氧化亚铜基复合光催化剂的研究进展

doi:10.11962/1006-4990.2019-0137

Abstract

Abstract:

Cuprous oxide（Cu₂O） has a wide range of application prospects in the field of photocatalysis,solar cell,sensor and so on.Combined with the research direction of Cu₂O photocatalyst,general methods,such as improvement of morphology,doping,metal loading and semiconductor recombination,to improve the photocatalytic performance were reviewed.Several representative Cu₂O based composite photocatalysts,involving metal-Cu₂O composite photocatalyst,Cu₂O-semiconductor composite photocatalyst,Cu₂O-carbon composite photocatalyst and ternary composite photocatalyst,as well as their mechanisms were introduced.At last the future development of Cu₂O based composite photocatalysts were put forward.

Key words: Cu₂O, doping, semiconductor, composite, photocatalysis

CLC Number:

TQ131.21

Xiao Shanshan,Bi Fei,Zhao Li,Wang Liyan,Gai Guangqing. Research progress of cuprous oxide based composite photocatalyst[J]. Inorganic Chemicals Industry, 2020, 52(1): 22-25.

References 28

[1]	Yu C, Zhou W, Liu H , et al. Design and fabrication of microsphere photocatalysts for environmental purification and energy conversion[J]. Chemical Engineering Journal, 2016,287:117-129.
[2]	Wang Y, Zhao J, Chen Z , et al. Construction of Z-scheme MoSe₂/CdSe hollow nanostructure with enhanced full spectrum photocatalytic activity[J]. Applied Catalysis B:Environmental, 2019,244:76-86.
[3]	He J, Zhang M, Primo A , et al. Selective photocatalytic benzene hydroxylation to phenol using surface-modified Cu₂O supported on graphene[J]. Journal of Materials Chemistry A, 2018,6(40):19782-19787.
[4]	Chen R, Pang S, An H , et al. Charge separation via asymmetric illumination in photocatalytic Cu₂O particles[J]. Nature Energy, 2018,3(8):655-663.
[5]	Liu P, Bao R, Fang D , et al. A facile synjournal of CNTs/Cu₂O-CuO heterostructure composites by spray pyrolysis and its visible light responding photocatalytic properties[J]. Advanced Powder Technology, 2018,29(9):2027-2034.
[6]	Hara M, Kondo T, Komoda M , et al. Cu₂O as a photocatalyst for over-all water splitting under visible light irradiation[J]. Chemical Communications, 1998(3):357-358.
[7]	Wang P, Qi C, Hao L , et al. Sepiolite/Cu₂O/Cu photocatalyst: Preparation and high performance for degradation of organic dye[J]. Journal of Materials Science & Technology, 2019,35(3):285-291.
[8]	樊雪敏, 白春华, 李光辉 , 等. 纳米二氧化钛光催化剂共掺杂的研究进展[J]. 无机盐工业, 2016,48(10):7-10,15.
[9]	Ma L L, Li J L, Sun H Z , et al. Self-assembled Cu₂O flowerlike architecture:polyol synjournal,photocatalytic activity and stability under simulated solar light[J]. Materials Research Bulletin, 2010,45(8):961-968.
[10]	Huang L, Peng F, Yu H , et al. Preparation of cuprous oxides with different sizes and their behaviors of adsorption,visible-light driven photocatalysis and photocorrosion[J]. Solid State Sciences, 2009,11(1):129-138.
[11]	Zheng Z, Huang B, Wang Z , et al. Crystal faces of Cu₂O and their stabilities in photocatalytic reactions[J]. The Journal of Physical Chemistry C, 2009,113(32):14448-14453.
[12]	Zou M, Liu H, Feng L , et al. Enhanced visible light photocatalytic activity in N-doped edge-and corner-truncated octahedral Cu₂O[J]. Solid State Sciences, 2017,65:22-28.
