铜基硫族化合物电催化二氧化碳还原制甲酸盐的研究进展

doi:10.19964/j.issn.1006-4990.2021-0622

Abstract

Abstract:

Electrocatalytic caybon dioxide reduction reaction（CO₂RR） has attracted widespread attention for its help in reducing atmospheric CO₂ concentration to alleviate environmental problems and producing high value-added chemicals.As one of the most important products of CO₂ electroreduction,formate is widely used in chemical industry,fuel cell and other fields.Cu-based chalcogenides（Cu_xS） have broad application prospects due to their low price and excellent catalytic performance.Based on this,researchers have devoted much effort to nanostructure regulation,electrolytes optimization and feed composition control to promote the catalytic activities and formate selectivity of Cu-based chalcogenides toward electrocatalytic CO₂RR.Recent advances in structural design of catalysts,influential factors and catalytic mechanism for Cu_xS in CO₂ electroreduction were reviewed.And the main challenges that Cu_xS faces in the CO₂RR field were also pointed out.The development prospect of Cu_xS catalysts as electrocatalysts for CO₂ reduction with high activity and stability was prospected.

Key words: electrocatalysis, carbon dioxide electroreduction, Cu-based chalcogenides, formate

CLC Number:

O643.32

CHEN Jingjuan,LÜ Lin,WAN Houzhao,WANG Hao. Recent progress on Cu-based chalcogenides for electrocatalytic carbon dioxide reduction to formate[J]. Inorganic Chemicals Industry, 2021, 53(12): 14-20.

Figures/Tables 4

Table 1

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References 59

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可能的反应途径	电极电位（vs.SHE）/V
CO₂（g）+4H⁺+4e^-→C（s）+2H₂O（l）	0.210
CO₂（g）+2H₂O（l）+4e^-→C（s）+4OH^-	-0.627
CO₂（g）+2H⁺+2e^-→HCOOH（l）	-0.250
CO₂（g）+H₂O（l）+2e^-→HCOO^-（aq）+OH^-	-1.078
CO₂（g）+2H⁺+2e^-→CO（g）+H₂O（l）	-0.106
CO₂（g）+H₂O（l）+2e^-→CO（g）+2OH^-	-0.934
CO₂（g）+4H⁺+4e^-→CH₂O（l）+H₂O	-0.070
CO₂（g）+3H₂O（l）+4e^-→CH₂O+4OH^-	-0.898
CO₂（g）+6H⁺+6e^-→CH₃OH（l）+H₂O	0.016
CO₂（g）+5H₂O（l）+6e^-→CH₃OH（l）+6OH^-	-0.812
CO₂（g）+8H⁺+8e^-→CH₄（g）+2H₂O	0.169
CO₂（g）+6H₂O（l）+8e^-→CH₄（g）+8OH^-	-0.659
2CO₂（g）+2H⁺+2e^-→H₂C₂O₄（aq）	-0.500
2CO₂（g）+2e^-→C₂O₄^2-（aq）	-0.590
2CO₂（g）+12H⁺+12e^-→CH₂CH₂（g）+4H₂O	0.064
2CO₂（g）+8H₂O（l）+12e^-→CH₂CH₂（g）+12OH^-	-0.764
2CO₂（g）+12H⁺+12e^-→CH₃CH₂OH（l）+3H₂O（l）	0.084
2CO₂（g）+9H₂O（l）+12e^-→CH₃CH₂OH（l）+12OH^-	-0.744

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Recent progress on Cu-based chalcogenides for electrocatalytic carbon dioxide reduction to formate

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