无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (6): 10-.

• 论文 • 上一篇    下一篇

双水相体系萃取分离金属离子研究进展

张永强1,2,孙体昌1,郭 清2,侯青霞2,郭英超2,卢铁强2,燕春环2   

  1. 1.北京科技大学土木与环境工程学院,北京 100083;2.燕山大学环境与化学工程学院
  • 出版日期:2016-06-10 发布日期:2016-06-02

Research progress on extraction and separation of metal ions with aqueous two-phase system

Zhang Yongqiang1,2,Sun Tichang1,Guo Qing2,Hou Qingxia2,Guo Yingchao2,Lu Tieqiang2,Yan Chunhuan2   

  1. 1.School of Civil and Environmental Engineering,Beijing Science and Technology University,Beijing 100083,China;
    2.College of Environmental and Chemical Engineering,Yanshan University
  • Online:2016-06-10 Published:2016-06-02

摘要: 双水相体系是一种绿色环保的新型分离技术,应用领域相当广泛,是近年来的研究热点。论述了双水相体系用于萃取分离金属离子的研究现状。根据所使用萃取剂的不同分3种情况进行了论述:不添加任何萃取剂直接萃取金属离子;以无机阴离子为萃取剂,依靠金属阳离子与无机阴离子形成的阴离子配合物(螯合物)而转移到萃取相,萃取金属离子;采用有机试剂作为萃取剂,依靠金属离子与萃取剂反应形成的中性配合物(螯合物)而转移到萃取相,萃取金属离子。论述了双水相体系萃取分离金属离子的发展趋势:建立金属离子在双水相体系中分配的机理模型;双水相体系成相物质的回收及再利用;通过无机盐水化能力的差异,或者通过双水相体系的温度诱导相分离,实现无机盐的分离与常温制备;开展双水相体系萃取分离金属离子的工程研究。

关键词: 双水相体系, 研究进展, 金属离子

Abstract: Aqueous two-phase system(ATPS) is a green,environmentally friendly,new separation technology and is of wide application prospect,and becomes an advanced research hotspot in recent years.It is discussed about the application research situation in extracting and separating metal ions by ATPS,which is divided into three aspects according to different extracting agents:directly extracting metal ion without any extracting agent,extracting metal ion complex by forming anion complex(chelate) between metal cation and inorganic anion extracting agent and metal cation and organic reagent extracting agent. The development tendency of extracting and separating metal ions by ATPS is predicted from four aspects:the first is to establish mechanism model of metal ions partition by ATPS;the second is to recover and recycle phase-forming substance of ATPS;the third is to achieve separation and normal temperature preparation of inorganic salts by hydration ability difference of inorganic salts or by temperature-induced phase separation of ATPS;and the fourth is to develop engineering research of extracting and separating metal ions by ATPS.

Key words: aqueous two-phase system, research progress, metal ions

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