无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (12): 89-.

• 论文 • 上一篇    

高纯硅溶胶制备及在加氢精制催化剂中的应用

周靖辉,胡 毅,于海斌,孙彦民,刘 峰,季 超   

  1. 中海油天津化工研究设计院有限公司,天津 300131
  • 出版日期:2016-12-10 发布日期:2016-12-08

Preparation of high purity silica sol and its application in hydrofining catalyst

 ZHOU  Jing-Hui, HU   Yi, YU  Hai-Bin, SUN  Yan-Min, LIU   Feng, JI   Chao   

  1. CenerTech Tianjin Chemical Research and Design Institute Co.,Ltd.,Tianjin 300131,China
  • Published:2016-12-10 Online:2016-12-08

摘要: 以市售硅溶胶为晶种,水玻璃为原料,采用离子交换及络合除杂等方法,制备了粒径为20~24 nm、质量分数为40%的高纯硅溶胶。分析了硅溶胶制备过程中的主要影响因素,即晶种浓度、反应过程pH、除杂过程络合剂选型。通过透射电镜(TEM)、纳米激光粒度仪、比表面积测试(BET)等方法对制备的高纯硅溶胶进行了分析。实验结果证明了该制备工艺的可行性。测试了制备的高纯硅溶胶在加氢精制催化剂中的应用效果。

关键词: 水玻璃, 硅溶胶, 晶种浓度, 反应pH

Abstract: With commercially available silica sol as the crystal seed and sodium silicate as raw material,a high-purity silica sol with 20~24 nm in particle size and with 40% in mass fraction was prepared by ion exchange and complexing purification method.The main influencing factors,such as seed concentration,reaction pH,and impurity removal,in the preparation pro- cess of silica sol were analyzed.The prepared product was analyzed by transmission electron microscope(TEM),nano zetasizer, and BET.The experimental results proved the feasibility of the process,and their application effect in hydrofining catalysts was also tested.

Key words: sodium silicate, silica sol, seed concentration, reaction pH

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