无机盐工业 ›› 2021, Vol. 53 ›› Issue (2): 17-23.doi: 10.11962/1006-4990.2020-0148
收稿日期:
2020-08-13
出版日期:
2021-02-10
发布日期:
2021-02-06
通讯作者:
李风亭
作者简介:
张彦星(1995— ),男,硕士研究生,主要研究方向为纳米环境材料制备及应用。
Zhang Yanxing1,Wu Yinan1,2,Li Fengting1,2()
Received:
2020-08-13
Online:
2021-02-10
Published:
2021-02-06
Contact:
Fengting Li
摘要:
金属有机框架化合物(Metal-organic frameworks,简称MOFs)是由金属离子(或簇)与有机配体配位并经由自组装而形成的一类多孔材料[1]。MOFs具有极其发达的孔道结构,比表面积和孔容远超其他多孔材料。有机/无机杂化这一特点也赋予了MOFs其他材料(例如沸石、活性炭等)所不具备的无限结构功能可调性[2]。此外,MOFs具有移除客体分子而主体框架完好保持的持久孔道或孔穴,这使得MOFs具有超乎寻常的化学及物理稳定性。正是基于以上这些特点,MOFs在许多领域有着丰富的应用[3-4],例如催化[5]、H2储存[6]、CO2捕集[7]、药物运输[8]、污染物吸附[9]、生物医学成像[10]等方面。MOFs的商业化探索成为了目前的热点。MOFs的很多应用都与可持续发展及“绿色材料”有关,但MOFs本身的合成过程也需要考虑可持续性和环境影响。金属有机化学所面临的环境挑战是独特的,因为它将金属离子、有机配体的危害联系在一起,且合成过程大多需要大量能耗。主要介绍了金属有机框架材料的绿色可持续合成,主要分为4个方面:1)使用更安全或生物相容性的配体;2)使用更绿色、低成本的金属源;3)绿色溶剂的开发;4)无溶剂合成法。
中图分类号:
张彦星,吴一楠,李风亭. 金属有机框架材料的绿色合成[J]. 无机盐工业, 2021, 53(2): 17-23.
Zhang Yanxing,Wu Yinan,Li Fengting. Synthesis of metal organic frameworks material[J]. Inorganic Chemicals Industry, 2021, 53(2): 17-23.
[1] |
Wang C, An B, Lin W. Metal-organic frameworks in solid-gas phase catalysis[J]. ACS Catalysis, 2018,9(1):130-146.
doi: 10.1021/acscatal.8b04055 |
[2] |
Ferey G. Some suggested perspectives for multifunctional hybrid po-rous solids[J].Dalton Trans.,2009(23):4400-4415.
doi: 10.1039/b817360p pmid: 19488432 |
[3] |
Kuppler R J, Timmons D J, Fang Q R, et al. Potential applications of metal-organic frameworks[J]. Coordination Chemistry Reviews, 2009,253(23/24):3042-3066.
doi: 10.1016/j.ccr.2009.05.019 |
[4] | Zou R, Abdel-Fattah A I, Xu H, et al. Storage and separation appli-cations of nanoporous metal-organic frameworks[J]. Cryst.Eng.Co-mm., 2010,12(5):1337-1353. |
[5] | Farrusseng D, Aguado S, Pinel C. Metal-organic frameworks:Oppor-tunities for catalysis[J]. Angew.Chem.Int.Ed.Engl., 2009,48(41):7502-7513. |
[6] | Hu Y H, Zhang L. Hydrogen storage in metal-organic frameworks[J]. Adv.Mater., 2010,22(20):E117-E130. |
[7] | Hedin N, Chen L, Laaksonen A. Sorbents for CO2 capture from flue gas—Aspects from materials and theoretical chemistry[J]. Nano-scale, 2010,2(10):1819-1841. |
[8] | Rojas S, Wheatley P S, Quartapelle-Procopio E, et al. Metal-organic frameworks as potential multi-carriers of drugs[J]. Cryst.Eng.Co-mm., 2013,15(45):9364-9367. |
[9] |
Qiu J, Feng Y, Zhang X, et al. Acid-promoted synjournal of UiO-66 for highly selective adsorption of anionic dyes:Adsorption perfor-mance and mechanisms[J]. J Colloid Interface Sci., 2017,499:151-158.
