鹏, 陈锡炯, 刘春红, 等. 火电脱硫石膏资源化利用研究进展[J]. 新型建筑材料, 2021, 48(6)：25-30. |
| 21 | XIANG Feipeng, CHEN Xijiong, LIU Chunhong, et al. Research status on resource utilization of power plant desulfurization gypsum[J]. New Building Materials, 2021, 48(6)：25-30. |
| 22 | DENG Yongqiang, ZOU Peng, WU Fayuan, et al. Discussion on the cause of scaling in wet desulfurization system of large coal-fired power plants[J]. IOP Conference Series：Earth and Environmental Science, 2018, 199.Doi：10.1088/1755-1315/199/5/052021 . |
| 23 | 马双忱, 徐昉, 徐东升, 等. 湿法脱硫吸收塔结垢原因分析与防治[J]. 电力科学与工程, 2019, 35(4)：51-58. |
| 23 | MA Shuangchen, XU Fang, XU Dongsheng, et al. Cause analysis and prevention of scale formation in wet desulfurization absorption tower[J]. Electric Power Science and Engineering, 2019, 35(4)：51-58. |
| 24 | 李文鼎, 高惠华, 蔡文丰. 石灰石–石膏湿法脱硫吸收塔结垢分析及预防措施[J]. 发电技术, 2019, 40(1)：51-55. |
| 24 | LI Wending, GAO Huihua, CAI Wenfeng. Scaling analysis and preventive measures of limestone-gypsum wet flue gas desulfurization[J]. Power Generation Technology, 2019, 40(1)：51-55. |
| 25 | 郭江源, 张志勇, 吴宇, 等. 石灰石-石膏湿法脱硫系统常见问题分析[C]//中国环境科学学会2019年科学技术年会——环境工程技术创新与应用分论坛论文集（四）.北京：中国环境科学学会环境工程分会, 2019：389-393. |
| 26 | 窦吉平, 刘文武, 高志斗. 脱硫系统设备与管道的腐蚀与防护[J]. 冶金能源, 2018, 37(5)：58-61. |
| 26 | DOU Jiping, LIU Wenwu, GAO Zhidou. Discussion and analysis of the corrosion and protection of the equipment and pipes in the desulfirization system[J]. Energy for Metallurgical Industry, 2018, 37(5)：58-61. |
| 27 | 刘林程, 左海滨, 许志强. 工业石膏的资源化利用途径与展望[J]. 无机盐工业, 2021, 53(10)：1-9. |
| 27 | LIU Lincheng, ZUO Haibin, XU Zhiqiang. Resource utilization approach of industrial gypsum and its prospect[J]. Inorganic Chemicals Industry, 2021, 53(10)：1-9. |
| 28 | NI Tingting, WANG Yunzhong, HUANG Chenghui, et al. Limestone-gypsum wet flue gas desulfurization wastewater treatment[J]. IOP Conference Series：Earth and Environmental Science, 2021, 651(4).Doi：10.1088/1755-1315/651/4/042034 . |
| 29 | 山乐胜. 应用氧化镁法烟气脱硫工艺的可行性分析[J]. 山东电力技术, 2003(6)：14-16. |
| 29 | SHAN Yuesheng. Feasibility study of application of magnesia FGD process[J]. Shandong Electric Power, 2003(6)：14-16. |
| 30 | 冯雅丽, 廖圣德, 李浩然, 等. 镁法脱硫及脱硫产物多元化利用研究现状[J]. 无机盐工业, 2019, 51(3)：1-6. |
| 30 | FENG Yali, LIAO Shengde, LI Haoran, et al. Research status of magnesium desulphurization and diversified utilization of desulfurization products[J]. Inorganic Chemicals Industry, 2019, 51(3)：1-6. |
| 31 | QU Litao, LI Caiting, LI Chao, et al. Evaluation of ultralow emission performance of magnesium oxide（MgO） wet flue gas desulfurization unit for coal-fired units[J]. IOP Conference Series：Earth and Environmental Science, 2019, 267(6).Doi：10.1088/1755-1315/267/6/062045 . |
| 32 | 王昕竑, 周欣, 王中原, 等. 七水硫酸镁干燥脱水制取一水硫酸镁实验研究[J]. 无机盐工业, 2011, 43(10)：45-47. |
| 32 | WANG Xinhong, ZHOU Xin, WANG Zhongyuan, et al. Study on preparation of magnesium sulfate monohydrate by dehydration of magnesium sulfate heptahydrate[J]. Inorganic Chemicals Industry, 2011, 43(10)：45-47. |
