金属元素掺杂尖晶石型镓酸镁的研究进展

doi:10.11962/1006-4990.2019-0330

Abstract

Abstract:

Magnesium gallate（MgGa₂O₄） is a kind of gallate with spinel structure,which is composed of magnesium oxide （MgO） and gallium oxide（Ga₂O₃）.It has good dielectric properties,optical properties,radiation resistance and high tempera-ture stability etc..Due to the existence of a self-activated emission band in the blue visible light region,it has received exten-sive attention in luminescence research.The doping of rare earth and transition metal elements can change the energy transfer process,improve the luminescence efficiency and broaden the luminescence range,which can be applied in many fields such as display,illumination,medical diagnosis and laser,and it has broad application prospect.The research progress on the structure and optical properties of MgGa₂O₄ single doped and co-doped with metal elements such as chromium（Cr）,cobalt（Co）,manganese（Mn）,dysprosium（Dy） and europium（Eu） in recent years was summarized,the main problems existing in the current researches were analyzed,and the research directions and development applications of MgGa₂O₄ doped with metal elements in the future were also prospected.

Key words: MgGa₂O₄, metal doping, optical property, research progress

CLC Number:

TQ132.2

Yao Yong,Guo Rui. Research progress of metal element doped spinel type MgGa₂O₄[J]. Inorganic Chemicals Industry, 2020, 52(4): 23-28.