doi: 10.1016/j.jcis.2017.03.101 pmid: 28371674 |
[10] | Jung S, Kim Y, Kim S J, et al. Bio-functionalization of metal-organic frameworks by covalent protein conjugation[J]. Chem.Commun.Camb., 2011,47(10):2904-2906. |
[11] | Müller P, Bucior B, Tuci G, et al. Computational screening,synth-journal and testing of metal-organic frameworks with a bithiazole linker for carbon dioxide capture and its green conversion into cyclic carbonates[J]. Molecular Systems Design & Engineering, 2019,4(5):1000-1013. |
[12] |
Furukawa H, Cordova K E, O′Keeffe M, et al. The chemistry and applications of metal-organic frameworks[J]. Science, 2013,341(6149):1230444.
doi: 10.1126/science.1230444 pmid: 23990564 |
[13] |
Yaghi O M, O′Keeffe M, Ockwig N W, et al. Reticular synjournal and the design of new materials[J]. Nature, 2003,423(6941):705-714.
doi: 10.1038/nature01650 pmid: 12802325 |
[14] |
Sumida K, Rogow D L, Mason J A, et al. Carbon dioxide capture in metal-organic frameworks[J]. Chemical Reviews, 2012,112(2):724-781.
doi: 10.1021/cr2003272 pmid: 22204561 |
[15] | Kawano M, Kawamichi T, Haneda T, et al. The modular synjournal of functional porous coordination networks[J]. Journal of the Am-erican Chemical Society, 2007,129(50):15418-15419. |
[16] |
Yang Z, Zhang J, Kintner-Meyer M C W, et al. Electrochemical energy storage for green grid[J]. Chemical Reviews, 2011,111(5):3577-3613.
doi: 10.1021/cr100290v pmid: 21375330 |
[17] | Lee C Y, Farha O K, Hong B J, et al. Light-harvesting metal-organic frameworks(MOFs):Efficient strut-to-strut energy transfer in bo-dipy and porphyrin-based MOFs[J]. Journal of the American Che-mical Society, 2011,133(40):15858-15861. |
[18] |
Simons C, Hanefeld U, Arends I W C E, et al. Noncovalent anchor-ing of asymmetric hydrogenation catalysts on a new mesoporous aluminosilicate:Application and solvent effects[J]. Chemistry-A European Journal, 2004,10(22):5829-5835.
doi: 10.1002/(ISSN)1521-3765 |
[19] | Gaab M, Trukhan N, Maurer S, et al. The progression of Al-based metal-organic frameworks-From academic research to industrial production and applications[J]. Microporous and mesoporous ma-terials, 2012,157:131-136. |
[20] |
Frišcic T, Halasz I, Štrukil V, et al. Clean and efficient synjournal us-ing mechanochemistry:Coordination polymers,metal-organic fra-meworks and metallodrugs[J]. Croatica Chemica Acta, 2012,85(3):367-378.
doi: 10.5562/cca2014 |
[21] |
Ibarra I A, Bayliss P A, Pérez E, et al. Near-critical water,a clean-er solvent for the synjournal of a metal-organic framework[J]. Green Chemistry, 2012,14(1):117-122.
doi: 10.1039/c1gc15726d |
[22] | Sarawade P, Tan H, Polshettiwar V. Shape-and morphology-con-trolled sustainable synjournal of Cu,Co,and in metal organic frame-works with high CO2 capture capacity[J]. ACS Sustainable Chemi-stry & Engineering, 2013,1(1):66-74. |
[23] |
Stock N, Biswas S. Synjournal of metal-organic frameworks(MOFs):Routes to various MOF topologies,morphologies,and composit-es[J]. Chemical Reviews, 2012,112(2):933-969.
