基于正交试验的泡沫脱硫石膏基复合材料性能研究

doi:10.19964/j.issn.1006-4990.2022-0363

Abstract

Abstract:

In order to understand the order of the effect of admixtures on the properties of foamed desulfurized gypsum materials，the desulfurized building gypsum was mixed with composite portland cement，granulated blast furnace slag powder and microsilica powder based on the method of orthogonal test.The foamed desulfurized gypsum-based composite cementitious material was prepared by the method of physical foaming，the physical and mechanical properties of the hardened body of the foamed desulfurized gypsum-based composite material were studied，and the influence factors were judged by combining the range and variance analysis..The results showed that the micro-silica powder was an important factor affecting the strength，water absorption and dry density，while the granulated blast furnace slag powder mainly affected the softening coefficient.Combined with the actual application requirements of the project，the optimal test scheme of foamed desulfurization gypsum-based composites was A₂B₁C₂ through range and variance analysis.The content of composite Portland cement was 12%，the content of slag powder was 10%，and the content of microsilica powder was 10%.

Key words: desulfurized gypsum, cement, slag powder, microsilica powder, orthogonal test

CLC Number:

TQ050.43

MURZATAEV Asan, XIAO Shihao, FU Rusong, AN Hongfang, KONG Dewen, WANG Lingling. Study on performance of foam desulfurization gypsum-based composites based on orthogonal tests[J]. Inorganic Chemicals Industry, 2023, 55(4): 92-96.

Figures/Tables 11

Table 1

Table 2

Table 3

Fig.1

Table 4

Fig.2

Table 5

Fig.3

Table 6

Table 7

Table 8

References 16

1	ZHUO Yuqun， XU Xuchang， ZHANG Hu，et al.The development of pollution control technology in coal combustion in China[J].Frontiers of Energy and Power Engineering in China，2007，1（1）：9-15.
2	XIE Haiwei， ZHANG Yan.The research status of acid rain[J].Advanced Materials Research，2013，726-731：4033-4036.
3	刘睿劼，张智慧.中国工业二氧化硫排放趋势及影响因素研究[J].环境污染与防治，2012，34（10）：100-104.
	LIU Ruijie， ZHANG Zhihui.Study on the emission trend and influencing factors of industrial sulfur dioxide in China[J].Environmental Pollution & Control，2012，34（10）：100-104.
4	贾立军，刘炳光.我国烟气脱硫技术综述[J].盐业与化工，2006，35（5）：35-39.
	JIA Lijun， LIU Bingguang.Review of the technology of sulfur elimination in smoke gas in China[J].Journal of Salt and Chemical Industry，2006，35（5）：35-39.
5	国家统计局.中华人民共和国2021年国民经济和社会发展统计公报[1]：2022年2月28日[N].人民日报，2022-03- 01（10）.
6	TELESCA A， MARROCCOLI M， CALABRESE D，et al.Flue gas desulfurization gypsum and coal fly ash as basic components of prefabricated building materials[J].Waste Management，2013，33（3）：628-633.
7	李和笙.气硬性无机胶凝材料：石灰和石膏[J].建筑工人，2002，23（8）：32-33.
	LI Hesheng.Pneumatic inorganic cementing materials-lime and gypsum[J].Builders' Monthly，2002，23（8）：32-33.
8	卢兰萍，李阳，王稷良，等.脱硫石膏综合利用的现状与分析[J].粉煤灰综合利用，2019，32（3）：95-98.
	LU Lanping， LI Yang， WANG Jiliang，et al.Research status and analysis on comprehensive utilization of desulfurization gypsum[J].Fly Ash Comprehensive Utilization，2019，32（3）：95-98.
9	王松，王家伟，赵平源，等.水泥掺量对磷石膏免烧砖性能的影响[J].非金属矿，2021，44（6）：19-22.
	WANG Song， WANG Jiawei， ZHAO Pingyuan，et al.Effect of cement content on the properties of phosphogypsum unfired brick[J].Non-Metallic Mines，2021，44（6）：19-22.
10	付建.硅酸盐水泥对建筑石膏强度和耐水性的影响[J].非金属矿，2019，42（5）：39-41.
	FU Jian.Effect of portland cement on strength and water resistance of building gypsum[J].Non-Metallic Mines，2019，42（5）：39-41.
11	何玉鑫，华苏东，瞿县.石膏矿渣绿色材料的研究进展[J].无机盐工业，2014，46（5）：13-15.
	HE Yuxin， HUA Sudong， QU Xian.Research progress of gypsum slag green material[J].Inorganic Chemicals Industry，2014，46（5）：13-15.
12	高育欣，麻鹏飞，程宝军，等.掺和料对磷石膏复合胶凝材料性能影响研究[J].非金属矿，2021，44（2）：102-106.
	GAO Yuxin， MA Pengfei， CHENG Baojun，et al.Investigation on effect of admixture to the performance of phosphogypsum composite binders[J].Non-Metallic Mines，2021，44（2）：102-106.
13	丁向群，刘丹阳，徐晓婉.石膏、硅灰对硅酸盐胶凝材料早期抗压强度的影响[J].硅酸盐通报，2017，36（1）：33-37.
	DING Xiangqun， LIU Danyang， XU Xiaowan.Influence of gypsum and silica fume on early compressive strength of portland cementing material[J].Bulletin of the Chinese Ceramic Society，2017，36（1）：33-37.
14	李静静.硅灰对石膏基自流平砂浆性能的影响研究[J].混凝土与水泥制品，2020（5）：80-82.
	LI Jingjing.Influence of silica fume on properties of gypsum-based self-leveling mortar[J].China Concrete and Cement Products，2020（5）：80-82.
15	ZHANG Linchun， ZHANG Ailian， LI Ke，et al.Research on the pretreatment and mechanical performance of undisturbed phosphogypsum[J].Case Studies in Construction Materials，2020，13.Doi：10.1016/j.cscm.2020.e00400 .
16	赵媛媛，郑柏存，邓最亮，等.发泡脱硫石膏的制备与性能研究[J].新型建筑材料，2019，46（5）：106-109.
	ZHAO Yuanyuan， ZHENG Baicun， DENG Zuiliang，et al.Preparation and properties of foamed desulfurized gypsum[J].New Building Materials，2019，46（5）：106-109.

