Inorganic Chemicals Industry ›› 2022, Vol. 54 ›› Issue (9): 1-13.doi: 10.19964/j.issn.1006-4990.2022-0235
• Reviews and Special Topics • Next Articles
Received:
2022-05-27
Online:
2022-09-10
Published:
2022-09-22
CLC Number:
WANG Ping. Quantitative analysis of linkage between lithium supply and demand and lithium price[J]. Inorganic Chemicals Industry, 2022, 54(9): 1-13.
Table 1
Composition of brine of major lithium rich salt lakes in the world[2]"
盐湖卤水来源 | m(Mg2+)/ m(Li+) | 主要成分质量分数/% | |||||||
---|---|---|---|---|---|---|---|---|---|
Li+ | Na+ | K+ | B3+ | Mg2+ | Ca2+ | Cl- | SO42- | ||
玻利维亚乌尤尼(Uyuni,Bolivia) | 20.249 | 0.032 | 7.06 | 1.17 | 0.071 | 0.650 | 0.030 6 | 5.00 | — |
智利阿塔卡玛(Atacama,Chile) | 6.146 | 0.157 | 9.10 | 2.36 | 0.040 | 0.965 | 0.045 | 18.95 | 1.59 |
阿根廷翁布雷穆埃尔托(Hombre Muerto,Argentina) | 1.371 | 0.062 | 9.789 | 0.617 | 0.035 | 0.085 | 0.053 | 15.80 | 0.853 |
美国瑟尔斯湖(Searles Lake,USA) | — | 0.005 | 11.08 | 2.53 | — | — | 0.001 6 | 12.30 | 4.61 |
美国银峰(Silver Peak,USA) | 6.667 | 0.006 | 6.20 | 0.80 | — | 0.040 | 0.050 | 10.06 | 0.71 |
以色列死海(Dead Sea,Israel) | 2 575.0 | 0.001 | 3.01 | 0.56 | 0.030 | 3.090 | 1.290 | 16.10 | 0.061 |
中国扎布耶(Zabuye,China) | 0.053 | 0.049 | 7.29 | 1.66 | — | 0.003 | 0.010 6 | 9.53 | — |
中国西台吉乃尔(Taiji'naier,China) | 65.161 | 0.031 | 5.63 | 0.44 | — | 2.020 | 0.020 | 13.42 | 3.41 |
中国一里坪(Yiliping,China) | 60.950 | 0.021 | 2.58 | 0.91 | 0.031 | 1.280 | 0.016 | 14.97 | 2.88 |
中国察尔汗(Qarhan,China) | 1 577.4 | 0.003 | 2.37 | 1.25 | 0.009 | 4.890 | 0.051 | 18.80 | 0.44 |
中国大柴旦(Da Qaidan,China) | 133.75 | 0.016 | 6.92 | 0.71 | 0.062 | 2.140 | — | 14.64 | 4.05 |
Table 2
Chemical composition and physical properties of some high?grade lithium minerals[3]"
矿物名称 | 化学式 | 硬度 | w(Li2O)/% | 密度/(g·cm-3) |
---|---|---|---|---|
锂辉石(spodumene) | LiAlSi2O6 | 5.9~7.6 | 3.1~3.2 | 6~7 |
透锂长石(petalite) | LiAlSi4O10 | 2.0~4.1 | 2.3~2.5 | 6.0~6.5 |
锂霞石(eucryptite) | LiAlSiO4 | 6.1 | 2.6 | 6.5 |
锂云母(lepidolite) | K(Li,Al)3(Si,Al)4O10(F,OH)2 | 3.2~5.7 | 2.8~3.3 | 2~4 |
铁锂云母(zinnwaldite) | K(Li,Fe,Al)3(Si,Al)4O10(F,OH)2 | 2.9~4.5 | 2.9~3.3 | 2~4 |
Table 3
Main chemical composition of different lithium clays at home and abroad[4]"
类型/产地 | 主要化学组成质量分数/% | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Li2O | SiO2 | Al2O3 | Fe2O3 | K2O | Na2O | MgO | CaO | TiO2 | P2O5 | |
河南含锂黏土矿 | 0.50 | 37.88 | 43.50 | 1.49 | 2.13 | 0.82 | 0.41 | 0.42 | 2.38 | 0.13 |
贵州含锂铝质岩 | 0.09 | 25.33 | 51.27 | 2.61 | 0.06 | — | 0.59 | 0.14 | 2.31 | 0.48 |
碳酸盐型锂矿 | 0.68 | 33.06 | 48.01 | 1.07 | 3.88 | 0.09 | 0.46 | 0.03 | 2.25 | 0.12 |