doi: 10.1021/cr200304e pmid: 22098087 |
[24] |
He Y, Zhou W, Qian G, et al. Methane storage in metal-organic fra-meworks[J]. Chemical Society Reviews, 2014,43(16):5657-5678.
doi: 10.1039/c4cs00032c |
[25] |
Suh M P, Park H J, Prasad T K, et al. Hydrogen storage in metal-organic frameworks[J]. Chemical Reviews, 2012,112(2):782-835.
doi: 10.1021/cr200274s pmid: 22191516 |
[26] |
Horcajada P, Gref R, Baati T, et al. Metal-organic frameworks in biomedicine[J]. Chemical Reviews, 2012,112(2):1232-1268.
doi: 10.1021/cr200256v pmid: 22168547 |
[27] | Llabrés I, Xamena F X, Corma A, et al. Applications for metal-or-ganic frameworks(MOFs) as quantum dot semiconductors[J]. Jo-urnal of Physical Chemistry C, 2007,111(1):80-85. |
[28] | Dhakshinamoorthy A, Asiri A M, Garcia H. Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts[J]. Catalysis Science & Technology, 2016,6(14):5238-5261. |
[29] |
Chen J, Shen K, Li Y. Greening the processes of metal-organic fra-mework synjournal and their use in sustainable catalysis[J]. Chem.Sus.Chem., 2017,10(16):3165-3187.
doi: 10.1002/cssc.201700748 pmid: 28589626 |
[30] | Czaja A, Leung E, Trukhan N, et al. Metal-organic frameworks:Applications from catalysis to gas storage[M]. Weinheim,Germany:Wiley-VCH Verlag GmbH, 2011. |
[31] | Mueller U, Schubert M, Teich F, et al. Metal-organic frameworks-Prospective industrial applications[J]. Journal of Materials Che-mistry, 2006,16(7):626-636. |
[32] |
Czaja A U, Trukhan N, Müller U. Industrial applications of metal-organic frameworks[J]. Chemical Society Reviews, 2009,38(5):1284-1293.
doi: 10.1039/b804680h pmid: 19384438 |
[33] |
Glavinovic M, Qi F, Katsenis A D, et al. Redox-promoted associa-tive assembly of metal-organic materials[J]. Chemical Science, 2016,7(1):707-712.
doi: 10.1039/c5sc02214b pmid: 28791114 |
[34] |
Horcajada P, Chalati T, Serre C, et al. Porous metal-organic-frame-work nanoscale carriers as a potential platform for drug delivery and imaging[J]. Nature Materials, 2010,9(2):172-178.
doi: 10.1038/nmat2608 pmid: 20010827 |
[35] |
Huxford R C, Della Rocca J, Lin W. Metal-organic frameworks as potential drug carriers[J]. Current Opinion in Chemical Biology, 2010,14(2):262-268.
doi: 10.1016/j.cbpa.2009.12.012 |
[36] |
Huskic I, Pekov I V, Krivovichev S V, et al. Minerals with metal-organic framework structures[J]. Science Advances, 2016,2(8):e1600621.
doi: 10.1126/sciadv.1600621 pmid: 27532051 |
[37] |
Sánchez-Sánchez M, Getachew N, Díaz K, et al. Synjournal of metal-organic frameworks in water at room temperature:Salts as linker sources[J]. Green Chemistry, 2015,17(3):1500-1509.
doi: 10.1039/C4GC01861C |
[38] |
Dreischarf A C, Lammert M, Stock N, et al. Green synjournal of Zr-CAU-28:Structure and properties of the first Zr-MOF based on 2,5-furandicarboxylic acid[J]. Inorganic Chemistry, 2017,56(4):2270-2277.
doi: 10.1021/acs.inorgchem.6b02969 pmid: 28165722 |
[39] |
Rose M, Weber D, Lotsch B V, et al. Biogenic metal-organic frame-works:2,5-furandicarboxylic acid as versatile building block[J]. Microporous and Mesoporous Materials, 2013,181:217-221.
