锂离子筛研究进展

doi:10.19964/j.issn.1006-4990.2021-0371

Abstract

Abstract:

Lithium ion sieves（manganese and titanium series） show high adsorption selectivity for lithium ion in salt lake brine with high Mg/Li ratio（mass ratio）.The lithium extraction mechanism of spinel structure lithium ion sieve mainly includes redox mechanism，ion exchange mechanism and composite mechanism，while the layered structure lithium ion sieve is mainly realized by simple ion exchange between Li⁺ and H⁺.The preparation process of lithium ion sieve is simple.First，solid phase combustion，microwave combustion or sol-gel process，hydrothermal method，coprecipitation method and molten salt synthesis method are used to prepare precursors，and then the Li⁺ in the corresponding precursor can be replaced by H⁺.The prepared lithium ion sieve can be used to extract lithium from liquid lithium resources such as salt lake brine and seawater with large reserves and low grade.In recent years，the research is mainly focused on titanium lithium ion sieve with higher structural stability，however，further studies are needed to further improve the structural stability and realize engineering application.

Key words: lithium ion sieve, lithium extraction mechanism, preparation method, ion exchange, selectivity

CLC Number:

TQ131.11

ZHANG Liyuan,SHEN Ruqian,YANG Jinju,LI Yan,SHUI Yi,SU Min. Research progress on lithium ion sieves[J]. Inorganic Chemicals Industry, 2022, 54(5): 28-37.

