石墨烯的制备及其应用研究进展

摘要/Abstract

摘要：

石墨烯具有独特的二维原子晶体结构以及众多优异性能,如高机械强度、高载流子迁移率、高光学透明性等,这些优异的力学、电学和光学等特性使得石墨烯成为化学、物理学和材料学等领域的研究热点。结合近几年国内外研究现状,综述了机械剥离法、化学剥离法和化学气相沉积法等3种制备石墨烯的方法,并分析了各种方法的优点和不足之处。介绍了石墨烯的应用研究进展,并对其未来的发展进行了展望。

关键词: 石墨烯制备, 化学气相沉积法, 应用研究进展

Abstract:

Graphene has a unique two-dimensional crystal structure and many excellent features,such as extraordinary mech-anical strength,high charge carrier mobility,and high optical transparency.Graphene,which possesses remarkable mechani-cal,electrical,and optical properties,has become a research hotspot in the fields of chemistry,physics and materials science.Combined with domestic and foreign researches in recent years,three main methods for preparing graphene,including mech-anical stripping,chemical exfoliation and chemical vapor deposition were reviewed.At the same time,the advantages and disadvantages of these methods were discussed.Finally,the research progress of application of graphene was introduced and its future development was prospected.

Key words: graphene preparation, chemical vapor deposition, application research progress

中图分类号:

O613.71

杜淼,张光荣. 石墨烯的制备及其应用研究进展[J]. 无机盐工业, 2019, 51(3): 12-15.

Du Miao,Zhang Guangrong. Progress in preparation and application of graphene[J]. Inorganic Chemicals Industry, 2019, 51(3): 12-15.

