基于氧化铁/生物质碳复合材料的高性能超级电容器研究

doi:10.19964/j.issn.1006-4990.2021-0352

Abstract

Abstract:

To improve the low specific capacitance of carbon materials as well as the poor electrical conductivity and low cyclic stability of ferric oxide（Fe₂O₃）,Fe₂O₃ was used to modify the surface of biomass-derived carbon to prepare Fe₂O₃/bio-mass carbon composites,which achieved higher specific capacitance and better stability by the synergistic effect of Fe₂O₃ and biomass-derived carbon.The samples were characterized by scanning electron microscopy（SEM）、X-ray photoelectron spec-troscopy（XPS） and Raman spectra.The results demonstrated that the prepared composites had a certain pore struc-ture,with Fe₂O₃ nanoparticles anchored on the carbon surface.When the mass ratio of Fe₂O₃ and biomass-derived carbon was 1:1,the prepared composites possessed the best electrochemical performance,showing a high specific capacitance of 430.8 F/g（1.0 A/g） in 3.0 mol/L KOH.The capacitance retention was still greater than 60% when the current density was increased by 20 times.The asymmetric supercapacitor constructed by using it as the negative electrode had a high voltage window（0~1.6 V） and achieved a high energy density of 39.1 W·h/kg.While,it also exhibited excellent cycling stability with 111% capacitance retention after 5 000 cycles at 10 A/g.

Key words: biomass, Fe₂O₃, composite materials, specific capacitance, supercapacitor

CLC Number:

WANG Dian,SU Qiong,PANG Shaofeng,CAO Shijun,KANG Lihui,LIANG Lichun,WANG Yanbin,LI Zhaoxia. Study on high-performance supercapacitors based on Fe₂O₃/biomass carbon composites[J]. Inorganic Chemicals Industry, 2022, 54(3): 59-65.