Figures/Tables 5

Fig.1

Table 1

Fig.2

Fig.3

Fig.4

References 84

1	KAVANAGH L， KEOHANE J， GARCIA CABELLOS G，et al.Global lithium sources—Industrial use and future in the electric vehicle industry：A review［J］.Resources，2018，7（3）：57.
2	SWAIN B.Recovery and recycling of lithium：A review［J］.Separation and Purification Technology，2017，172：388-403.
3	GOLMOHAMMADZADEH R， FARAJI F， RASHCHI F.Recovery of lithium and cobalt from spent lithium ion batteries（LIBs） using organic acids as leaching reagents：A review［J］.Resources，Conservation and Recycling，2018，136：418-435.
4	KING S， BOXALL N J.Lithium battery recycling in Australia：Defining the status and identifying opportunities for the development of a new industry［J］.Journal of Cleaner Production，2019，215：1279-1287.
5	ORDOÑEZ J， GAGO E J， GIRARD A.Processes and technologies for the recycling and recovery of spent lithium⁃ion batteries［J］.Renewable and Sustainable Energy Reviews，2016，60：195-205.
6	ZENG Xianlai， LI Jinhui， SINGH N.Recycling of spent lithium⁃ion battery：A critical review［J］.Critical Reviews in Environmental Science and Technology，2014，44（10）：1129-1165.
7	LUONG V T， KANG Dong jun， AN J W，et al.Factors affecting the extraction of lithium from lepidolite［J］.Hydrometallurgy，2013，134/135：54-61.
8	LUONG V T， KANG Dong jun， AN J W，et al.Iron sulphate roasting for extraction of lithium from lepidolite［J］.Hydrometallurgy，2014，141：8-16.
9	BARBOSA L I， VALENTE G， OROSCO R P，et al.Lithium extraction from β-spodumene through chlorination with chlorine gas［J］.Minerals Engineering，2014，56：29-34.
10	CHOUBEY P K， KIM M S， SRIVASTAVA R R，et al.Advance re⁃view on the exploitation of the prominent energy⁃storage element：Lithium. Part I：From mineral and brine resources［J］. Minerals Engineering， 2016，89：119-137.
11	VIECELI N， NOGUEIRA C A， PEREIRA M F C，et al.Optimization of an innovative approach involving mechanical activation and acid digestion for the extraction of lithium from lepidolite［J］.International Journal of Minerals，Metallurgy，and Materials，2018，25（1）：11-19.
12	GRIFFITH C S， GRIFFIN A C， ROPER A，et al.Development of Si Leach technology for the extraction of lithium silicate miner⁃als［J］.Extraction，2018：35-45.
13	CHEN Hao， SHEN Julia.A degradation⁃based sorting method for lithium⁃ion battery reuse［J］.PLoS One，2017，12（10）：1-15.
14	PRANOLO Y， ZHU Zhaowu， CHENG Chu yong.Separation of lithi⁃um from sodium in chloride solutions using SSX systems with LIX 54 and Cyanex 923［J］.Hydrometallurgy，2015，154：33-39.
15	LIU Xuheng， ZHONG Maoli， CHEN Xingyu，et al.Separating lithium and magnesium in brine by aluminum⁃based materials［J］.Hydrometallurgy，2018，176：73-77.
16	BIAN Shaoju， LI Dongdong， GAO Dandan，et al.Hydrometallurgical processing of lithium，potassium，and boron for the comprehensive utilization of Da Qaidam Lake brine via natural evaporation and freezing［J］.Hydrometallurgy，2017，173：80-83.
17	GUO Xiaoyu， HU Shaofang， WANG Chenxi，et al.Highly efficient separation of magnesium and lithium and high⁃valued utilization of magnesium from salt lake brine by a reaction⁃coupled separation technology［J］.Industrial & Engineering Chemistry Research，2018，57（19）：6618-6626.