Figures/Tables 1

References 40

[1]	Sosman L P, da Fonseca R J M, Jr Tavares A D , et al. New spectro-scopic results of trivalent chromium in magnesium gallate[J]. Jour-nal of Physics & Chemistry of Solids, 2007,68(1):22-25.
[2]	Tsai B S, Chang Y H, Chen Y C . Preparation and luminescent char-acteristics of Eu ³+-activated Mg_xZn₁-_xGa₂O₄ nanocrystals [J]. Journal of Alloys and Compounds, 2006,407(1/2):289-293. doi: 10.1016/j.jallcom.2005.06.021
[3]	Liu Z, Hu P, Jing X , et al. Luminescence of native defects in MgGa₂O₄[J]. Journal of The Electrochemical Society, 2009,156(1):43-46.
[4]	Luchechko A, Kravets O . Novel visible phosphors based on MgGa₂O₄-ZnGa₂O₄ solid solutions with spinel structure co-doped with Mn ²+ and Eu ³+ ions [J]. Journal of Luminescence, 2017,192:11-16. doi: 10.1016/j.jlumin.2017.05.046
[5]	Duan X, Wu Y, Wang X , et al. Synjournal,structure and optical pro-perties of Co-doped MgGa₂O₄/SiO₂ nano-glass-ceramic composit-es[J]. Applied Surface Science, 2013,276(10):613-619. doi: 10.1016/j.apsusc.2013.03.141
[6]	Luchechko A, Kravets O, Kostyk L , et al. Luminescence spectrosco-py of Eu ³+ and Mn ²+ ions in MgGa₂O₄ spinel [J]. Radiation Measurements, 2016,90:47-50. doi: 10.1016/j.radmeas.2015.12.003
[7]	Nazarov M, Tsukerblat B, Noh D Y . Multiphase green phosphor {SrGa₂S₄+MgGa₂O₄}:Eu ²+:synjournal and luminescence [J]. Physics Procedia, 2009,2(2):571-575. doi: 10.1016/j.phpro.2009.07.043
[8]	Luchechko A, Zhydachevskyy Y, Maraba D , et al. TL and OSL pro-perties of Mn ²+-doped MgGa₂O₄ phosphor [J]. Optical Materials, 2018,78:502-507. doi: 10.1016/j.optmat.2018.03.004
[9]	齐贵宁 . ZnAl₂O₄:Cr ³+长余辉材料的制备技术与性能表征 [D]. 北京:华北电力大学, 2018.
[10]	Basavaraju N, Sharma S, Bessière A , et al. Red persistent lumines-cence in MgGa₂O₄:Cr ³+;a new phosphor for in vivo imaging [J]. Journal of Physics D:Applied Physics, 2013,46(37):542-553.
[11]	da Silva M A F M, Carvalho I C S, Cella N , et al. Evidence of broad emission band in the system MgGa₂O₄-Ga₂O₃ doped with Cr ³+ions [J]. Optical Materials, 2013,35(3):543-546. doi: 10.1016/j.optmat.2012.10.008
[12]	da Silva M A F M, Sosman L P, Yokaichiya F , et al. Neutron powder diffraction measurements of the spinel MgGa₂O₄:Cr ³+—a compara-tive study between the high flux diffractometer D2B at the ILL and the high resolution powder diffractometer aurora at IPEN [J]. Journal of Physics:Conference Series, 2012,340(1):012041. doi: 10.1088/1742-6596/340/1/012041
[13]	Duan X L, Liu J, Wang X Q , et al. Cation distribution and optical properties of Cr-doped MgGa₂O₄ nanocrystals[J]. Optical Materi-als, 2014,37:854-861.
[14]	Mondal A, Das S, Manam J , et al. Hydrothermal synjournal,structu-ral and luminescent properties of a Cr ³+ doped MgGa₂O₄ near-infra-red long lasting nanophospor [J]. RSC Advances, 2016,6(86):82484-82495. doi: 10.1039/C6RA15119A
[15]	张万鑫, 王银海, 李海玲 , 等. Zn元素替代对MgGa₂O₄:Cr ³+的结构和发光性能的影响 [J]. 光谱学与光谱分析, 2013,33(1):31-35.
[16]	Zhang S C, Xia H P, Wang J H , et al. Growth of Mn ²+,Co ²+ and Ni ²+-doped near-stoichiometric LiNbO₃ by Bridgman method using K₂O flux [J]. Journal of Alloys and Compounds, 2008,463:446-452. doi: 10.1016/j.jallcom.2007.09.052
[17]	Lakshminarayana G, Buddhudu S . Spectral analysis of Mn ²+,Co ²+ and Ni ²+:B₂O₃-ZnO-PbO glasses [J]. Spectrochimica Acta Part A, 2006,63(2):295-304. doi: 10.1016/j.saa.2005.05.013
[18]	Duan X L, Yuan D R, Cheng X F , et al. Preparation of Co ²+-doped MgGa₂O₄ nanocrystals by citrate sol-gel method [J]. Journal of Al-loys and Compounds, 2007,439(1/2):355-357.
[19]	Sosman L P, Jr Tavares A D, Fonseca R J M , et al. Dependence of MgGa₂O₄:Co ²+ photoluminescence on temperature and impurity concentration [J]. Journal of Optics A Pure & Applied Optics, 2008,10(10):104025-104030.
[20]	吕海亮, 马文玲, 杜吉勇 , 等. 燃烧法制备MgGa₂O₄:Co ²+纳米晶及其发光性能研究 [J]. 化学通报, 2010,73(10):900-904.
[21]	Pedro S S, da Silva M A F M, López A , et al. Structural and photo-luminescent properties of the MgGa₂O₄:Co ²+ ceramic compound re-visited after two decades [J]. Journal of Advanced Ceramics, 2015,4(4):267-271. doi: 10.1007/s40145-015-0160-2
[22]	Bao A, Yang H, Tao C , et al. Luminescent properties of nanoparti-cles YP_XV₁-_XO₄:Dy phosphors[J]. Journal of Luminescence, 2008,128(1):60-66. doi: 10.1016/j.jlumin.2007.05.011
[23]	Vengala Rao B, Jang Kiwan, Lee Ho Sueb , et al. Synjournal and pho-toluminescence characterization of RE ³+(=Eu ³+,Dy ³+)-activated Ca₃La(VO₄)₃ phosphors for white light-emitting diodes [J]. Journal of Alloys and Compounds, 2010,496(1/2):251-255. doi: 10.1016/j.jallcom.2009.12.175
[24]	Yan B, Su X Q . Chemical co-precipitation synjournal and photolu-minescence of LnP_xV₁-_xO₄:Dy ³+(Ln=Gd,La) derived from assem-bling hybrid precursors [J]. Journal of Alloys and Compounds, 2007,431(1/2):342-347.
[25]	徐金琴, 张霞, 王路明 . 稀土掺杂荧光材料的研究进展[J]. 化工新型材料, 2011,39(6):22-25.
[26]	Yu L, Liu H . Photoluminescent properties of Dy ³+ in MgO-Ga₂O₃-SiO₂ nano-glass-ceramic prepared by sol-gel method [J]. Physica B:Condensed Matter, 2011,406(15/16):3101-3103. doi: 10.1016/j.physb.2011.05.015
[27]	Liu H, Yu L X, Li F H . Photoluminescent properties of Eu ³+ and Dy ³+ions doped MgGa₂O₄ phosphors [J]. Journal of Physics & Chemistry of Solids, 2013,74(2):196-199.
[28]	Li Y, Niu P, Hu L , et al. Monochromatic blue-green and red emis-sion of rare-earth ions in MgGa₂O₄ spinel[J]. Journal of Lumines-cence, 2009,129(10):1204-1206.
[29]	Costa G K B, Pedro S S, Carvalho I C S , et al. Preparation,struc-ture analysis and photoluminescence properties of MgGa₂O₄:Mn ²+ [J]. Optical Materials, 2009,31(11):1620-1627. doi: 10.1016/j.optmat.2009.03.011
[30]	Suzuki T, Hughes M, Ohishi Y . Optical properties of Ni-doped MgGa₂O₄ single crystals grown by floating zone method[J]. Journal of Luminescence, 2010,130(1):121-126. doi: 10.1016/j.jlumin.2009.07.029
[31]	Duan X L, Liu J, Yu F P , et al. Co/Cr co-doped MgGa₂O₄ nanopar-ticles:Microstructure and optical properties[J]. Materials Resea-rch Bulletin, 2016,73:90-95.
[32]	Sun J, Yu L, Li F , et al. Up-conversion and near infrared lumines-cence in Er ³+/Yb ³+ co-doped glass-ceramic containing MgGa₂O₄nano-crystals [J]. Journal of Luminescence, 2016,170:444-450.
[33]	Moon Y M, Choi Sungho, Jung Ha-Kyun , et al. Sensitized photolu-minescent properties of manganese-activated magnesium gallate phosphor[J]. Journal of Luminescence, 2008,128(9):1491-1495. doi: 10.1016/j.jlumin.2008.02.010
[34]	Song E H, Wang J L, Yu D C , et al. Anomalous tunable visible to near infrared emission in the Mn ²+-doped spinel MgGa₂O₄ and room-temperature upconversion in the Mn ²+ and Yb ³+ -codoped spinel [J]. J.Mater.Chem.C, 2014,2(41):8811-8816.
[35]	Luchechko A, Kravets O . Synjournal and luminescent properties of magnesium gallate spinel doped with Mn ²+ and Eu ³+ ions [J]. Phys-ica Status Solidi (c), 2017,14(1/2):1600146.
[36]	Wang J L, Song E H, Wu M , et al. Selectively enhanced up-and down-conversion emissions of Er ³+ via Yb ³+-Mn ²+ dimer sensitizing in spinel MgGa₂O₄:Er ³+,Yb ³+,Mn ²+ [J]. Materials Research Bulletin, 2016,74:340-345. doi: 10.1016/j.materresbull.2015.10.043
[37]	Li K Y, Xue D F . A new set of electronegativity scale for trivalent lanthanides[J]. Physica Status Solidi (b), 2007,244(6):1982-1987. doi: 10.1002/(ISSN)1521-3951
[38]	Pauling L. The nature of the chemical bond[M].3rd ed. New York: Cornell University Press, 1960.
[39]	Li K Y, Xue D F . Estimation of electronegativity values of elements in different valence states[J]. Journal of Physical Chemistry A, 2006,110(39):11332-11337. doi: 10.1021/jp062886k pmid: 17004743
[40]	Li K Y, Kang C Y, Xue D F . Effect of electrostatic and size on do-pant occupancy in lithium niobate single crystal[J]. Inorganic Che-mistry, 2013,52(17):10206-10210. doi: 10.1021/ic401805x pmid: 23967902

