无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (11): 52-.

• 论文 • 上一篇    下一篇

负载氧化镧泡沫玻璃脱除水中氟离子

胡 东1,李 坤1,孙富兴2,陈俊律2   

  1. 1.常州大学功能材料实验室,江苏常州 213164;2.江阴市晶瑞特环保材料有限公司
  • 出版日期:2016-11-10 发布日期:2016-11-28

Removal of fluoride from water by lanthanum oxide loaded foam glass

Hu Dong1,Li Kun1,Sun Fuxing2,Chen Junlü2   

  1. 1.Functional Material Laboratory,Changzhou University,Changzhou 213164,China;
    2.Jiangyin Jingruite Environment Protection New Materials Co.,Ltd.
  • Published:2016-11-10 Online:2016-11-28

摘要: 饮用水中过量的氟会对人体造成危害,因此发展成本低、高效率除氟材料对于高氟地区饮用水安全和含氟废水处理很有必要。以泡沫玻璃为载体,采用浸渍法制备了泡沫玻璃负载氧化镧的复合材料。对复合材料组成、表面形貌、镧的溶出率和除氟效果做了表征。结果表明:负载氧化镧7%(质量分数)的泡沫玻璃除氟效果最佳,用100 g的该材料就可以将600 mL废水中的氟离子质量浓度从32 mg/L降至1 mg/L以下,达到了饮用水标准。使用过的复合材料通过草酸溶液处理,于600 ℃下热解,可以使复合材料再生。

关键词: 泡沫玻璃, 氧化镧, 浸渍法, 除氟

Abstract: Excessive fluoride in drinking water can cause harm to human body.It is necessary to develop low-cost and high efficiency fluoride removal material for drinking water safety.The La(Ⅲ)-loaded foam glass composite was prepared by dip- molding method with foam glass as a carrier.The composition,surface morphology,dissolution rate of lanthanum,and the effect of fluoride removal of the composite material were characterized.Results showed that the best load was 7%(mass frac- tion) lanthanum oxide.The fluoride content of 600 mL waste water could be decreased from 32 mg/L down to 1 mg/L below via 100 g La(Ⅲ)-loaded foam glass composite,which reached the standard for drinking water.After fluoride removal,composite material can be regenerated by the oxalic acid solution treatment and pyrolysis at 600 ℃.

Key words: foam glass, lanthanum oxide, dip-molding, fluoride removal

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