18	GUO Zhiyuan， JI Zhiyong， CHEN Qingbai，et al.Prefractionation of LiCl from concentrated seawater/salt lake brines by electrodialysis with monovalent selective ion exchange membranes［J］.Journal of Cleaner Production，2018，193：338-350.
19	NIE Xiaoyao， SUN Shuying， SONG Xingfu，et al.Further investigation into lithium recovery from salt lake brines with different feed characteristics by electrodialysis［J］.Journal of Membrane Science，2017，530：185-191.
20	卞维柏，潘建明.选择性吸附提锂材料的研究进展［J］.化工进展，2020，39（6）：2206-2217.
	BIAN Weibai， PAN Jianming.Research progress in selective adsorption materialsfor lithium extraction［J］.Chemical Industry andEngineering Progress，2020，39（6）：2206-2217.
21	李文杰，高建明，赵茜，等.固相法合成磁性可回收锰系离子筛及其锂吸附性能研究［J］.功能材料，2020，51（12）：12120-12125.
	LI Wenjie， GAO Jianming， ZHAO Qian，et al.Facilesynthesis of magnetically recyclable manganese ion sieve using solid state reaction method and its lithium adsorption performance［J］.Journal of Functional Materials，2020，51（12）：12120-12125.
22	郭佳明，刘明言，吴强，等.硝酸锂改性钛系离子筛的制备及其吸附性能［J］.化工学报，2020，71（2）：879-888.
	GUO Jiaming， LIU Mingyan， WU Qiang，et al.Preparation and adsorption performance of titanium based lithium ion sieve improved by LiNO₃ ［J］.CIESC Journal，2020，71（2）：879-888.
23	董殿权，王永顺，房超.多孔掺杂型钛系离子筛的制备及吸附性能［J］.化工学报，2017，68（7）：2812-2817.
	DONG Dianquan， WANG Yongshun， FANG Chao.Preparation and adsorption properties of porous doped titanium series［J］.CIESC Journal，2017，68（7）：2812-2817.
24	刘炳光，祖晓冬，李建生，等.负载型锂离子筛吸附剂研究进展［J］.无机盐工业，2019，51（9）：12-16.
	LIU Bingguang， ZU Xiaodong， LI Jiansheng，et al.Research progress in supported lithium ion sieve absorbents［J］.Inorganic Chemicals Industry，2019，51（9）：12-16.
25	LIU Dongfan， SUN Shuying， YU Jianguo.Electrochemical and adsorption behaviour of Li⁺，Na⁺，K⁺，Ca²⁺，and Mg²⁺ in LiMn₂O₄/λ-MnO₂ structures［J］.The Canadian Journal of Chemical Engineering，2018，97：1589-1595.
26	GAO Aolei， HOU Xinjuan， SUN Zhenhua，et al.Lithium⁃desorption mechanism in LiMn₂O₄，Li_1.33Mn_1.67O₄，and Li_1.6Mn_1.6O₄ according to precisely controlled acid treatment and density functional theory calculations［J］.Journal of Materials Chemistry A，2019，7（36）：20878-20890.
27	QIAN Fangren， GUO Min， QIAN Zhiqiang，et al.Highly lithium adsorption capacities of H_1.6Mn_1.6O₄ ion⁃sieve by ordered array structure［J］.ChemistrySelect，2019，4（34）：10157-10163.
28	ONODERA Y， IWASAKI T， HAYASHI H，et al.A new inorganic material with high selective adsorbability for lithium ions［J］.Chemistry and Industry，1988（24）：786-789.
29	ZHANG Liyuan， SHUI Yi， ZHAO Lingling，et al.Preparation of Ni-doped Li₂TiO₃ using an inorganic precipitation⁃peptization⁃ method［J］.Coatings，2019，9（11）：701.
30	ZHANG Liyuan， WAN Xiangjun， SHUI Yi，et al.The effect of surfactants on the properties of colloid precursor Li₂TiO₃ ［J］.Russian Journal of Physical Chemistry A，2020，94（3）：590-603.
31	ZHANG Liyuan， ZHOU Jiabei， HE Gang，et al.Extraction difficulty of lithium ions from various crystal planes of lithium titanate［J］.Journal of Wuhan University of Technology-Material，2018，33（5）：1086-1091.
32	HUNTER J C.Preparation of a new crystal form of manganese dioxide：λ-MnO₂ ［J］.Journal of Solid State Chemistry，1981，39（2）：142-147.