| 33 | 亢万忠. 镁法烟气脱硫副产物资源化利用研究[D].上海：华东理工大学, 2011. |
| 33 | KANG Wanzhong. Research on resources utilization of by-product from flue gas desulfurization employing magnesium process[D]. Shanghai：East China University of Science and Technology, 2011. |
| 34 | 高原, 王振平, 沈小瑞, 等. 工业锅炉钙、镁法烟气脱硫经济性分析[J]. 山东化工, 2021, 50(20)：249-250. |
| 34 | GAO Yuan, WANG Zhenping, SHEN Xiaorui, et al. Analysis of dosage of calcium and magnesium flue gas desulfurization agents for industrial boilers[J]. Shandong Chemical Industry, 2021, 50(20)：249-250. |
| 35 | 王海风, 张春霞, 齐渊洪. 氨法脱硫研究进展[J]. 环境工程, 2010, 28(6)：55-58, 62. |
| 35 | WANG Haifeng, ZHANG Chunxia, QI Yuanhong. Status of research on desulfurization by ammonia method[J]. Environmental Engineering, 2010, 28(6)：55-58, 62. |
| 36 | 丁红蕾, 苏秋凤, 张涌新, 等. 湿式氨法烟气脱硫工艺影响因素的试验研究[J]. 热力发电, 2014, 43(1)：96-98, 136. |
| 36 | DING Honglei, SU Qiufeng, ZHANG Yongxin, et al. Experimental study on factors affecting the ammonia-based WFGD process[J]. Thermal Power Generation, 2014, 43(1)：96-98, 136. |
| 37 | LIAN Zhouyang, LUO Zhengwei, YUAN Lirui, et al. Corrosion inhibition of organic amine on Q235 steel in ammonium sulfate slurry of ammonia flue gas desulfurization system[J]. Anti-Corro- sion Methods and Materials, 2017, 64(4)：432-442. |
| 38 | 祁晓晖, 冯想红. 氨法脱硫的硫酸铵结晶影响因素探究[C]//第二十五届大气污染防治技术研讨会论文集.北京：中国环境科学学会, 2021：271-275. |
| 39 | 聂鑫. 海水法烟气脱硫技术在爪哇7号工程中的应用[J]. 能源科技, 2021, 19(2)：57-62. |
| 39 | NIE Xin. Application of seawater flue gas desulfurization technology in jawa No.7 project[J]. Energy Science and Technology, 2021, 19(2)：57-62. |
| 40 | 姜华, 薛军, 祝良燮. 我国火电厂烟气海水脱硫的发展建议[J]. 环境保护, 2014, 42(S1)：69-71. |
| 40 | JIANG Hua, XUE Jun, ZHU Liangxie. Suggestions for development of flue gas seawater desulfurization in thermal power plants in China[J]. Environmental Protection, 2014, 42(S1)：69-71. |
| 41 | 郭娟, 袁东星, 陈进生, 等. 燃煤电厂海水脱硫工艺的排水对海域环境的影响[J]. 环境工程学报, 2008(5)：707-711. |
| 41 | GUO Juan, YUAN Dongxing, CHEN Jinsheng, et al. Impact of discharge water from seawater flue gas desulfurization system of coal-fired power plant on the environment of surrounding sea area[J]. Chinese Journal of Environmental Engineering, 2008(5)：707-711. |
| 42 | 李枭鸣, 王圣, 姜艳靓, 等. 沿海燃煤电厂采用海水脱硫的环境影响适用性分析研究[J]. 环境科学与管理, 2015, 40(1)：94-97. |
| 42 | LI Xiaoming, WANG Sheng, JIANG Yanliang, et al. Environmental impact feasibility of using seawater FGD process in coastal city[J]. Environmental Science and Management, 2015, 40(1)：94-97. |
| 43 | 顾晓薇, 张延年, 张伟峰, 等. 大宗工业固废高值建材化利用研究现状与展望[J]. 金属矿山, 2022(1)：2-13. |
| 43 | GU Xiaowei, ZHANG Yannian, ZHANG Weifeng, et al. Research status and prospect of high value building materials utilization of bulk industrial solid waste[J]. Metal Mine, 2022(1)：2-13. |
| 44 | 郭本凯, 夏瑞杰, 王吉营, 等. 硬石膏和脱硫石膏对低钙硫铝酸盐水泥熟料性能的影响[J]. 水泥工程, 2021(4)：4-7, 15. |
