无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (7): 55-.

• 论文 • 上一篇    下一篇

内蒙古油砂尾砂制备水玻璃的工艺研究

吴 杨1,李文深1,张书宇2,李晓鸥1,李东胜1,刘 洁1   

  1. 1.辽宁石油化工大学,辽宁抚顺 113001;2.中国石油抚顺石化公司石油二厂
  • 出版日期:2015-07-10 发布日期:2015-09-24

Study on preparation of sodium silicate by Inner Mongolia oil sand tailings

Wu Yang1,Li Wenshen1,Zhang Shuyu2,Li Xiaoou1,Li Dongsheng1,Liu Jie1   

  1. 1.Liaoning Shihua University,Fushun 113001,China;2.Refinery No.2 of Fushun Petrochemical Company,CNPC
  • Published:2015-07-10 Online:2015-09-24

摘要: 内蒙古油砂尾砂中硅含量以二氧化硅计质量分数接近85%。探索了以内蒙古油砂尾砂中二氧化硅为原料在低温下制备水玻璃的工艺路线。通过单因素实验及正交实验考察得出,3个因素对水玻璃模数(硅钠物质的量 比)及二氧化硅溶出率的影响程度均为温度>物料比(钠硅物质的量比)>时间。以水玻璃模数为考察指标,其最佳工艺条件为:反应温度为800 ℃、反应时间为1 h、物料比为2,得到水玻璃模数为2.764。以二氧化硅溶出率为考察指标,其最佳工艺条件为:反应温度为800 ℃、反应时间为2.5 h、物料比为2,得到二氧化硅溶出率为87.6%。

关键词: 油砂尾砂, 水玻璃, 模数, 二氧化硅溶出率

Abstract: The content of silicon(Si) in Inner Monglia oil sand tailings was close to 85%,that was calculated in the form of silica.The process of preparation for sodium silicate by using the silica in the Inner Mongolia oil sands as the raw material under low temperature was designed.Through single factor and orthogonal experiment,the degree of influences of technological conditions on modules of soluble silicate and deliquescent rate of SiO2 was in order of reaction temperature>material mix ratio (amount?鄄of?鄄substance ratio of Na to Si)>reaction time.With modules of soluble silicate as the detecting indexes,the optimal conditions were as follows:the reaction temperature was 800℃,the reaction time was 1 h,and the material mix ratio was 2. Under the optimal conditions,the module of sodium silicate was 2.764.With deliquescent rate of SiO2 as the detecting indexes,the optimal conditions were as follows:  the reaction temperature was 800 ℃,the reaction time was 2.5 h,and the material mix ratio was 2.Under the optimal conditions,the deliquescent rate of SiO2 was 87.6%.

Key words: oil sand tailings, sodium silicate, module, deliquescent rate of SiO2

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