[13]	Zhou C, Wang S, Zhao Z , et al. A facet-dependent schottky-junction electron shuttle in a BiVO₄ {010}-Au-Cu₂O Z-scheme photocatayst for efficient charge separation[J]. Advanced Functional Materials, 2018,28(31):1801214.
[14]	Mo X, Hu J, Shen H , et al. Surface modification of micro-sized CuO by in situ-growing heterojunctions CuO/Cu₂O and CuO/Cu₂O/Cu:effect on surface charges and photogenerated carrier lifetime[J]. Applied Physics A, 2018,124(10):719.
[15]	Gong H, Zhang Y, Cao Y , et al. Pt@Cu₂O/WO₃ composite photocatalyst for enhanced photocatalytic water oxidation performance[J]. Applied Catalysis B:Environmental, 2018,237:309-317.
[16]	Li J, Cushing S K, Bright J , et al. Ag@Cu₂O core-shell nanoparticles as visible-light plasmonic photocatalysts[J]. Acs Catalysis, 2013,3(1):47-51.
[17]	Ma Y, Zhu X, Xu S , et al. Gold nanobipyramid@cuprous oxide ju-jube-like nanostructures for plasmon-enhanced photocatalytic performance[J]. Applied Catalysis B:Environmental, 2018,234:26-36.
[18]	Kou T, Jin C, Zhang C , et al. Nanoporous core-shell Cu@Cu₂O nanocomposites with superior photocatalytic properties towards the degradation of methyl orange[J]. RSC Advances, 2012,2(33):12636-12643.
[19]	Kandjani A E, Sabri Y M, Periasamy S R , et al. Controlling core/shell formation of nanocubic p-Cu₂O/n-ZnO toward enhanced photocatalytic performance[J]. Langmuir, 2015,31(39):10922-10930.
[20]	Liu Y, Zhang B, Luo L , et al. TiO₂/Cu₂O core/ultrathin shell nanorods as efficient and stable photocatalysts for water reduction[J]. Angewandte Chemie, 2015,54(50):15260-15265.
[21]	Yuan Q, Chen L, Xiong M , et al. Cu₂O/BiVO₄ heterostructures:synjournal and application in simultaneous photocatalytic oxidation of organic dyes and reduction of Cr (Ⅵ) under visible light[J]. Chemical Engineering Journal, 2014,255:394-402.
[22]	Kulandaivalu T, Rashid S A, Sabli N , et al. Visible light assisted photocatalytic reduction of CO₂ to ethane using CQDs/Cu₂O nanocomposite photocatalyst[J]. Diamond and Related Materials, 2019,91:64-73.
[23]	Han X, He X, Sun L , et al. Increasing effectiveness of photogenerated carriers by in situ anchoring of Cu₂O nanoparticles on a nitrogen-doped porous carbon yolk-shell cuboctahedral framework[J]. ACS Catalysis, 2018,8(4):3348-3356.
[24]	Liu X, Li Z, Zhao W , et al. A facile route to the synjournal of reduced graphene oxide-wrapped octahedral Cu₂O with enhanced photocatalytic and photovoltaic performance[J]. Journal of Materials Chemistry A, 2015,3(37):19148-19154.
[25]	Niu J, Dai Y, Yin L , et al. Photocatalytic reduction of triclosan on Au-Cu₂O nanowire arrays as plasmonic photocatalysts under visible light irradiation[J]. Physical Chemistry Chemical Physics, 2015,17(26):17421-17428.
[26]	Sasmal A K, Dutta S, Pal T . A ternary Cu₂O-Cu-CuO nanocomposite:a catalyst with intriguing activity[J]. Dalton Transactions, 2016,45(7):3139-3150.
[27]	Police A K R, Vattikuti S V P, Mandari K K , et al. Bismuth oxide cocatalyst and copper oxide sensitizer in Cu₂O/TiO₂/Bi₂O₃ ternary photocatalyst for efficient hydrogen production under solar lightirradiation[J]. Ceramics International, 2018,44(10):11783-11791.
[28]	Wei Q, Wang Y, Qin H , et al. Construction of rGO wrapping octahedral Ag-Cu₂O heterostructure for enhanced visible light photocatalytic activity[J]. Applied Catalysis B:Environmental, 2018,227:132-144.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Research progress of cuprous oxide based composite photocatalyst