参考文献 38

[1]	Geim A K, Novoselov K S . The rise of graphene[J]. Nature Materials, 2007,6(3):183-191. doi: 10.1038/nmat1849 pmid: 17330084
[2]	Novoselov K S, Geim A K . Electric field effect in atomically thin car-bon films[J]. Science, 2004,306(5696):666-669. doi: 10.1126/science.1102896 pmid: 15499015
[3]	Geim A K . Graphene:status and prospects[J]. Science, 2009,324(5934):1530-1534. doi: 10.1126/science.1158877 pmid: 19541989
[4]	Wu J S, Pisula W, Müllen K . Graphenes as potential material for electronics[J]. Chemical Reviews, 2007,107(3):718-747. doi: 10.1021/cr068010r pmid: 17291049
[5]	Rao C N R, Sood A K . Some novel attributes of graphene[J]. Journal of Physical Chemistry Letters, 2010,1(2):572-580. doi: 10.1021/jz9004174
[6]	Allen M J, Tung V C, Kaner R B . Honeycomb carbon:a review of graphene[J]. Chemical Reviews, 2010,110(1):132-145. doi: 10.1021/cr900070d pmid: 19610631
[7]	刘义林, 高原, 鲍建设 , 等. 功能化石墨烯掺杂熔盐的制备及性能研究[J]. 无机盐工业, 2016,48(7):16-20.
[8]	Lee C . Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science, 2008,321(5887):385-388. doi: 10.1126/science.1157996 pmid: 18635798
[9]	van den Brink J . Graphene:from strength to strength[J]. Nature Nano-technology, 2007,2(4):199-201.
[10]	Mayorov A S, Gorbachev R V, Morozov S V , et al. Micrometer-scale ballistic transport in encapsulated graphene at room tempera-ture[J]. Nano Letters, 2011,11(6):2396-2399. doi: 10.1021/nl200758b pmid: 21574627
[11]	Solís-Fernández P, Bissett M, Ago H . Synjournal,structure and ap-plications of graphene-based 2D heterostructures[J]. Chemistry Society Reviews, 2017,46(15):4572-4613. doi: 10.1039/c7cs00160f pmid: 28691726
[12]	Jan R, Habib A, Akram M A , et al. Uniaxial drawing of graphene-PVA nanocomposites:improvement in mechanical characteristics via strain-induced exfoliation of graphene[J]. Nanoscale Research Letters, 2016,11(1):3771-3779. doi: 10.1186/s11671-016-1595-2 pmid: 27558496
[13]	Lin Z, Karthik P S . Simple technique of exfoliation and dispersion of multilayer graphene from natural graphite by ozone-assisted sonication[J]. Nanomaterials, 2017,7(6):12501-12510. doi: 10.3390/nano7060125 pmid: 28555015
[14]	Brodie B C .On the atomic weight of graphite[J].Philosophical Tr-ansactions of the Royal Society of London, 1859,149:249-259.
[15]	Staudenmaier L .Verfahren zur darstellung der graphitsäure[J].Berichte der Deutschen Chemischen Gesellschaft, 1898,31(2):1481-1487. doi: 10.1002/(ISSN)1099-0682
[16]	Hummers Jr W S, Offeman R E . Preparation of graphitic oxide[J]. Journal of the American Chemical Society, 1958,80(6):1339. doi: 10.1021/ja01539a017
[17]	Li D, Müller M B, Gilje S , et al. Processable aqueous dispersion of graphene nanosheets[J]. Nature Nanotechnology, 2008,3:101-105. doi: 10.1038/nnano.2007.451 pmid: 18654470
[18]	Fu W Z, Zhang Z Q . One-pot hydrothermal synjournal of magneti-cally recoverable palladium/reduced graphene oxide nanocompo-sites and its catalytic applications in cross-coupling reactions[J]. Journal of Colloid and Interface Science, 2017,497:83-92. doi: 10.1016/j.jcis.2017.02.063 pmid: 28273514
[19]	Kumar R, Singh R K, Vaz A R , et al. Self-assembled and one-step synjournal of interconnected 3D network of Fe₃O₄/reduced grapheneoxide nanosheets hybrid for high-performance supercapacitor elec-trode[J]. ACS Applied Materials & Interfaces, 2017,9:8880-8890. doi: 10.1021/acsami.6b14704 pmid: 28225588
[20]	Song J, Kang S W . Regulating the catalytic function of reduced gr-aphene oxides using capping agents for metal-free catalysis[J]. ACS Applied Materials & Interfaces, 2017,9:1692-1701. doi: 10.1021/acsami.6b13970 pmid: 27991751
[21]	Peng L, Xu Z, Liu Z , et al. An iron-based green approach to 1-hproduction of single-layer graphene oxide[J]. Nature Communica-tions, 2015,6:57161-57169. doi: 10.1038/ncomms6716 pmid: 25607686
[22]	Babichev A V, Rykov S A, Tchernycheva M , et al. Influence of su-bstrate microstructure on the transport properties of CVD-grap-hene[J]. ACS Applied Materials & Interfaces, 2016,8:240-246. doi: 10.1021/acsami.5b08479 pmid: 26652757
[23]	Hemasiri B W N H, Kim J K, Lee J M . Fabrication of highly conduc-tive graphene/ITO transparent bi-film through CVD and organic additives-free sol-gel techniques[J]. Scientific Reports, 2017,7:1786801-1786812. doi: 10.1038/s41598-017-18063-w pmid: 29259236
[24]	Komissarov I V, Kovalchuk N G . Nitrogen-doped twisted graphene grown on copper by atmospheric pressure CVD from a decane pre-cursor[J]. Beilstein Journal of Nanotechnology, 2017,8:145-158. doi: 10.3762/bjnano.8.15 pmid: 28243551
[25]	Pasternak I . Graphene growth on Ge(100)/Si(100) substrates by CVD method[J]. Scientific Reports, 2016,6:217731-217737. doi: 10.1038/srep21773 pmid: 26899732
[26]	Li J H, Wang G, Geng H , et al. CVD growth of graphene on NiTi al-loy for enhanced biological activity[J]. ACS Applied Materials & Interfaces, 2015,7:19876-19881. doi: 10.1021/acsami.5b06639 pmid: 26323051
[27]	Du Y, Li N, Zhang T L , et al. Reduced graphene oxide coating with anticorrosion and electrochemical property-enhancing effects ap-plied in hydrogen storage system[J]. ACS Applied Materials & Interfaces, 2017,9:28980-28989. doi: 10.1021/acsami.7b05809 pmid: 28776973
[28]	Wan L F, Liu Y S, Cho E S , et al. Atomically thin interfacial subo-xide key to hydrogen storage performance enhancements of magne-sium nanoparticles encapsulated in reduced graphene oxide[J]. Nano Letters, 2017,17:5540-5545. doi: 10.1021/acs.nanolett.7b02280 pmid: 28762272
[29]	Cho E S, Ruminski A M . Graphene oxide/metal nano-crystal multil-aminates as the atomic limit for safe and selective hydrogen stora-ge[J]. Nature Communications, 2016,7:108041-108047.
[30]	Kim S, Kim S K . Reduced graphene oxide/LiI composite lithiumion battery cathodes[J]. Nano Letters, 2017,17:6893-6899. doi: 10.1021/acs.nanolett.7b03290 pmid: 29053279
[31]	Chang P, Liu X X . Constructing three-dimensional honeycombed graphene/silicon skeletons for high-performance Li-ion batteri-es[J]. ACS Applied Materials & Interfaces, 2017,9:31879-31886. doi: 10.1021/acsami.7b09169 pmid: 28840710
[32]	Mo R W, Rooney D, Sun K N , et al. 3D nitrogen-doped graphene foam with encapsulated germanium/nitrogen-doped graphene yolk-shell nanoarchitecture for high-performance flexible Li-ion batt-ery[J]. Nature Communications, 2017,8:139491-139499. doi: 10.1038/ncomms13949 pmid: 28051065
[33]	Russier J, León V, Orecchioni M , et al. Few-layer graphene kills selectively tumor cells from myelomonocytic leukemia patients[J]. Angewandte Chemie International Edition, 2017,56:3014-3019. doi: 10.1002/anie.201700078 pmid: 28156035
[34]	Dai C . Two-dimensional graphene augments nanosonosensitized so-nocatalytic tumor eradication[J]. ACS Nano, 2017,11:9467-9480. doi: 10.1021/acsnano.7b05215 pmid: 28829584
[35]	Zhu J Q, Xu M . Graphene oxide induced perturbation to plasma membrane and cytoskeletal meshwork sensitize cancer cells to chemotherapeutic agents[J]. ACS Nano, 2017,11:2637-2651. doi: 10.1021/acsnano.6b07311 pmid: 28208020
[36]	Chen Y Y, Song X H . A phosphorylethanolamine-functionalized super-hydrophilic 3D graphene-based foam filter for water purifica-tion[J]. Journal of Hazardous Materials, 2018,343:298-303. doi: 10.1016/j.jhazmat.2017.09.045 pmid: 28988055
[37]	Xu W L, Fang C, Zhou F L , et al. Self-assembly:a facile way of form-ing ultrathin,high-performance graphene oxide membranes for wa-ter puriflcation[J]. Nano Letters, 2017,17:2928-2933. doi: 10.1021/acs.nanolett.7b00148 pmid: 28388082
[38]	Zhu C T, Liu P, Mathew A P . Self-assembled TEMPO cellulose nano-flbers:Graphene oxide-based biohybrids for water puriflcation[J]. ACS Applied Materials & Interfaces, 2017,9:21048-21058. doi: 10.1021/acsami.7b06358 pmid: 28557432

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