无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2025, Vol. 57 ›› Issue (6): 64-69.doi: 10.19964/j.issn.1006-4990.2024-0148

• 研究与开发 • 上一篇    下一篇

氯化铯化学法狼毒活性炭的制备研究

党世民(), 郭建霞, 李海朝()   

  1. 青海民族大学青海省应用物理化学重点实验室,青海 西宁 810007
  • 收稿日期:2024-03-14 出版日期:2025-06-10 发布日期:2025-06-25
  • 通讯作者: 李海朝(1973— ),男,博士,教授;E-mail:lihaichao@vip.163.com
  • 作者简介:党世民(2000— ),男,硕士,主要研究方向为材料与化工;E-mail:1612070239@qq.com
  • 基金资助:
    青海省重点研发与转化计划项目(2022-QY-210)

Study on preparation of activated carbon of Stellera chamaejasme Linn by cesium chloride chemical method

DANG Shimin(), GUO Jianxia, LI Haichao()   

  1. Key Laboratory of Applied Physical Chemistry of Qinghai Province,Qinghai Minzu University,Xining 810007,China
  • Received:2024-03-14 Published:2025-06-10 Online:2025-06-25

摘要:

为了提升瑞香狼毒的工业应用价值,拓展盐湖铯盐资源的利用空间,以氯化铯为活化剂,采用化学活化法活化瑞香狼毒,制备了孔径均一的狼毒活性炭。实验采用碘和亚甲基蓝作为吸附质,测试狼毒活性炭的吸附性能;通过全自动比表面积分析仪(BET)、X射线衍射仪(XRD)、拉曼光谱仪(Ranman)、扫描电镜(SEM)、傅里叶红外光谱仪(FT-IR)、X射线光电子能谱仪(XPS)对狼毒活性炭的比表面积、表面形貌、表面官能团及孔隙结构进行检测。实验结果表明:所制备的狼毒活性炭是一种无定形活性炭;该活性炭的表面官能团以含碳、含氧类官能团为主,活性炭的比表面积达到549.42 m2/g,碘的吸附量达到530.4 mg/g,亚甲基蓝的吸附量达到133.7 mg/g,优势孔径为1.01 nm,孔容为0.25 cm3/g,是一种微孔活性炭,炭得率为17.71%。该研究为青海狼毒资源与盐湖铯盐资源的利用提供了一定的理论基础。

关键词: 瑞香狼毒, 氯化铯, 微孔活性炭, 活化剂

Abstract:

In order to enhance the industrial application value of Stellera chamaejasme Linn and expand the utilisation space of cesium salt resources in the salt lake,Stellera chamaejasme Linn was activated with cesium chloride as the activator and chemical activation method was used to prepare Stellera chamaejasme Linn activated carbon with uniform pore size.Iodine and methylene blue were used as adsorbents to test the adsorption performance of activated carbon.The experiments were carried out by fully automated specific surface area analyser(BET),X-ray diffractometer(XRD),Raman spectrometer,scanning electron microscope(SEM),Fourier-transform infrared spectroscopy(FT-IR),and X-ray electron spectroscopy(XPS) to examine the specific surface area of the activated carbon,the surface morphology,the surface functional groups and the pore structure.The test results showed that the wolfsbane activated carbon prepared in this study was an amorphous activated carbon.The surface functional groups of the activated carbon were mainly carbon-containing and oxygen-containing functional groups.The specific surface area of this activated carbon was 549.42 m2/g,the iodine adsorption value was 530.4 mg/g,the methylene blue adsorption value was 133.7 mg/g,and the predominant pore size was 1.01 nm,and the pore volume was 0.25 cm3/g,and it was microporous activated carbon,and the carbon yield was 17.71%.This study provided a theoretical basis for the utilisation of Stellera chamaejasme Linn resources and cesium salt resources in Qinghai.

Key words: Stellera chamaejasme Linn, cesium chloride, microporous activated carbon, activator

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