INORGANICCHEMICALSINDUSTRY ›› 2014, Vol. 46 ›› Issue (2): 74-.

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Microwave-assisted hydrothermal synthesis of SAPO-11 molecular sieves

 WANG   Qiong   

  1. Refining and Sales Department,China National Offshore Oil Corporation,Beijing 100010,China
  • Online:2014-02-10 Published:2014-01-24

Abstract: The pure SAPO-11 molecular sieves were synthesized by microwave-assisted method and with pseudo-boehmite and silica gel etc. as raw materials.The method greatly reduced the crystallization time and saved the cost of synthesis.The prepared samples were characterized by powder X-ray diffraction and scanning electron microscopy.The influences of silica source,structure-directing agent,the ratio of silica to alumina and the crystallization conditions(such as time,temperature, and pH) on the synthesis of pure SAPO-11 have been investigated in detail.The results indicated that the influences of pH and crystallization time were significant.The pure phase SAPO-11 molecular sieves were efficiently synthesized via microwave-assisted method using silica gel as silicon source,and di-n-propylamine as template agent under the conditions of crystallization temperature of 185 ℃,crystallization time of 10 h,pH=5.7,and n(SiO2)∶n(Al2O3)=0.6.

Key words: microwave assistance, hydrothermal synthesis, SAPO-11, molecular sieves

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