doi: 10.1016/j.micromeso.2013.06.039 |
[40] |
Crawford D E, Casaban J. Recent developments in mechanochemi-cal materials synjournal by extrusion[J]. Advanced Materials, 2016,28(27):5747-5754.
doi: 10.1002/adma.201505352 pmid: 26932541 |
[41] |
Rubio-Martinez M, Hadley T D, Batten M P, et al. Scalability of continuous flow production of metal-organic frameworks[J]. Chem.Sus.Chem., 2016,9(9):938-941.
doi: 10.1002/cssc.201501684 pmid: 27075923 |
[42] |
Wißmann G, Schaate A, Lilienthal S, et al. Modulated synjournal of Zr-fumarate MOF[J]. Microporous and Mesoporous Materials, 2012,152:64-70.
doi: 10.1016/j.micromeso.2011.12.010 |
[43] | Werpy T, Petersen G. Top value added chemicals from biomass:Volume Ⅰ-results of screening for potential candidates from sugars and synreport gas[R].Golden,CO(US):National Renewable En-ergy Lab., 2004. |
[44] |
Wang Z, Liu H, Wang S, et al. A luminescent Terbium-succinate MOF thin film fabricated by electrodeposition for sensing of Cu2+ in aqueous environment[J]. Sensors and Actuators B:Chemical, 2015,220:779-787.
doi: 10.1016/j.snb.2015.05.129 |
[45] | Liu J Q, Wang Y Y, Liu P, et al. A novel 3D twofold interpenetrat-ing microporous metal-organic framework containing 1D water ta-pes with cyclic pentamer units[J]. Inorganic Chemistry Communi-cations, 2007,10(3):343-347. |
[46] |
Cliffe M J, Mottillo C, Stein R S, et al. Accelerated aging:A low en-ergy,solvent-free alternative to solvothermal and mechanochemi-cal synjournal of metal-organic materials[J]. Chemical Science, 2012,3(8):2495-2500.
doi: 10.1039/c2sc20344h |
[47] |
Guillerm V, Gross S, Serre C, et al. A zirconium methacrylate oxo-cluster as precursor for the low-temperature synjournal of porous zirconium(Ⅳ) dicarboxylates[J]. Chemical communications, 2010,46(5):767-769.
doi: 10.1039/b914919h pmid: 20087514 |
[48] | Deleu W P R, Stassen I, Jonckheere D, et al. Waste PET (bottles)as a resource or substrate for MOF synjournal[J]. Journal of Materi-als Chemistry A, 2016,4(24):9519-9525. |
[49] |
Lo S H, Raja D S, Chen C W, et al. Waste polyethylene terephtha-late(PET) materials as sustainable precursors for the synjournal of nanoporous MOFs,MIL-47,MIL-53(Cr,Al,Ga) and MIL-101 (Cr)[J]. Dalton Transactions, 2016,45(23):9565-9573.
doi: 10.1039/c6dt01282e pmid: 27198203 |
[50] |
Ren J, Dyosiba X, Musyoka N M, et al. Green synjournal of chromi-um-based metal-organic framework(Cr-MOF) from waste polyet ethylene terephthalate(PET) bottles for hydrogen storage applica-tions[J]. International Journal of Hydrogen Energy, 2016,41(40):18141-18146.
doi: 10.1016/j.ijhydene.2016.08.040 |
[51] |
Hawxwell S M, Brammer L. Solvent hydrolysis leads to an unusual Cu(Ⅱ) metal-organic framework[J]. Cryst.Eng.Comm., 2006,8(6):473-476.
doi: 10.1039/b603274e |
[52] |
Al-Ghoul M, Issa R, Hmadeh M. Synjournal,size and structural ev-olution of metal-organic framework-199 via a reaction-diffusion process at room temperature[J]. Cryst.Eng.Comm., 2017,19(4):608-612.
doi: 10.1039/C6CE02436J |
[53] |
Hou S, Wu Y N, Feng L, et al. Green synjournal and evaluation of iron-based metal-organic framework MIL-88B for the efficient de-contamination of arsenate from water[J]. Dalton Transactions, 2018.Doi: 10.1039.C7DT03775A.