编号	各指标的试验结果（28 d）
编号	抗压强度/MPa	抗折强度/MPa	吸水率	软化系数	干密度/ （kg∙m^-3）
1	13.54	2.68	0.20	0.49	1 008
2	13.45	4.20	0.17	0.51	972
3	12.21	3.59	0.17	0.46	958
4	15.40	4.60	0.17	0.49	994
5	13.56	3.22	0.19	0.48	1 012
6	13.47	4.78	0.17	0.43	1 033
7	13.29	3.59	0.17	0.52	977
8	15.02	4.25	0.18	0.46	1 025
9	13.69	4.22	0.18	0.47	982

项目	吸水率			软化系数
k₁	0.18	0.18	0.18	0.49	0.5	0.46
k₂	0.18	0.18	0.17	0.47	0.48	0.49
k₃	0.18	0.17	0.18	0.48	0.46	0.49
R	0.004 4	0.007 4	0.011 6	0.02	0.05	0.03

项目		干密度/（kg∙m^-3）
k₁	979.5	993.25	1 022.14
k₂	1 013.24	1 003.39	983.03
k₃	994.91	991.01	982.49
R	33.74	12.38	39.65

方差来源	离差平方和	自由度	均方	F值	显著性
A	2.05	2	1.03	1.93	*
B	1.70	2	0.85	1.60
C	2.36	2	1.18	2.21	**
误差	1.06	2

方差来源	离差平方和	自由度	均方	F值	显著性
A	0.000 67	2	0.000 34	1.00
B	0.003 14	2	0.001 57	4.68	**
C	0.001 66	2	0.000 83	2.48	*
误差	0.000 67	2

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on performance of foam desulfurization gypsum-based composites based on orthogonal tests

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 11

References 16

Related Articles 15

Metrics

Comments

Recommended 0

水平	因素
水平	A水泥掺量/%	B矿渣粉掺量/%	C微硅粉掺量/%
1	10	10	8
2	12	12	10
3	14	14	12

方差来源	离差平方和	自由度	均方	F值	显著性
A	1 711.57	2	855.79	1.02	*
B	261.12	2	130.56	0.16
C	3 102.41	2	1 551.21	1.86	**
误差	122.04	2