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References 28

Related Articles 15

Metrics

Comments

Recommended 10

[1]	Feng Fei,Li Shuwen,Wang Tielin,Wang Weiguo,Wang Cunwen. Synthesis and photocatalytic performance of sheet-like Bi/BiVO₄ composite catalyst [J]. Inorganic Chemicals Industry, 2021, 53(1): 107-112.
[2]	Zhao Shihao,Lin Xihua,Ma Pengfei,Yuan Yijin,Gao Yuxin,Zhang Ping,Zhou Dali. Study on formulation calculation of phosphogypsum-based composite cementitious materials based on expansion and failure of critical AFt [J]. Inorganic Chemicals Industry, 2020, 52(9): 91-95.
[3]	Chen Lijia,Chen Haibin,Li Rongyong. Application progress of mechanical coating technique in preparation of photocatalytic materials [J]. Inorganic Chemicals Industry, 2020, 52(8): 1-5.
[4]	Huang Qiumei,Lü Xiaowei,Tan Jialin,Li Lijun,Cheng Hao,Feng Jun,Huang Wenyi. Preparation of Sm doped ZnO QDs and its fluorescence performance [J]. Inorganic Chemicals Industry, 2020, 52(8): 30-35.
[5]	Zhang Shuli,Xu Xupeng,Chen Shurui,Liu Qianshu,Wang Benju. Photocatalytic activity of vanadium doped titanium dioxide [J]. Inorganic Chemicals Industry, 2020, 52(8): 93-97.
[6]	Zhou Jian,Tang Hongbo. Preparation and photocatalytic properties of ZnWO₄/Ag₃PO₄ composite photocatalyst [J]. Inorganic Chemicals Industry, 2020, 52(6): 101-104.
[7]	Zhang Jie,Zhao Mengjie,Cui Yingqi,Li Chenggang,Gao Jinhai. Research progress in effect of doping on properties of CeO₂-based electrolyte materials [J]. Inorganic Chemicals Industry, 2020, 52(5): 1-5.
[8]	Bai Hongliang,Wang Junsheng,Wang Yan. Study on oxidation reacting conditions of benzyl alcohol catalyzed by Au-Pd/ZrO₂ under visible light [J]. Inorganic Chemicals Industry, 2020, 52(4): 100-103.
[9]	Yao Yong,Guo Rui. Research progress of metal element doped spinel type MgGa₂O₄ [J]. Inorganic Chemicals Industry, 2020, 52(4): 23-28.
[10]	Xu Naicai,Li Sixia,Cao Jiajia,Yang Gangshenga. Research on doping modification and adsorption performance of manganese oxides lithium ion sieve [J]. Inorganic Chemicals Industry, 2020, 52(4): 37-41.
[11]	Wang Guosheng,Han Siyu,Tang Fengxiang,Xu Ronghui. Preparation and properties of modified basic magnesium chloride whisker/styrene butadiene rubber composites [J]. Inorganic Chemicals Industry, 2020, 52(3): 51-54.
[12]	Li Tong,Shi Yunbin,Liu Qingbin,He Shuang. Structure and electrochemical properties of cathode materials for new energy automotive lithium batteries doped and modified by Se [J]. Inorganic Chemicals Industry, 2020, 52(2): 17-22.
[13]	Guo Qiushuang,Wu Tongxu,Cai Zhe,Cai Qi,Li Xiaoyun,Sun Yanmin. Study on influence factors of specific surface area of Ti-Si composite oxides [J]. Inorganic Chemicals Industry, 2020, 52(12): 109-112.
[14]	Tian Qizhe,Ye Junwei,Ning Guiling. Preparation and antibacterial properties of MgO-CuO-CaO composite by microwave hydrothermal method [J]. Inorganic Chemicals Industry, 2020, 52(12): 12-16.
[15]	Luo Shuang,Fu Rubin,Kong Dewen,Xie Lang,Zhou Yinsheng,Zhao Yan. Summary on effects of admixtures on water resistance and strength of phosphogypsum-based composite cementitious materials [J]. Inorganic Chemicals Industry, 2020, 52(11): 6-6.