33	KOZAWA A， POWERS R A.The manganese dioxide electrode in alkaline electrolyte；the electron⁃proton mechanism for the discharge process from MnO₂ to MnO_1.5 ［J］.Journal of the Electrochemical Society，1966，113（9）：870.
34	OOI K， MIYAI Y， KATOH S，et al.Lithium⁃ion insertion/extraction reaction with λ-MnO₂in the aqueous phase［J］.Chemistry Letters，1988，17（6）：989-992.
35	OOI K， MIYAI Y， KATOH S，et al.Topotactic lithium（1+） insertion to lambda-manganese dioxide in the aqueous phase［J］.Langmuir，1989，5（1）：150-157.
36	OOI K， MIYAI Y， KATOH S，et al.The pH titration study of lithium ion adsorption on λ-MnO₂ ［J］.Bulletin of the Chemical Society of Japan，1988，61（2）：407-411.
37	TANG Weiping， KANOH H，OOI K.Lithium ion extraction from orthorhombic LiMnO₂in ammonium peroxodisulfate solutions［J］.Journal of Solid State Chemistry，1999，142（1）：19-28.
38	SHEN Xiangmu， CLEARFIELD A.Phase transitions and ion exchange behavior of electrolytically prepared manganese dioxide［J］.Journal of Solid State Chemistry，1986，64（3）：270-282.
39	SATO K， POOJARY D M， CLEARFIELD A，et al.The surface structure of the proton⁃exchanged lithium manganese oxide spinels and their lithium⁃ion sieve properties［J］.Journal of Solid State Chemistry，1997，131（1）：84-93.
40	ZHANG Qinhui， LI Shaopeng， SUN Shuying，et al.LiMn₂O₄ spinel direct synthesis and lithium ion selective adsorption［J］.Chemical Engineering Science，2010，65（1）：169-173.
41	AMMUNDSEN B， JONES D J， ROZIÈRE J，et al.Ion exchange in manganese dioxide spinel：proton，deuteron，and lithium sites determined from neutron powder diffraction data［J］.Chemistry of Materials，1998，10（6）：1680-1687.
42	KIM Y S， KANOH H， HIROTSU T，et al.Chemical bonding of ion⁃exchange type sites in spinel⁃type manganese oxides Li_1.33Mn_1.67O₄ ［J］.Materials Research Bulletin，2002，37（2）：391-396.
43	OOI K， MIYAI Y， SAKAKIHARA J.Mechanism of lithium（1+） insertion in spinel⁃type manganese oxide.Redox and ion⁃exchange reactions［J］.Langmuir，1991，7（6）：1167-1171.
44	FENG Qi， MIYAI Y， KANOH H，et al.Lithium（1+） extraction/insertion with spinel⁃type lithium manganese oxides.Characterization of redox⁃type and ion⁃exchange⁃type sites［J］.Langmuir，1992，8（7）：1861-1867.
45	CHITRAKAR R， MAKITA Y，OOI K，et al.Lithium recovery from salt lake brine by H₂TiO₃ ［J］.Dalton Transactions，2014，43（23）：8933-8939.
46	HOSOGI Y， KATO H， KUDO A.Visible light response of AgLi1/₃M2/₃O₂（M=Ti and Sn） synthesized from layered Li2MO3［J］.Journal of Materials Chemistry，2008，18（6）：647-653.
47	DENISOVA T A， MAKSIMOVA L G， POLYAKOV E V，et al.Metatitanic acid：Synthesis and properties［J］.Russian Journal of Inorganic Chemistry，2006，51（5）：691-699.
48	HE Gang， ZHANG Liyuan， ZHOU Dali，et al.The optimal condition for H₂TiO₃-lithium adsorbent preparation and Li⁺ adsorption confirmed by an orthogonal test design［J］.Ionics，2015，21（8）：2219-2226.
49	MARTHI R， ASGAR H， GADIKOTA G，et al.On the structure and lithium adsorption mechanism of layered H₂TiO₃ ［J］.ACS Applied Materials & Interfaces，2021，13（7）：8361-8369.
50	YANG Xiaojing， KANOH H， TANG Weiping，et al.Synthesis of Li_1.33Mn_1.67O₄ spinels with different morphologies and their ion adsorptivities after delithiation［J］.Journal of Materials Chemistry，2000，10（8）：1903-1909.
