多孔碳基非贵金属氧还原电催化剂研究进展

doi:10.19964/j.issn.1006-4990.2023-0038

Abstract

Abstract:

The application of electrocatalysts for oxygen reduction reaction in energy storage and conversion has attracted extensive attention.However，the large-scale application of platinum-based catalysts is limited by their high cost，scarce resources and poor stability.Carbon-based non noble metal catalysts are expected to be a substitute for platinum-based catalysts due to their low price，excellent reactivity and strong methanol penetration resistance.At present，the improvement of the oxygen reduction activity of carbon-based catalysts reported in the literature was regulating the electronic structure of active sites，increasing the density and accessibility of active sites，and regulating the interface structure of carbon/metal composites.The research progress of carbon-based oxygen reduction catalysts was reviewed from the following three aspects：nonmetallic elements doped carbon-based catalysts，carbon-based non noble metal single-atom catalysts and carbon-based non noble metal nanoparticles catalysts.The problems and challenges faced by carbon-based catalysts were summarized and pointed out，and the development prospects of the catalyst were prospected.

Key words: oxygen reduction, carbon materials, single-atom, doping, nanoparticles

CLC Number:

O643.36

WU Luming, YU Haibin, WANG Yaquan. Research progress of porous carbon-based non noble metal electrocatalysts for oxygen reduction[J]. Inorganic Chemicals Industry, 2023, 55(10): 13-23.

Figures/Tables 6

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Table 1

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催化剂类型	催化剂	电解液	E_1/2/ （V vs.RHE）	塔菲尔斜率/ （mV·dec^-1）	参考文献
非金属元素掺杂碳基催化剂	N-GRW	1 mol/L KOH	0.84	53	［11］
	NPCS-900	0.1 mol/L KOH	0.87	—	［12］
	NPG-1000	0.1 mol/L KOH	0.84	71.2	［14］
	NPS-HC	0.1 mol/L KOH	0.862	57	［16］
	NCN-1000-5	0.1 mol/L KOH	0.82	86	［46］
	N-doped CDs	0.1 mol/L KOH	0.78	60.9	［47］
	Me-CFZ-900	0.1 mol/L KOH	0.86	—	［48］
	NGS4-900	0.1 mol/L KOH	0.859	72	［49］
	N-G-1000	0.1 mol/L KOH	0.862	—	［50］
	NFLGDY-900c	0.1 mol/L KOH	0.87	60.0	［51］
碳基非贵金属单原子催化剂	Fe/N/C-HP	0.1 mol/L KOH	0.90	57.5	［24］
	FeN _x /NC-S	0.1 mol/L KOH	0.92	61.3	［25］
	Cu-SAs/N-C	0.1 mol/L KOH	0.895	63	［26］
	MnNC-700	0.1 mol/L KOH	0.87	—	［29］
	Zn-NC	0.1 mol/L KOH	0.86	97.8	［30］
	（Fe，Co）/CNT	0.1 mol/L KOH	0.954	—	［31］
	Ni-N₄/GHSs/Fe-N₄	0.1 mol/L KOH	0.83	55	［33］
	Fe-N-Si-CNFs	0.1 mol/L KOH	0.86	65	［52］
	NR-CNT@FeNPC-800	0.1 mol/L KOH	0.88	51	［53］
	MoSACs/N-C	0.1 mol/L KOH	0.83	—	［54］
	Fe/PNC@HCF	0.1 mol/L KOH	0.93	77.5	［55］
	Cu-SAs@N-CNS	0.1 mol/L KOH	0.91	62.47	［56］
	Fe，CoSAs-PNCF	0.1 mol/L KOH	0.93	77	［57］
	GO-Fe-N	0.1 mol/L KOH	0.87	66.2	［58］
碳基非贵金属纳米颗粒催化剂	Fe-bNCNT/NC-900	0.1 mol/L KOH	0.884	57	［59］
	Co@NCNTs-800	0.1 mol/L KOH	0.88	63	［37］
	N-Co@C/CNT	0.1 mol/L KOH	0.83	75.2	［38］
	CoNC_-1NaCl_-800	0.1 mol/L KOH	0.84	—	［60］
	Co@N-C（DM）	0.1 mol/L KOH	0.83	—	［39］
	Fe₃C/C-800	0.1 mol/L KOH	0.83	—	［40］
	Fe₃C@MHNFs	0.1 mol/L KOH	0.90	—	［42］
	3D-FePDC	0.1 mol/L KOH	0.84	81	［43］
	FeS/Fe₃C@N-S-C-800	0.1 mol/L KOH	0.87	—	［61］
	PFeC-900	0.1 mol/L KOH	0.88	53	［44］
	FeP@PGL	0.1 mol/L KOH	0.90	64	［45］
	Co@G/N-GCNs	0.1 mol/L KOH	0.86	69.66	［62］

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Research progress of porous carbon-based non noble metal electrocatalysts for oxygen reduction

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