[1]	LI Keke, XUE Jiangwei, WANG Luwei, GUAN Xuemao. Effect of MgAl-layered double hydroxides on properties of high-iron low-calcium portland cement [J]. Inorganic Chemicals Industry, 2024, 56(4): 57-63.
[2]	YU Zhou, HE Zhaoyi, TANG Liang, HE Sheng, XIAO Haixin, XIAO Yixun. Study on preparation and microscopic properties of typical sulfate solid waste composite cementitious materials [J]. Inorganic Chemicals Industry, 2024, 56(4): 90-97.
[3]	WANG Ruting, ZHAO Xiaorong, HUANG Xuquan, WANG Haojie, XUE Fei, CAI Jiawei. Research on preparation and early performance of mixed phase phosphogypsum-based cementing materials [J]. Inorganic Chemicals Industry, 2024, 56(3): 98-104.
[4]	XU Li, ZHANG Qiang. Experimental study on properties of iron tailings powder cement-based materials [J]. Inorganic Chemicals Industry, 2023, 55(6): 116-123.
[5]	LI Bo, LIAO Bihai. Preparation of functionalized graphene oxide and its application in portland cement [J]. Inorganic Chemicals Industry, 2023, 55(6): 57-62.
[6]	ZHAO Liping, WANG Fei. Effect of amine-functionalized graphene oxide on mechanical properties of cement composites [J]. Inorganic Chemicals Industry, 2023, 55(3): 66-70.
[7]	LI Peng, WANG Likun, MENG Qiuyan. Study on effect of α-hemihydrate gypsum on performance of cement mortar and its hydration mechanism [J]. Inorganic Chemicals Industry, 2023, 55(3): 98-103.
[8]	DU Changqing, WANG Zhangxuan, TONG Teng, LIU Xiaofan, LIU Liang. Study on dispersion of silica fume/graphene oxide in hardened cement paste [J]. Inorganic Chemicals Industry, 2023, 55(11): 115-120.
[9]	ZHANG Yanru, REN Changzai, SONG Zhanlong, ZHU Jianjun, ZHAO Baofeng, XIE Hongzhang, WANG Zhenjiang, QI Xiaole. Study on performance of biomass power plant ash as alternative to cement clinker in blended cements [J]. Inorganic Chemicals Industry, 2023, 55(10): 128-135.
[10]	YU Meng,LI Xiang,TIE Leilei,LI Zhiyuan,LIU Wenhui,WU Bao,Zheng Yufei. Research and evaluation of silicate composite viscoelastic oil displacement agent [J]. Inorganic Chemicals Industry, 2022, 54(9): 102-107.
[11]	ZHANG Taiyue,XIE Fan,GUO Junyuan. Study on performance optimization and mechanism of phosphogypsum based composite cementitious materials [J]. Inorganic Chemicals Industry, 2022, 54(9): 136-142.
[12]	LEI Ming,ZHU Hanyu,LIU Zilong,CHEN Guopeng,YUAN Junsheng. Distribution and speciation of heavy metals in hardened solid of net slurry co?disposed by cement kiln [J]. Inorganic Chemicals Industry, 2022, 54(8): 107-113.
[13]	ZHOU Yuanzhong,WANG Hongjie,CHEN Hong,FAN Yong,FAN Ling,LI Jie. Experimental study on preparation of cement?based wet?mixed plastering mortar by dihydrate phosphogypsum [J]. Inorganic Chemicals Industry, 2022, 54(8): 114-118.
[14]	FU Rusong,LU Yuexian,AN Hongfang,KONG Dewen,FU Rubin. Study on preparation of cementitious materials from raw phosphogypsum cured by hemihydrate phosphogypsum and their properties [J]. Inorganic Chemicals Industry, 2022, 54(6): 109-114.
[15]	WANG Youyou,YUAN Hao,HAN Qingqing,CHEN Shiying. Activation of activator on fly ash?titanium gypsum?calcium carbide slag system and its hydration mechanism [J]. Inorganic Chemicals Industry, 2022, 54(6): 115-119.