无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (9): 31-.

• 论文 • 上一篇    下一篇

钛渣连续酸解工艺技术研究

税必刚,马维平,程晓哲,杜剑桥,任亚平   

  1. 攀钢集团研究院有限公司,钒钛资源综合利用国家重点实验室,四川攀枝花 617000
  • 出版日期:2013-09-10 发布日期:2013-09-13

Study on continuous acidolysis technology of titanium slag

 SHUI  Bi-Gang, MA  Wei-Ping, CHENG  Xiao-Zhe, DU  Jian-Qiao, REN  Ya-Ping   

  1. State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization,Pangang Group
    Research Institute Co.,Ltd.,Panzhihua 617000,China
  • Published:2013-09-10 Online:2013-09-13

摘要: 用钛渣代替钛铁矿生产钛白粉,可以有效降低硫酸消耗,杜绝绿矾产生,是硫酸法钛白产业清洁生产的发展趋势。但是由于钛渣中强放热性物质(如氧化铁等)很少,因此酸解反应不可能像钛铁矿一样依赖反应生成热维持反应连续进行,需要补充一定的热量。通过对钛渣连续酸解热量分析,自主开发了一套实验室钛渣连续酸解装置。实验结果表明,该装置对钛渣连续酸解热量补充是可行的,解决了钛渣连续酸解热量不足的问题;掌握了浆料预热温度、熟化时间、酸料比、反应酸浓度等钛渣连续酸解的关键工艺操作参数,钛渣连续酸解成套工艺运行稳定;钛渣连续酸解其酸解率较间歇式酸解提高2%以上,降低了钛白粉的生产能耗,而且酸解得到的钛液质量稳定可控。

关键词: 钛渣, 钛铁矿, 连续酸解, 钛白粉

Abstract: The technology,which uses titanium slag to replace ilmenite for the production of titanium dioxide can effectively reduce consumption of sulfuric acid,and especially can prevent the generation of copperas.It is the development trend of clean production of titanium dioxide industry with sulfuric acid process.However,due to lack of the strongly exothermal materials(such as Fe2O3) in the slag,the acidolysis reaction will need to supplement some heat to maintain it go on continuously like ilmenite.A set of laboratory continuous acidolysis device was independently developed by heat analysis of slag′s continuous acidolysis.Experimental results showed the titanium slag continuous acidolysis could be heated and the problem of insufficient heat was solved;the key process parameters,such as the slurry preheating temperature,aging time,acid-material ratio,and reaction acid concentrations etc.were mastered,and the device worked very steadily;continuous acidolysis rate compared with intermittent acid solution was improved by more than 2%.Furthermore,energy consumption in the production of titanium dioxide was saved,and the quality of titanium liquid of continuous acidolysis was stable and controllable.

Key words: titanium slag, ilmenite , continuous acidolysis, titanium dioxide

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