无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (12): 27-.

• 论文 • 上一篇    下一篇

菱镁矿混合氯化镁焙烧制备高纯氧化镁

张晨洋,陈建铭,宋云华   

  1. 教育部超重力工程研究中心,北京化工大学,北京 100029
  • 出版日期:2016-12-10 发布日期:2016-12-08

Preparation of high purity magnesia from calcining magnesite mixed magnesium chloride

 ZHANG  Chen-Yang, CHEN  Jian-Ming, SONG  Yun-Hua   

  1. Research Center of the Ministry of Education for High Gravity Engineering and Technology,
    Beijing University of Chemical Technology,Beijing 100029,China
  • Published:2016-12-10 Online:2016-12-08

摘要: 采用菱镁矿添加无水氯化镁混合焙烧的方式,在较低焙烧温度下制备了高纯度的氧化镁。通过热重-差热(TG-DTA)法分析了菱镁矿的焙烧反应过程,并对焙烧产品进行了X射线衍射(XRD)、扫描电镜(SEM)及纯度分析。与传统焙烧方法制备氧化镁相比,添加氯化镁的焙烧工艺可有效地达到除钙效果。通过机理探讨表明,氯化镁渗透到菱镁矿中起隔断作用,有效增加了菱镁矿的比表面积,降低了焙烧温度,达到了节能降耗的效果。在焙烧温度为650 ℃、保温时间为1 h条件下,所得氧化镁的纯度可达99.3%,钙杂质质量分数可降至0.07%。

关键词: 氯化镁, 节能降耗, 高纯氧化镁, 菱镁矿

Abstract: High-purity magnesium oxide was prepared by calcining magnesite which mixed with anhydrous magnesium chlo- ride at a lower calcination temperature.The thermal decomposition of mixed powders was analyzed by thermogravimetric anal- ysis and dynamic thermogravimetric analysis(TG-DTA).The prepared product was also characterized by X-ray diffraction (XRD),scanning electronic microscope(SEM),and purity analysis.Compared with the traditional method,the results showed that adding magnesium chloride can effectively remove calcium.Through mechanism discussion,because of chloride ion′s penetration,magnesium chloride played a role of partition to magnesite,it made magnesite′s specific surface area increase and calcination temperature decrease,which got the effect of energy-saving and cost-reducing.The product′s purity could reach 99.3% and calcium impurity mass fraction reduced to 0.07%,when calcination temperature was 650 ℃ and calcination time was 1 h.

Key words: magnesium chloride, energy-saving and cost-reducing, high-purity magnesium oxide, magnesite

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