蒙砂粉熟化过程与蚀刻玻璃表面的研究

doi:10.19964/j.issn.1006-4990.2021-0578

Abstract

Abstract:

The aging quality of solid masking powder is an important factor to determine the etching effect of glass.X-ray diffraction（XRD），energy dispersive spectrometer（EDS），Raman spectra，Viscometer，Zeta potential and alkali titration were used to study the change law of physical and chemical properties with the aging time of the masking powder mainly consisting of citric acid and ammonium bifluoride，and the effect of aging time on the etching effect of GG6 mobile phone cover glass was investigated and evaluated.The results showed that the viscosity and the hydrogen ion concentration of the suspension were the maximum when the aging time was 36 h.The leading roughness，haze，transparency and glossy of the etched glass were 265 nm，84%，92.4% and 11.7%，respectively，which met the etching quality requirements of industrial mobile phone glass cover plate.After etching，the GG6 glass surface had a layer of fluorosilicic acid crystal，which constituted a more uniform micro-nano pore structure.The determination of the physical and chemical properties of the masking liquid was helpful to better understand the curing process of frosted powder，and had a certain theoretical guidance for the etching process of frosted powder，so as to effectively improve the production efficiency of glass anti-glare process.

Key words: masking powder, cover glass, anti-glare, aging, etching

CLC Number:

TQ171.1

GE Shengzhuo,ZHANG Xihua,CHEN Xiaoqun,JIANG Chongwen. Study on aging process of masking powder and etching on glass surface[J]. Inorganic Chemicals Industry, 2022, 54(7): 91-97.

Figures/Tables 11

Fig.1

Fig.2

Table 1

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

Table 2

Fig.8

Fig.9

References 22

1	沈斌，冯小江，李培春.浅谈智能手机玻璃盖板发展及应用研究［J］.科技创新与应用，2017（28）：151，153.
	SHEN Bin， FENG Xiaojiang， LI Peichun.Brief introduction to development and application of smart phone cover glass［J］.Technology Innovation and Application，2017（28）：151，153.
2	DU Jiangtao， ZHANG Xin， KING D.An investigation into the risk of night light pollution in a glazed office building：The effect of shading solutions［J］.Building and Environment，2018，145：243-259
3	DOBROWOLSKI J A， POITRAS D， MA Penghui，et al.Toward perfect antireflection coatings：Numerical investigation［J］.Applied Optics，2002，41（16）：3075-3083.
4	YE Hui， LI Yaguo， YUAN Zhigang，et al.Ultrasonic-assisted wet chemical etching of fused silica for high-power laser systems［J］.International Journal of Applied Glass Science，2018，9（2）：288-295
5	PIRET N， SANTORO R， DOGOT L，et al.Influence of glass composition on the kinetics of glass etching and frosting in concentrated HF solutions［J］.Journal of Non-Crystalline Solids，2018，499：208-216.
6	STAROŃ A， DŁUGOSZ O， SZOSTAK A.Study of the influence of etching mixture components on the frosted glass effect［J］.Journal of Non-Crystalline Solids，2021，554.Doi：10.1016/j.jnoncrysol. 2020.120583 . doi: 10.1016/j.jnoncrysol. 2020.120583
7	RYU H， KIM P K，LIM G.Advanced glass etching method exhibiting the controllable etch stop using metal etchant［J］.Journal of Micromechanics and Microengineering，2012，22（12）：1519-
	1529.
8	LIU Fanfan， ZHOU Aiguo， CHEN Jinfeng，et al.Preparation of Ti₃C₂ and Ti₂C MXenes by fluoride salts etching and methane adsorptive properties［J］.Applied Surface Science，2017，416：781-789
9	温丰源，李霞.氟化氢铵的生产工艺与最新进展［J］.无机盐工业，2013，45（10）：5-7.
	WEN Fengyuan， LI Xia.Production technology of ammonium bifluoride and latest progress thereof［J］.Inorganic Chemicals Industry，2013，45（10）：5-7.
10	王海风，王丹，王青，等.防眩玻璃制备工艺的研究［J］.玻璃与搪瓷，2012，40（4）：6-9，14.
	WANG Haifeng， WANG Dan， WANG Qing，et al.Study on the preparation process of anti-glare glass［J］.Glass & Enamel，2012，
	40（4）：6-9，14.
11	刘存海，张佳.微氟循环玻璃蚀刻的工艺研究［J］.陕西师范大学学报：自然科学版，2014，42（1）：62-64.
	LIU Cunhai， ZHANG Jia.Study on micro fluorine recycling etched glass［J］.Journal of Shaanxi Normal University：Natural Science Edition，2014，42（1）：62-64.
12	SURYANI S， HERYANTO H， RUSDAENI R，et al.Quantitative analysis of diffraction and infra-red spectra of composite cement/BaSO₄/Fe₃O₄ for determining correlation between attenuation coefficient，structural and optical properties［J］.Ceramics International，2020，46（11）：18601-18607.
13	张鹏，张煜，段江飞，等.离子交换法合成硫酸钡的研究［J］.无机盐工业，2020，52（5）：40-44.
	ZHANG Peng， ZHANG Yu， DUAN Jiangfei，et al.Research on synthesis of barium sulfate by ion-exchange method［J］.Inorganic
	Industry Chemicals，2020，52（5）：40-44.
14	SAINZ M A， SERRANO F J， AMIGO J M，et al.XRD microstructural analysis of mullites obtained from kaolinite-alumina mixtures［J］.Journal of the European Ceramic Society，2000，20（4）：403-412.
15	SU Shuangqing， MA Hongwen， CHUAN Xiuyun.Hydrothermal synthesis of zeolite A from K-feldspar and its crystallization me-
	chanism［J］.Advanced Powder Technology，2016，27（1）：139-144
16	冯敏，王玉芳，王翚，等.柠檬酸与钛络合过程的拉曼光谱分析［J］.光散射学报，2008，20（3）：265-268.
	FENG Min， WANG Yufang， WANG Hui，et al.Raman spectra analysis of Ti and ditric acid coordination［J］.The Journal of Light Scattering，2008，20（3）：265-268.
17	LI Jinjiang， CHATTERJEE K， MEDEK A，et al.Acid-base characteristics of bromophenol blue-citrate buffer systems in the amor-
	phous state［J］.Journal of Pharmaceutical Sciences，2004，93（3）：697-712.
18	JUDGE J S.A study of the dissolution of SiO₂ in acidic fluoride solutions［J］.Journal of the Electrochemical Society，1971，118（11）：1772-1775.
19	CACUA K， ORDOÑEZ F， ZAPATA C，et al.Surfactant concentration and pH effects on the zeta potential values of alumina nanofluids to inspect stability［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects，2019，583.Doi：10.1016/j.colsurfa.2019.123960 . doi: 10.1016/j.colsurfa.2019.123960
20	BARBOUX P， LAGHZIZIL A， BESSOLES Y，et al.Paradoxical crystalline morphology of frosted glass［J］.Journal of Non-Cryst- alline Solids，2004，345-346：137-141.
21	吴光辉，邓安民，崔瑞元.水剂玻璃蒙砂粉的研究［J］.玻璃与搪瓷，2001，29（2）：22-25.
	WU Guanghui， DENG Anmin， CUI Ruiyuan.The studies on aqueous type of glass frosting powder［J］.Glass & Enamel，2001，29（2）：22-25.
22	李筱凡，郝霞，王琦，等.常温下对高铝玻璃的高透过防眩表面处理［J］.硅酸盐学报，2021，49（5）：1000-1005.
	LI Xiaofan， HAO Xia， WANG Qi，et al.Treatment for high-transmittance and anti-glare surface of high alminum glass at normal temperature［J］.Journal of the Chinese Ceramic Society，2021，49（5）：1000-1005.