| 44 | GUO Benkai, XIA Ruijie, WANG Jiying, et al. Effect of anhydrite and desulfurized gypsum on the properties of low calcium sulphoaluminate cement clinker[J]. Cement Engineering, 2021(4)：4-7, 15. |
| 45 | 秦萍, 肖国举, 罗成科, 等. 燃煤电厂脱硫石膏改良碱化土壤种植甜高粱的施用量研究[J]. 现代农业科学, 2008(12)：32-35. |
| 45 | QIN Ping, XIAO Guoju, LUO Chengke, et al. Study on the application amount of desulfurized gypsum from coal-fired power plant in improving alkalized soil to plant sweet sorghum[J]. Modern Agricultural Sciences, 2008(12)：32-35. |
| 46 | 梁玲. 离子液循环吸收脱硫工程主要设备参数计算与选型[J]. 有色冶金节能, 2021, 37(1)：62-66. |
| 46 | LIANG Ling. Parameters calculation and selection of main equipment for ionic liquid absorption cyclic desulfurization[J]. Energy Saving of Nonferrous Metallurgy, 2021, 37(1)：62-66. |
| 47 | 产文兵, 万皓, 宋桂东, 等. 钠碱法烟气脱硫工艺技术[J]. 上海大学学报：自然科学版, 2013, 19(5)：474-478. |
| 47 | CHAN Wenbing, WAN Hao, SONG Guidong, et al. FGD process technology with sodium alkaline method[J]. Journal of Shanghai University：Natural Science, 2013, 19(5)：474-478. |
| 48 | 袁志国, 刘有智, 康晓峰, 等. 超重力-磷酸钠法脱除低浓度SO2 [J]. 环境工程学报, 2013, 7(11)：4475-4480. |
| 48 | YUAN Zhiguo, LIU Youzhi, KANG Xiaofeng, et al. Removal of low concentration sulfur dioxide from gas by aqueous of sodium phosphate in high gravity[J]. Chinese Journal of Environmental Engineering, 2013, 7(11)：4475-4480. |
| 49 | 王亚. 烟气氨酸法脱硫技术在锌冶炼中的应用[J]. 中国金属通报, 2018(4)：73-74. |
| 49 | WANG Ya. Application of flue gas ammonia acid desulfurization technology in zinc smelting[J]. China Metal Bulletin, 2018(4)：73-74. |
| 50 | 李洪伟, 彭红寒, 袁红欣, 等. 铅锌冶炼烟气氨酸法脱硫技术的研究与运用[J]. 硫酸工业, 2017(1)：29-32. |
| 50 | LI Hongwei, PENG Honghan, YUAN Hongxin, et al. Research and application of desulphurization method by ammonia in sulphuric acid plant based on lead and zinc smelting off-gases[J]. Sulphuric Acid Industry, 2017(1)：29-32. |
| 51 | 黄金凤. 膜吸收法烟气脱硫的研究[D].南京：南京理工大学, 2004. |
| 52 | LIU Jie, DENG Mengxuan, YUAN Junsheng, et al. An aeration membrane absorption seawater flue gas desulfurization process intensified by combining dual-phase flow and oxidation reaction[J]. Chemical Engineering and Processing-Process Intensification, 2020, 153.Doi：10.1016/j.cep.2020.107935 . |
| 53 | 刘铮, 关毅鹏, 曹震, 等. 膜气体吸收-氨法脱硫技术在煤化工废气处理中的应用[J]. 膜科学与技术, 2018, 38(2)：106-110. |
| 53 | LIU Zheng, GUAN Yipeng, CAO Zhen, et al. Application of membrane gas absorption and ammonia desulphurization combination technique in the treatment of coal chemical waste gas[J]. Membrane Science and Technology, 2018, 38(2)：106-110. |
| 54 | 崔振东, 侯纯扬, 陈颖, 等. 膜吸收法浓海水烟气脱硫试验研究[J]. 膜科学与技术, 2011, 31(1)：84-88. |
| 54 | CUI Zhendong, HOU Chunyang, CHEN Ying, et al. Study of concentrated seawater flue gas desulphurization by membrane absorption[J]. Membrane Science and Technology, 2011, 31(1)：84-88. |
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