Fe3+协同Ni基金属-有机框架提升电催化析氧反应活性的研究

doi:10.19964/j.issn.1006-4990.2023-0287

Abstract

Abstract:

The metal-organic framework materials（phen-Ni） were synthesized by solvothermal method，and then Fe@phen-Ni electrocatalys were prepared by doping heterometallic Fe³⁺.The morphology，crystal structure and chemical composition of Fe@phen-Ni were characterized by X-ray single crystal diffractometer，scanning electron microscope（SEM），transmission electron microscope（TEM） and X-ray photoelectron spectrometer（XPS）.The electrochemical oxygen evolution reaction（OER） activity of Fe@phen-Ni was investigated by linear sweep voltammetry（LSV） and electrochemical impedance spectroscopy（EIS）.The results exhibited that Fe@phen-Ni had more excellent electrocatalytic performance with an overpotential of 333 mV at the current density of 10 mA/cm² when compared with that of phen-Ni.The improvement could be attributed to the two factors.The introduction of Fe³⁺ increased the active site of the electrocatalyst.The synergistic action of Fe³⁺ and Ni²⁺ promoted the electron transfer.This work not only confirmed that doping of Fe³⁺ was beneficial to improve the electrocatalytic oxygen-evolution activity，but also provided a new idea for the preparation of electrocatalytic OER catalysts based on metal-organic frame materials.

Key words: metal-organic frameworks, electrocatalysis, oxygen evolution reaction, nonprecious metal electrocatalyst

CLC Number:

TQ426

CHEN Xingliang, FAN Wenjuan, CHANG Hui, HUANG Haiping, JIANG Zhiqiang. Study on collaborative strategy between Fe³⁺ and Ni-based metal-organic frameworks for boosting electrocatalytic oxygen evolution[J]. Inorganic Chemicals Industry, 2024, 56(2): 152-158.

Figures/Tables 9

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References 23

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化合物	化学式		相对分子质量	测试温度/℃	晶系	空间群	a/Å
phen-Ni	C₂₆H₁₇NiN₂O_5.5		504.35	23.29	单斜晶系	P2₁/n	7.616
化合物	b/Å	c/Å	α/（º）	β/（º）	γ/（º）	晶胞体积/（Å³）	单位晶胞中所含分子个数
phen-Ni	19.370	15.222	90	97.407	90	2 532.0	4
化合物	单胞中电子的数目	单胞密度/（g∙cm^-3）	吸收系数/ （mm^-1）	收集衍射点	独立衍射点	等效衍射点的等效性	基于F²的GOOF值
phen-Ni	648	1.508	0.82	11 323	4 366	0.040	1.08

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Study on collaborative strategy between Fe³⁺ and Ni-based metal-organic frameworks for boosting electrocatalytic oxygen evolution

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Study on collaborative strategy between Fe3+ and Ni-based metal-organic frameworks for boosting electrocatalytic oxygen evolution