Figures/Tables 7

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

References 31

[1]	DINH K N, LIANG Q, DU C F, et al. Nanostructured metallic transi-tion metal carbides,nitrides,phosphides,and borides for energy sto-rage and conversion[J]. Nano Today, 2019, 25:99-121. doi: 10.1016/j.nantod.2019.02.008
[2]	MURALEEGOPI C V V, VINODH R, SAMBASIVAM S, et al. Rec-ent progress of advanced energy storage materials for flexible and wearable supercapacitor:From design and development to applicat-ions[J]. Journal of Energy Storage, 2020, 27.Doi: 10.1016/j.est.2019.101035. doi: 10.1016/j.est.2019.101035
[3]	SETHURAMAN B, PURUSHOTHAMAN K K, MURALIDHARAN G. Synjournal of mesh-like Fe₂O₃/C nanocomposite via greener route for high performance supercapacitors[J]. RSC Advances, 2014, 4(9):4631-4637. doi: 10.1039/C3RA45025B
[4]	SHENG L, JIANG L, WEI T, et al. Spatial charge storage within ho-neycomb-carbon frameworks for ultrafast supercapacitors with high energy and power densities[J]. Advanced Energy Materials, 2017, 7(19).Doi: 10.1002/aenm.201700668. doi: 10.1002/aenm.201700668
[5]	PAN Z, ZHONG J, ZHANG Q, et al. Ultrafast all-solid-state coaxial asymmetric fiber supercapacitors with a high volumetric energy den-sity[J]. Advanced Energy Materials, 2018, 8(14).Doi: 10.1002/aenm.201702946. doi: 10.1002/aenm.201702946
[6]	HAN J, HIRATA A, DU J, et al. Intercalation pseudocapacitance of amorphous titanium dioxide@nanoporous graphene for high-rate and large-capacity energy storage[J]. Nano Energy, 2018, 49:354-362. doi: 10.1016/j.nanoen.2018.04.063
[7]	LI Y, ZHANG H, WANG S, et al. Facile low-temperature synjournal of hematite quantum dots anchored on a three-dimensional ultra-po-rous graphene-like framework as advanced anode materials for asy-mmetric supercapacitors[J]. Journal of Materials Chemistry A, 2016, 4(29):11247-11255. doi: 10.1039/C6TA02927B
[8]	JI W, JI J, CUI X, et al. Polypyrrole encapsulation on flower-like po-rous NiO for advanced high-performance supercapacitors[J]. Che-mical Communications, 2015, 51(36):7669-7672.
[9]	HAO J, PENG S, LI H, et al. A low crystallinity oxygen-vacancy-rich Co₃O₄ cathode for high-performance flexible asymmetric supercapa-citors[J]. Journal of Materials Chemistry A, 2018, 6(33):16094-16100. doi: 10.1039/C8TA06349D
[10]	何启贤, 袁学韬. 基于纳米片状二氧化锰的柔性固态超级电容的性能研究[J]. 无机盐工业, 2018, 50(2):43-45.
[11]	QI Z, YOUNIS A, CHU D, et al. A facile and template-free one-pot synjournal of Mn₃O₄ nanostructures as electrochemical supercapaci-tors[J]. Nano-Micro Letters, 2016, 8(2):165-173. doi: 10.1007/s40820-015-0074-0
[12]	JIA H, WANG Z, LI C, et al. Designing oxygen bonding between reduced graphene oxide and multishelled Mn₃O₄ hollow spheres for enhanced performance of supercapacitors[J]. Journal of Materi-als Chemistry A, 2019, 7(12):6686-6694.
[13]	XU W, DAI S, LIU G, et al. CuO nanoflowers growing on carbon fiber fabric for flexible high-performance supercapacitors[J]. Elec-trochimica Acta, 2016, 203:1-8.
[14]	CHO E C, CHANG-JIAN C W, LEE K C, et al. Ternary composite based on homogeneous Ni(OH)₂ on graphene with Ag nanoparticles as nanospacers for efficient supercapacitor[J]. Chemical Engineer-ing Journal, 2018, 334:2058-2067.
[15]	ZHANG H, GAO Q, YANG K, et al. Solvothermally induced α-Fe₂O₃/graphene nanocomposites with ultrahigh capacitance and excellent rate capability for supercapacitors[J]. Journal of Materi-als Chemistry A, 2015, 3(44):22005-22011.
[16]	张硕嘉, 杨玉彬, 唐宇, 等. 高活性Fe₂O₃@Ni复合电极制备及电化学性能研究[J]. 无机盐工业, 2019, 51(7):24-27.