McDermitt黏土 | 1.29 | 53.00 | 5.86 | 3.57 | 4.46 | 0.78 | 15.00 | 2.25 | — | — |
McDermitt A | 0.77 | 53.05 | 2.83 | 0.76 | 0.20 | 0.80 | 20.00 | 1.58 | — | — |
McDermitt B | 1.37 | 53.48 | 7.56 | 2.71 | 5.66 | 0.24 | 12.83 | 1.82 | — | — |
尼日利亚黏土 | 0.58 | 51.60 | 43.20 | 1.06 | 0.24 | 0.87 | — | 0.87 | — | — |
埃及黏土 | 1.20 | 54.70 | 5.20 | 4.30 | 5.20 | 1.10 | 12.40 | 4.10 | — | — |
[1] | BRIAN W J.Mineral commodity summaries-Lithium[R].Reston:U.S.Geological Survey,2022. |
[2] | 丁涛,郑绵平,彭苏萍,等.盐湖提锂工艺:高镁锂比盐湖锂盐吸附剂研发进展[J].科技导报,2020,38(14):94-101. |
DING Tao, ZHENG Mianping, PENG Suping, et al.Extracting lithium from salt lake with a high magnesium⁃to⁃lithium ratio:Research progress and prospect of lithium salt adsorbents[J].Science & Technology Review,2020,38(14):94-101. | |
[3] | 宋彭生,项仁杰.盐湖锂资源开发利用及对中国锂产业发展的建议[J].矿床地质,2014,33(5):977-992. |
SONG Pengsheng, XIANG Renjie.Utilization and exploitation of lithium resources in salt lakes and some suggestions concerning development of Li industries in China[J].Mineral Deposits,2014,33(5):977-992. | |
[4] | 朱丽.黏土型锂资源矿物学特征及绿色浸出工艺研究[J].硕士电子期刊,2021,12:1-75. |
ZHU Li.Study on mineralogical characteristics and green leaching technology of clay⁃type lithium resources[J].Master's Electronic Journal,2021,12:1-75. | |
[5] | SOLAY M P D, SMITH K, KAPLAN N, et al.Delivering Growth[C]//Allkem.Investor strategy day.Brisbane QLD,2022:1-65. |
[6] | 高峰,郑绵平,乜贞,等.盐湖卤水锂资源及其开发进展[J].地球学报,2011,32(4):483-492. |
GAO Feng, ZHENG Mianping, NIE Zhen, et al.Brine lithium resource in the salt lake and advances in its exploitation[J].Acta Geoscientica Sinica,2011,32(4):483-492. | |
[7] | 叶流颖,曾德文,陈驰,等.卤水提锂吸附剂应用研究进展[J].无机盐工业,2019,51(3):16-19. |
YE Liuying, ZENG Dewen, CHEN Chi, et al.Research progress in application of absorbent of lithium extraction from brine[J].Inorganic Chemicals Industry,2019,51(3):16-19. | |
[8] | GRAVES P.2020 Sustainability report[R].Philadephia:Livent,2021. |
[9] | 时历杰,张大义,王敏,等.用于从高镁锂比的盐湖卤水分离锂的盐湖卤水处理方法:中国,103074502[P].2014-04-23. |
[10] | 李陇岗,秦佳政,余明祥,等.一种从硫酸镁亚型盐湖卤水中提取电池级碳酸锂的方法:中国,109607578[P].2019-04-12. |
[11] | 马培华,邓小川,温现民.从盐湖卤水中分离镁和浓缩锂的方法:中国,1281497[P].2006-10-25. |
[12] | 赵茜.可回收锰系锂离子筛的掺杂改性制备及其吸附性能研究[J].硕士电子期刊,2020,1:1-79. |
ZHAO Qian.Study on preparation of magnetically recyclable met⁃al⁃doped lithium ion sieves and the adsorption performance[J].Master's Electronic Journal,2020,1:1-79. | |
[13] | 杨建元,夏康明.用高镁含锂卤水生产碳酸锂、氧化镁和盐酸的方法:中国,1313373[P].2007-05-02. |
[14] | AVERILL W A, OLSON D L.A review of extractive processes for lithium from ores and brines[J].Energy,1978,3(3):305-313. |