51	LAWAGON C P， NISOLA G M，MUN J，et al.Adsorptive Li⁺ mining from liquid resources by H₂TiO₃：Equilibrium，kinetics，thermodynamics，and mechanisms［J］.Journal of Industrial and Engineering Chemistry，2016，35：347-356.
52	KOSOVA N V， UVAROV N F， DEVYATKINA E T，et al.Mechanochemical synthesis of LiMn₂O₄ cathode material for lithium batteries［J］.Solid State Ionics，2000，135（1/2/3/4）：107-114.
53	HUANG Yudai， JIANG Rongrong， BAO Shujuan，et al.LiMn₂O_4- _y Br _y nanoparticles synthesized by a room temperature solid-state coordination method［J］.Nanoscale Research Letters，2009，4（4）：353-358.
54	CUI Tao， HUA Ning， HAN Ying，et al.Preparation and electrochemical properties of LiMn₂O₄ by a rheological⁃phase⁃assisted microwave synthesis method［J］.Inorganic Materials，2008，44（5）：542-548.
55	NAKAYAMA M， WATANABE K， IKUTA H，et al.Grain size control of LiMn₂O₄ cathode material using microwave synthesis method［J］.Solid State Ionics，2003，164（1/2）：35-42.
56	CHITRAKAR R， KANOH H， MIYAI Y，et al.Synthesis of o-LiMnO₂ by microwave irradiation and StudyIts heat treatment and lithium exchange［J］.Journal of Solid State Chemistry，2002，163（1）：1-4.
57	ZAKHAROVA G S， SINGER L， FATTAKHOVA Z A，et al.MoO₂/C composites prepared by tartaric acid and glucose⁃assisted Sol-gel processes as anode materials for lithium⁃ion batteries［J］.Journal of Alloys and Compounds，2021，863.Doi：10.1016/j.jallcom.2020.158353 . doi: 10.1016/j.jallcom.2020.158353
58	ILIA G， SIMULESCU V， HULKA I.Hybrids containing zirconium and phosphorus compounds obtained by sol-gel method［J］.Colloid and Polymer Science，2021，299（1）：137-151.
59	JALILPOUR M， REZVANI M， HAMEDANI M T，et al.Investigation of the structural properties and bioactivity of P₂O₅-CaO-Na₂O-TiO₂ glass and glass⁃ceramics synthesized via a novel sol-gel method by acetone and DMF solvents［J］.Journal of Sol-Gel Science and Technology，2021，97（1）：213-227.
60	SUN Y K， OH I H， KIM K Y.Synthesis of spinel LiMn₂O₄ by the sol-gel method for a cathode⁃active material in lithium secondary batteries［J］.Industrial & Engineering Chemistry Research，1997，36（11）：4839-4846.
61	SEYEDAHMADIAN M， HOUSHYARAZAR S， AMIRSHAGHA⁃GHI A.Synthesis and characterization of nanosized of spinel LiMn₂O₄via sol-gel and freeze drying methods［J］.Bulletin of the Korean Chemical Society，2013，34（2）：622-628.
62	KUSHIDA K， KURIYAMA K.Crystallization mechanism of sol-gel synthesized spinel LiMn₂O₄ ［J］.Physica Status Solidi （c），2015，12（6）：549-552.
63	SEKIGUCHI T， MIYASHITA S， OBARA K，et al.Hydrothermal growth of ZnO single crystals and their optical characterization［J］.Journal of Crystal Growth，2000，214/215：72-76.
64	THANH N T K， MACLEAN N， MAHIDDINE S.Mechanisms of nucleation and growth of nanoparticles in solution［J］.Chemical Reviews，2014，114（15）：7610-7630.
65	CHITRAKAR R， KANOH H， MIYAI Y，et al.A new type of manganese oxide （MnO₂·0.5H₂O） derived from Li_1.6Mn_1.6O₄ and its lithium ion⁃sieve properties［J］.Chemistry of Materials，2000，12（10）：3151-3157.
66	MARTRA G.Lewis acid and base sites at the surface of microcrystalline TiO₂ anatase：Relationships between surface morphology and chemical behaviour［J］.Applied Catalysis A：General，2000，200（1/2）：275-285.
67	HA T H， KOO H J， CHUNG B H.Shape⁃controlled syntheses of gold nanoprisms and nanorods influenced by specific adsorption of halide ions［J］.The Journal of Physical Chemistry C，2007，111（3）：1123-1130.
