无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (9): 37-.

• 论文 • 上一篇    下一篇

钛白粉生产工艺优化与设备改进

刘 宏1,陈文娟1,戴建军2   

  1. 1.湖南化工职业技术学院,湖南株洲 412004;2.中盐湖南株洲化工集团有限责任公司
  • 出版日期:2013-09-10 发布日期:2013-09-13

Process optimization and equipment renovation of titanium dioxide

Liu Hong1,Chen Wenjuan1, Dai Jianjun2   

  1. 1.Hunan Chemical Vocational Technology College,Zhuzhou 412004,China;
    2.Hunan Zhuzhou Chemical Industry Group Co.,Ltd., CNSIC
  • Published:2013-09-10 Online:2013-09-13

摘要: 某公司1.5万t/a硫酸法钛白粉生产工艺存在“三废”排放量大、能耗高、生产成本居高不下等问题。针对以上问题对钛白粉生产工艺进行了优化,对设备进行了改造,主要包括酸解反应过程、煅烧尾气处理过程以及转窑系统等,最大程度地降低了钛白粉的生产成本。实践结果表明:将废酸回用于酸解反应,可将酸解率提高并稳定在95%以上,每吨钛白粉硫酸消耗从4.52 t下降到4.25 t;将偏钛酸二次洗水用作煅烧尾气喷淋水再回用到偏钛酸一次洗水,每年可节约蒸汽5.9×103 t;改造转窑系统,提高了燃烧效率,每吨钛白粉煤气消耗从780 m3降至533 m3。通过以上工艺优化和设备改进,累计可降低钛白粉生产成本912.8元/t。

关键词: 钛白粉, 节能降耗, 工艺优化, 设备改造

Abstract: There are many problems,such as serious ‘three wastes’,high energy consumption,and high cost,in a company′s titanium dioxide production process by the sulfuric acid method with annual output of 15 000 t.By means of process optimization and equipment renovation,the titanium dioxide production cost has been greatly reduced from the acidolysis process,calcination off-gas treatment process,and the rotary furnace system etc..It has been demonstrated that the acidolysis ratio rate was improved and stabilized more than 95%,while the waste acid was reclaimed to the acidolysis reaction, and the acid consumption for producing 1 t TiO2 reduced from 4.52 t to 4.25 t;5.9×103 t vapor could be saved every year,while the secondary washing water of metatitanic acid was used as spray water for off-gas in calcination process,and then returned to the primary water washing process;the rotary furnace system was rebuilt to increase combustion efficiency,and the consumption of coal gas for producing 1 t TiO2 was sharply reduced from 780 m3 to 533 m3.The above measurements brought a total titanium dioxide production cost reduction of  ¥ 912.8 per ton on an accumulative basis.

Key words: titanium dioxide, energy-saving and emission-reduction, technology optimization, equipment renovation

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