[15] | 徐龙泉,曾祖亮,梁虎,等.硫酸法生产电池级碳酸锂:中国,1267636A[P].2000-09-27. |
[16] | 姚开林,金鹏,霍立明,等.硫酸锂溶液生产低镁电池级碳酸锂的方法:中国,101125668[P].2008-02-20. |
[17] | 余裕森,崔立雪,王云帆,等.锂云母提锂技术的研究进展[J/OL].中国有色金属学报,[2022-04-01].https://kns.cnki.net/kcms/detail/43.1238.tg.20220330.1132.001.html. |
YU Yusen, CUI Lixue, WANG Yunfan, et al.Research progress of lithium extraction technology from lepidolite[J/OL].The Chinese Journal of Nonferrous Metals,[2022-04-01].https://kns.cnki.net/kcms/detail/43.1238.tg.20220330.1132.001.html. | |
[18] | 张利珍,张永兴,张秀峰,等.采用氯化焙烧-水浸工艺综合提取锂钾铷铯[J].无机盐工业,2019,51(10):48-50,80. |
ZHANG Lizhen, ZHANG Yongxing, ZHANG Xiufeng, et al.Extraction of lithium,potassium,rubidium and cesium by chlorination roasting⁃water leaching process[J].Inorganic Chemicals Industry,2019,51(10):48-50,80. | |
[19] | 罗林山,周健,文小强,等.锂云母混合盐法提锂和析盐的回收再利用[J].无机盐工业,2018,50(3):31-33,59. |
LUO Linshan, ZHOU Jian, WEN Xiaoqiang, et al.Study on extracting lithium from lepidolite by compound salt method and recycling and reuse of precipitated salt[J].Inorganic Chemicals Industry,2018,50(3):31-33,59. | |
[20] | 南进喜,曾小毛,穆健书,等.一种复合硫酸盐酸化焙烧锂云母制备碳酸锂的方法:中国,113104867A[P].2021-07-13. |
[21] | 王丁,陈树.高压蒸汽法处理锂云母提锂工艺研究[J].无机盐工业,2020,52(2):47-49. |
WANG Ding, CHEN Shu.Study on extraction process of lithium from lepidolite by high pressure steam[J].Inorganic Chemicals Industry,2020,52(2):47-49. | |
[22] | 李良彬,陈超,郁兴国,等.一种含锂黏土提锂的方法:中国,111893318A[P].2020-11-06. |
[23] | 南东东,曾小毛,张国强,等.一种混合硫酸盐法焙烧从锂瓷石矿物中提锂的方法:中国,113999970[P].2022-02-01. |
[24] | 刘够生,王林林,刘跃龙.硫酸铵法利用中低品位锂瓷土矿制备碳酸锂技术研究[J].无机盐工业,2020,52(10):125-129. |
LIU Gousheng, WANG Linlin, LIU Yuelong.Preparation of lithium carbonate from medium-and low⁃grade lithium clay by ammonium sulfate process[J].Inorganic Chemicals Industry,2020,52(10):125-129. | |
[25] | REZOS G, WEDIN F, KREUTER H, et al.2022 Half year repo⁃rt[C]//Vulcan.Investor conference.Perth WA,2022:1-50. |
[26] | 孙景文.全球锂资源供需现状与展望[C]//旺材新媒体.2022年第六届动力锂电池正极材料高峰论坛暨全球锂产业链发展大会.湖南长沙,2022:1-31. |
SUN Jingwen.Status and prospect of supply and demand of global lithium resources[C]//Wangcai New Media.The 6th Summit of Cathode Materials for Lithium Battery of EV and Global Conference of Lithium Industry Chain Development in 2022.Changsha,Hunan,2022:1-31. | |
[27] | MASTERS K.Albemarle investor presentation[C]//J.P.Morgan.Industrials conference.New York,2022:1-21. |
[28] | 陈媛.供应链牛鞭效应的原因分析及其破解之道[J].中小企业管理与科技:下旬刊,2021(11):149-151. |
CHEN Yuan.Analysis of the reasons of the bullwhip effect in supply chain and its solution[J].Management & Technology of SME,2021(11):149-151. |
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