68	FAN Jie， LEI Jie， WANG Limin，et al.Rapid and high⁃capacity immobilization of enzymes based on mesoporous silicas with controlled morphologies［J］.Chemical Communications（Cambridge，England），2003，9（17）：2140-2141.
69	FENG Qi， MIYAI Y， KANOH H，et al.Lithium（1+） and magnesium（2+） extraction and lithium（1+） insertion reactions with lithium magnesium manganese oxide（LiMg_0.5Mn_1.5O₄） spinel in the aqueous phase［J］.Chemistry of Materials，1993，5（3）：311-316.
70	LIU Yifan， FENG Qi，OOI K.Li⁺ extraction/insertion reactions with LiAlMnO₄ and LiFeMnO₄ spinels in the aqueous phase［J］.Journal of Colloid and Interface Science，1994，163（1）：130-
136
71	LIU Hongmei， ZHU Guobin， ZHANG Li，et al.Controllable synthesis of spinel lithium nickel manganese oxide cathode material with enhanced electrochemical performances through a modified oxalate co⁃precipitation method［J］.Journal of Power Sources，2015，274：1180-1187.
72	NAGHASH A R， LEE J Y.Preparation of spinel lithium manganese oxide by aqueous co⁃precipitation［J］.Journal of Power Sources，2000，85（2）：284-293.
73	HELAN M， BERCHMANS L J.Synthesis of LiSm_0.01Mn_1.99O₄ by molten salt technique［J］.Journal of Rare Earths，2010，28（2）：255-259.
74	HELAN M， BERCHMANS L J.Low⁃temperature synthesis of lithium manganese oxide using LiCl-Li₂CO₃ and manganese acetate eutectic mixture［J］.Materials and Manufacturing Processes，2011，26（11）：1369-1373.
75	HELAN M， BERCHMANS L J， HUSSAIN A Z.Synthesis of LiMn₂O₄ by molten salt technique［J］.Ionics，2010，16（3）：227-231.
76	ZHANG Liyuan， LIU Yiwu， HUANG Lan，et al.A novel study on preparation of H₂TiO₃-lithium adsorbent with titanyl sulfate as titanium source by inorganic precipitation-peptization method［J］.RSC Advances，2018，8（3）：1385-1391.
77	SINHA N N， MUNICHANDRAIAH N.Synthesis and characterization of submicron size particles of LiMn₂O₄ by microemulsion route［J］.Journal of Solid State Electrochemistry，2008，12（12）：1619-1627.
78	KIM H U， SUN Y K， LEE B S，et al.Synthesis of defective⁃structure Li₄Mn₅O₁₂ by combustion method and its application to hybrid capacitor［J］.Journal of the Korean Electrochemical Society，2010，13（2）：103-109.
79	WU H M， TU J P， YUAN Y F，et al.Structural，morphological and electrochemical characteristics of spinel LiMn₂O₄ prepared by spray⁃drying method［J］.Scripta Materialia，2005，52（6）：513-517.
80	HAMZAOUI A H， M'NIF A， HAMMI H，et al.Contribution to the lithium recovery from brine［J］.Desalination，2003，158（1/2/3）：221-224.
81	CHAGNES A， SWIATOWSKA J.Lithium process chemistry：Resources，extraction，batteries，and recycling［M］.Elsevier Science Publishing，2015.
82	PELLY I.Recovery of lithium from Dead Sea brines［J］.Journal of Applied Chemistry and Biotechnology，1978，28（7）：469-474.
83	SUN Ying， GUO Xiaoyu， HU Shaofang，et al.Highly efficient extraction of lithium from salt lake brine by LiAl-layered double hydroxides as lithium⁃ion⁃selective capturing material［J］.Journal of Energy Chemistry，2019，34：80-87.
84	LIMJUCO L A， NISOLA G M， LAWAGON C P，et al.H₂TiO₃ composite adsorbent foam for efficient and continuous recovery of Li⁺ from liquid resources［J］.Colloids and Surfaces A：Physicochemical and Engineering Aspects，2016，504：267-279.

