无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (7): 56-.

• 论文 • 上一篇    下一篇

卤化亚铜的制备及催化应用研究进展

张霞艳,刘定华,刘晓勤   

  1. 南京工业大学化学化工学院,材料化学工程国家重点实验室,江苏南京 210009
  • 发布日期:2012-07-11

Research progress in preparation and catalytic application of cuprous halide

 ZHANG  Xia-Yan, LIU  Ding-Hua, LIU  Xiao-Qin-   

  1. State Key Laboratory of Materials-Oriented Chemical Engineering,School of Chemistry and Chemical Engineering,
    Nanjing University of Technology,Nanjing 210009,China
  • Online:2012-07-11

摘要: 综述了卤化亚铜 (CuX) 无机材料的制备工艺研究新进展,讨论了制备的具体工艺,为卤化亚铜绿色制备工艺的进一步研究、开发与工业化提供可行性依据。同时,就卤化亚铜催化合成应用从氧化羰基化反应、自由基加成反应、甲氧基化反应及交叉偶联反应方向进行了归纳介绍与讨论。

关键词: 卤化亚铜, 水热还原法, 催化合成

Abstract: Research progress in preparation methods of cuprous halide(CuX) inorganic materials was summarized,and the specific processes of preparation were discussed.This work offered feasible basis for the further research,development,and industrialization of green preparation technology of CuX.Meanwhile,introduction and discussion about the application of CuX in catalytic synthesis were made from the directions of oxidative carbonylation,radical addition, methoxylation,and cross-coupling reactions.

Key words: cuprous halide, hydrothermal reduction method, catalytic synthesis

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