掺杂样品	激发波段/ nm	发射波段/ nm	应用
MgGa₂O₄： Cr^{3+[10,11,12,13,14]}	230	707	生物成像探针、可调谐激光器
MgGa₂O₄： Co^2+[19,20,21]	545	680	可调谐介质、高寿命光学器件
MgGa₂O₄： Dy^3+[26,27]	350	480、575、665	白色LED荧光粉
MgGa₂O₄：Eu^3+[28]	257	613	固态激光器件、低能量
MgGa₂O₄：Pr^3+[28]	247	497	激发荧光粉
MgGa₂O₄：Mn^2+[29]	300/532	501/642	绿色/红色光源材料、荧光显示器
MgGa₂O₄：Ni^2+[30]	974	1 260	近红外可调谐激光器
MgGa₂O₄： Co²⁺,Cr^3+[31]	585	680、700	红色光源材料
MgGa₂O₄： Er³⁺,Yb^3+[32]	980	522、545、 651、1 530	激光器、光纤放大器
MgGa₂O₄： Mn²⁺,Eu^2+[33]	254	503	等离子体显示器
MgGa₂O₄： Mn²⁺,Ce^3+[33]	254	503	等离子体显示器
MgGa₂O₄： Mn²⁺,Yb^3+[34]	976	507	高效光电器件
MgGa₂O₄： Mn²⁺,Eu^3+[35]	260	430、505、617	白光高效荧光粉
MgGa₂O₄：Er³⁺, Yb³⁺,Mn^2+[36]	980	507、1 500	温度传感器、光传输

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Research progress of metal element doped spinel type MgGa₂O₄

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