	晶胞参数	原子间距				离子类型
	晶胞参数	d_Mn—O	d_Li—O	d_{Li—O（oct）}		Mn	O	Li
Li_1.33Mn_1.67O₄	8.190	1.933	1.986	1.933	1.82		-1.01	0.76（tet）
Li_1.33Mn_1.67O₄	8.190	1.933	1.986	1.933	1.62		-0.82	0.65（oct）

[1]	HAN Hongjing, ZHANG Jingze, LAMAO Zhuoma, HAN Jizhe, WU Yongmin, TANG Weiping. Preparation of Al-Co co-doped lithium manganese oxide and its adsorption performance of lithium [J]. Inorganic Chemicals Industry, 2023, 55(7): 38-44.
[2]	GUO Zhanzhan,ZHOU Wenyuan,YANG Yunfei,WU Junshu,WANG Jinshu,SUN Lingmin,ZHANG Zhigang,DU Yucheng. Study on controlled synthesis of magadiite and its metal ion exchange properties [J]. Inorganic Chemicals Industry, 2023, 55(2): 45-54.
[3]	HU Yue, MO Hengliang, LI Tianyu, PENG Wenjuan, SUN Guangdong, XIAO Hongkang, CHEN Yili, LI Suoding, TANG Yang. Study on spinning molding and performance of Ti-based lithium ion sieve powder and PVDF resin [J]. Inorganic Chemicals Industry, 2023, 55(11): 58-63.
[4]	JI Ying, ZHANG Ying, HOU Xuechao, ZHU Xiaofeng, JIANG Run, PENG Wenjuan, SUN Guangdong, LÜ Long. Application research of titanium adsorbent of carbonate-type salt lake in Tibet [J]. Inorganic Chemicals Industry, 2023, 55(11): 70-77.
[5]	ZHOU Lei,YUAN Yongshun,LI Lu,LIU Bingguang,LI Jiansheng. Research progress on preparation and application of lithium ion sieve from spent lithium ion batteries [J]. Inorganic Chemicals Industry, 2022, 54(8): 33-39.
[6]	HAN Hongjing,WU Yongmin,CAO Yongsheng,HAN Tingting,TANG Weiping. Preparation of nano?flake polyhedral manganese based lithium ion sieve and its adsorption and desorption characteristic for Li⁺ [J]. Inorganic Chemicals Industry, 2022, 54(8): 59-65.
[7]	YANG Chen,WU Junshu,WANG Jinshu,SUN Lingmin,XU Meng,DU Yucheng. Controlled zeolitization of diatomite for the adsorption and its immobilization of Pb（Ⅱ） ions [J]. Inorganic Chemicals Industry, 2022, 54(4): 128-134.
[8]	ZHOU Weifeng,CHI Yongzhi,LI Kaixiong,TIAN Sufeng,LIU Muzhi. Study on removal of salts from MVR condensate wastewater in the hydrometallurgical industry by ion exchange method [J]. Inorganic Chemicals Industry, 2022, 54(4): 152-158.
[9]	Liu Meili,Long Xiang,Tang Haiyan,Gao Banghui,Li Long,Shao Jiaojing. Construction,properties and applications of two-dimensional nanofluidic channels [J]. Inorganic Chemicals Industry, 2021, 53(6): 101-109.
[10]	Zhang Zheng,Wang Shaohua,Zhao Yaxu,Hua Zhongqiu,Tian Xuemin,Wu Yi. Study on gas sensitivity of HZSM5 zeolite film combined with SnO₂ for methane [J]. Inorganic Chemicals Industry, 2021, 53(2): 105-109.
[11]	Wu Zhaomin,Yang Lin,Wang Xinlong,Zhuang Haibo,Ye Runzhou,Wang Ye,Li Yaoji. Study on process of dynamic ion-exchange for etching waste acid containing aluminum in electronic industry [J]. Inorganic Chemicals Industry, 2021, 53(2): 61-65.
[12]	Chen Wang,Jiang Lei,Pan Qiaozhen,Yang Weiwei,Zhu Xianrong,Chen Linlin,Zhu Wenshuai. Research on preparation and adsorption performance of titanium lithium ion sieve [J]. Inorganic Chemicals Industry, 2021, 53(10): 47-51.
[13]	Zhuang Haibo,Yang Lin,Deng Qiang,Ye Runzhou,Wu Zhaomin. Study on dynamic adsorption of Mn ²⁺ from phosphoric acid by ion exchange technology [J]. Inorganic Chemicals Industry, 2021, 53(1): 18-23.
[14]	Tang Na,Gong Jingkuan,Xiang Jun. Preparation and adsorption properties of aluminum-based lithium adsorbent [J]. Inorganic Chemicals Industry, 2020, 52(8): 51-56.
[15]	Gu Junjie,Li Zengrong,Tang Faman,Zhang Xu,Hou Miaomiao,Wang Xiaohu. Study on continuous ion exchange process applied in lithium extraction from salt lake brine with adsorption method [J]. Inorganic Chemicals Industry, 2020, 52(7): 46-51.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research progress on lithium ion sieves

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 5

References 84

Related Articles 15

Metrics

Comments

Recommended 0