熟化时间/h	w（氟）/%	w（钡）/%	w（铝）/%	w（钠）/%
6	39.48	1.05	2.36	2.89
12	22.97	0.68	1.02	1.25
24	25.56	0.87	1.55	1.96
36	32.43	0.87	1.75	1.67
48	34.51	0.63	1.02	8.24

项目	w（硅）	w（铝）	w（钠）	w（氧）	w（氟）
蒙砂前	21.43	16.22	5.31	50.10	0.00
蒙砂后	17.74	12.06	5.35	55.27	1.33

[1]	PENG Shuang, CHEN Chaoyi, WANG Shiyu, BAI Yang, LI Tianpei, GU Wei. Study on preparation of titanium carbide derived carbon by electrolysis-etching in CaCl₂ molten salt [J]. Inorganic Chemicals Industry, 2023, 55(3): 78-83.
[2]	Wen Yanshen,Chen Gang,Wang Weihong,Chen Changming,Gong Chuangzhou,Zhao Jie. Standardization and development trend of utilization of copper-containing etching waste solution on circuit boards [J]. Inorganic Chemicals Industry, 2021, 53(8): 27-30.
[3]	YANG Junfang,ZHOU Huan,ZHA Zhengjiong,WANG Yongcheng. Preparation process and product characterization of various copper oxychloride with respective crystal form from etching waste solution [J]. Inorganic Chemicals Industry, 2021, 53(11): 107-113.
[4]	Chen Zhenbang,Yang Shousheng. Aging mechanism and life prediction of ammonium polyphosphate thermal-oxidative acceleration aging [J]. Inorganic Chemicals Industry, 2019, 51(3): 20-24.
[5]	Yu Xinrui，Gao Feng，Lü Chao，Sheng Yu，Tong Qingsong. Effects of aging temperature on electrochemical properties of LiNi0.5Co0.2Mn0.3O2 cathode material [J]. Inorganic Chemicals Industry, 2019, 51(10): 51-55.
[6]	TONG Meng-Liang, SHU Jun-Jie, WANG Luo-Qiang. Preparation and performance study on Mg-Al-hydrotalcite [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(4): 22-.
[7]	ZHAO Peng-Wei, HU Lin-Na, FEI Chang-Rong, HE Yu-Ji. Discussion on several issues of technical reforms in light calcium carbonate production process [J]. INORGANICCHEMICALSINDUSTRY, 2013, 45(10): 1-.
[8]	Yang Yuwang;Dai Qing;Xu Yan;Liu Jingli;Yu Haibin;Guo Ying;Fei Jiaming. Effects of aging conditions on properties of aluminium hydroxide [J]. INORGANICCHEMICALSINDUSTRY, 2010, 0(11): 0-0.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on aging process of masking powder and etching on glass surface

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 11

References 22

Related Articles 8

Metrics

Comments

Recommended 0