[17]	HE T, TU M, ZHANG J, et al. Nanoparticles of iron nitride encaps-ulated in nitrogen-doped carbon bulk derived from polyaniline/Fe₂O₃ blends and its electrochemical performance[J]. Particle & Particle Systems Characterization, 2020, 37(7).Doi: 10.1002/ppsc.202000132. doi: 10.1002/ppsc.202000132
[18]	FU C, MAHADEVEGOWDA A, GRANT P S. Production of hollow and porous Fe₂O₃ from industrial mill scale and its potential for large-scale electrochemical energy storage applications[J]. Journal of Materials Chemistry A, 2016, 4(7):2597-2604. doi: 10.1039/C5TA09141A
[19]	HUANG X, YU H, CHEN J, et al. Ultrahigh rate capabilities of li-thium-ion batteries from 3D ordered hierarchically porous electro-des with entrapped active nanoparticles configuration[J]. Advan-ced Materials, 2014, 26(8):1296-1303.
[20]	CHEN J, XU J, ZHOU S, et al. Template-grown graphene/porous Fe₂O₃ nanocomposite：A high-performance anode material for pseu-docapacitors[J]. Nano Energy, 2015, 15:719-728. doi: 10.1016/j.nanoen.2015.05.021
[21]	FANG K, CHEN J, ZHOU X, et al. Decorating biomass-derived po-rous carbon with Fe₂O₃ ultrathin film for high-performance super-capacitors[J]. Electrochimica Acta, 2018, 261:198-205. doi: 10.1016/j.electacta.2017.12.140
[22]	ZHAO P, WANG N, HU W, et al. Anode electrodeposition of 3D mesoporous Fe₂O₃ nanosheets on carbon fabric for flexible solid-state asymmetric supercapacitor[J]. Ceramics International, 2019, 45(8):10420-10428. doi: 10.1016/j.ceramint.2019.02.101
[23]	SONG Z, LIU W, WEI W, et al. Preparation and electrochemical properties of Fe₂O₃/reduced graphene oxide aerogel(Fe₂O₃/rGOA) composites for supercapacitors[J]. Journal of Alloys and Compo-unds, 2016, 685:355-363.
[24]	SHAN D, YANG J, LIU W, et al. Biomass-derived three-dimensio-nal honeycomb-like hierarchical structured carbon for ultrahigh energy density asymmetric supercapacitors[J]. Journal of Materi-als Chemistry A, 2016, 4(35):13589-13602.
[25]	LI P, XIE H, WANG X, et al. Sustainable production of nano α-Fe₂O₃/N-doped biochar hybrid nanosheets for supercapacitors[J]. Sustainable Energy & Fuels, 2020, 4(9):4522-4530.
[26]	WANG Y, SHEN C, NIU L, et al. Hydrothermal synjournal of CuCo₂O₄/CuO nanowire arrays and RGO/Fe₂O₃ composites for high-perfor-mance aqueous asymmetric supercapacitors[J]. Journal of Materi-als Chemistry A, 2016, 4(25):9977-9985.
[27]	DONG T, DENG T, CHU X, et al. Carbon intermediate boosted Fe-ZIF derived alpha-Fe₂O₃ as a high-performance negative electrode for supercapacitors[J]. Nanotechnology, 2020, 31(13).Doi: 10.1088/1361-6528/ab5baf. doi: 10.1088/1361-6528/ab5baf
[28]	DESHMUKH P R, SOHN Y, SHIN W G. Electrochemical perfor-mance of facile developed aqueous asymmetric(Fe,Cr)₂O₃//MnO₂ supercapacitor[J]. Electrochimica Acta, 2018, 285:381-392. doi: 10.1016/j.electacta.2018.07.197
[29]	LI Y, KANG L, BAI G, et al. Solvothermal synjournal of Fe₂O₃ loaded activated carbon as electrode materials for high-performance elec-trochemical Capacitors[J]. Electrochimica Acta, 2014, 134:67-75. doi: 10.1016/j.electacta.2014.04.094
[30]	ZHANG S, YIN B, WANG Z, et al. Super long-life all solid-state asymmetric supercapacitor based on NiO nanosheets and α-Fe₂O₃ nanorods[J]. Chemical Engineering Journal, 2016, 306:193-203. doi: 10.1016/j.cej.2016.07.057
[31]	KARTHIKEYAN K, AMARESH S, LEE S N, et al. Fluorine-doped Fe₂O₃ as high energy density electroactive material for hybrid su-percapacitor applications[J]. Chemistry:An Asian Journal, 2014, 9(3):852-857. doi: 10.1002/asia.v9.3