doi: 10.1039/d0dt04061d pmid: 33523054 |
[54] |
Capello C, Fischer U, Hungerbühler K. What is a green solvent? A comprehensive framework for the environmental assessment of sol-vents[J]. Green Chemistry, 2007,9(9):927-934.
doi: 10.1039/b617536h |
[55] | Martins G A V, Byrne P J, Allan P, et al. The use of ionic liquids in the synjournal of zinc imidazolate frameworks[J]. Dalton Transac-tions, 2010,39(7):1758-1762. |
[56] |
Jessop P G. Searching for green solvents[J]. Green Chemistry, 2011,13(6):1391-1398.
doi: 10.1039/c0gc00797h |
[57] |
Parnham E R, Morris R E. Ionothermal synjournal of zeolites,metal-organic frameworks,and inorganic-organic hybrids[J]. Accounts of Chemical Research, 2007,40(10):1005-1013.
doi: 10.1021/ar700025k pmid: 17580979 |
[58] |
Lin J B, Lin R B, Cheng X N, et al. Solvent/additive-free synjournal of porous/zeolitic metal azolate frameworks from metal oxide/hydro-xide[J]. Chemical Communications, 2011,47(32):9185-9187.
doi: 10.1039/c1cc12763b |
[59] |
Do J L, Friscic T. Mechanochemistry:A force of synjournal[J]. ACS Central Science, 2017,3(1):13-19.
doi: 10.1021/acscentsci.6b00277 pmid: 28149948 |
[60] |
Frišcic T, Fábián L. Mechanochemical conversion of a metal oxide into coordination polymers and porous frameworks using liquid-assisted grinding(LAG)[J]. Cryst.Eng.Comm., 2009,11(5):743-745.
doi: 10.1039/b822934c |
[61] |
Frišcic T, Reid D G, Halasz I, et al. Ion-and liquidšassisted grin-ding:Improved mechanochemical synjournal of metal-organic frame-works reveals salt inclusion and anion templating[J]. Angewandte Chemie International Edition, 2010,49(4):712-715.
doi: 10.1002/anie.200906583 pmid: 20017178 |
[62] | Bennett T D, Cao S, Tan J C, et al. Facile mechanosynjournal of am-orphous zeolitic imidazolate frameworks[J]. Journal of the Ameri-can Chemical Society, 2011,133(37):14546-14549. |
[63] |
Bennett T D, Cheetham A K. Amorphous metal-organic framewo-rks[J]. Accounts of Chemical Research, 2014,47(5):1555-1562.
doi: 10.1021/ar5000314 |
[64] |
Kaur P, Hupp J T, Nguyen S T. Porous organic polymers in cataly-sis:Opportunities and challenges[J]. Acs Catalysis, 2011,1(7):819-835.
doi: 10.1021/cs200131g |
[1] | 赵闯,李犇,范景新,臧甲忠,马浴铭,李滨,孙振海,宫毓鹏,于海斌. 多孔材料烷烃/烯烃分离技术的研究[J]. 无机盐工业, 2019, 51(8): 79-82. |
[2] | 刘玉欣1,石凤娟2,吕耀辉1,魏世丞1,王玉江1,何东昱1,王文宇1. 纳米或多孔氧化铬粒子制备的研究进展[J]. 无机盐工业, 2019, 51(10): 1-6. |
[3] | 王东镇, 梁生荣, 申志兵, 崔生航. ZSM-5的合成及应用进展[J]. 无机盐工业, 2016, 48(5): 1-. |
[4] | 戴川涛, 戴惠良. 新型国产双氧水浓缩工艺技术的实现[J]. 无机盐工业, 2012, 44(7): 38-. |
[5] | 戴洪兴, 邓积光, 张磊, 赵振璇, 王国志, 刘彩欣, 李惠宁. 软、硬模板合成多孔氧化镁、氧化钙和碳酸钙[J]. 无机盐工业, 2011, 43(5): 18-. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||
|