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on high-performance supercapacitors based on Fe₂O₃/biomass carbon composites

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 31

Related Articles 15

Metrics

Comments

Recommended 0

[1]	ZHANG Feigang, LIU Zhongli. Study on application of CuO/g-C₃N₄ composites in organic dye degradation and supercapacitors [J]. Inorganic Chemicals Industry, 2025, 57(1): 129-136.
[2]	WU Qingqing, XU Xuetang, WANG Fan. Study on capacitor performance of high⁃mass⁃loading ZnCo-based carbonate hydroxide electrode materials [J]. Inorganic Chemicals Industry, 2024, 56(7): 46-54.
[3]	ZHOU Xuan, LI Mengrui, CHEN Yichen, FAN Huiqiang, WANG Bin, YUAN Gang. Research progress of nickel-based phosphide composites in improving of catalytic water electrolysis for hydrogen evolution performance [J]. Inorganic Chemicals Industry, 2024, 56(4): 8-15.
[4]	YAN Zhen, QIU Zhaofu, JIN Xibiao, WANG Yuan, LIU Chang, YANG Ji. Study on 4A molecular sieve loaded with Ce and γ-Fe₂O₃ for removal of Sb（Ⅲ） and Sb（Ⅴ） in water [J]. Inorganic Chemicals Industry, 2024, 56(1): 81-89.
[5]	YAN Chaoqun, ZHANG Xianming, WEI Juan, CHENG Zhiliang, XU Qian, ZHANG Xuan. Synthesis of cubic α-Fe₂O₃ catalyst and its photo-Fenton degradation performance of antibiotic under visible light [J]. Inorganic Chemicals Industry, 2023, 55(8): 28-35.
[6]	WANG Jianfang, YANG Heping, LI Kaibin, CONG Shiqiang, ZHANG Bojie, GUO Shan. Study on preparation of C₃N₄/MnCo₂S₄ composites and their capacitive properties [J]. Inorganic Chemicals Industry, 2023, 55(7): 70-74.
[7]	XU Xuetang, WANG Xukai, ZHANG Shenhe, HUANG Meixiang, NONG Shuliu, XU Nuo. Study on preparation and properties of vanadate doped NiCo-LDH electrode [J]. Inorganic Chemicals Industry, 2023, 55(5): 52-58.
[8]	LAN Yinghua, CHEN Yanmei, MA Ruixiao, ZHANG Yanhui. Preparation and photocatalytic performance of Ce-Ti oxide-attapulgite composites [J]. Inorganic Chemicals Industry, 2023, 55(4): 133-140.
[9]	ZHANG Yanru, REN Changzai, SONG Zhanlong, ZHU Jianjun, ZHAO Baofeng, XIE Hongzhang, WANG Zhenjiang, QI Xiaole. Study on performance of biomass power plant ash as alternative to cement clinker in blended cements [J]. Inorganic Chemicals Industry, 2023, 55(10): 128-135.
[10]	LIU Jinhang,YANG Zhipeng,CHEN Xiudong,LUO Yuxuan,YU Langhua,WANG Yawei,ZHAN Changchao,CAO Xiaohua. Preparation of new porous carbon and its lithium storage performance [J]. Inorganic Chemicals Industry, 2022, 54(9): 85-89.
[11]	JIANG Tiantian,XU Xuetang,WANG Fan. Research on growth and supercapacitance of NiCo based electrode materials regulated by halogen ions [J]. Inorganic Chemicals Industry, 2022, 54(8): 66-73.
[12]	Zhang Tianliang,Li Jun,Xiong Wei,Zhang Haiyan,Tao Xiaoqiu. Study on one-step preparation of activated carbon with high specific surface by K₂CO₃ activation and its capacitance performance [J]. Inorganic Chemicals Industry, 2022, 54(4): 159-164.
[13]	LU Zheng,CHEN Kunfeng,XUE Dongfeng. Study on large-scale preparation and electrochemical properties of high thermal stabilized α-Fe₂O₃ [J]. Inorganic Chemicals Industry, 2022, 54(3): 45-50.
[14]	LIANG Qunfang,XU Xuetang,WANG Fan. Study on improvement of capacitance performance of NiMn-LDH electrode material by anions exchange [J]. Inorganic Chemicals Industry, 2022, 54(2): 38-44.
[15]	ZHAO Zhichao,WANG Honglin,WANG Xia,SUN Gang,ZHAO Cuilian,SUN Nannan. Controllable preparation of NiMoO₄ nanosheets-based microspheres by hydrothermal method and their supercapacitor properties [J]. Inorganic Chemicals Industry, 2022, 54(2): 60-64.

Study on high-performance supercapacitors based on Fe2O3/biomass carbon composites