无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (9): 23-.

• 论文 • 上一篇    下一篇

铜镁铝类水滑石插层改性及摩擦性能研究

赵 维,李玉红   

  1. 咸阳师范学院化学与化工学院,陕西咸阳 712000
  • 出版日期:2016-09-10 发布日期:2016-09-18

Study on intercalating modification and friction performance of Cu-Mg-Al  hydrotalcite-like  compounds

 ZHAO   Wei, LI  Yu-Hong   

  1. College of Chemistry and Chemical Engineering,Xianyang Normal University,Xianyang 712000,China
  • Online:2016-09-10 Published:2016-09-18

摘要: 采用液相共沉淀法制备了铜镁铝类水滑石,选用十二烷酸(月桂酸)作为改性剂以离子交换法对类水滑石进行插层改性。借助红外光谱仪对改性前后类水滑石进行成分、结构、形貌分析与表征。实验结果表明,制得的类水滑石为Cu-Mg-Al-CO3、改性类水滑石为Cu-Mg-Al-月桂酸。将改性前后类水滑石以3%(质量分数)的比例添加到摩擦材料的基础配方中制成摩擦片,利用XD-MSM定速式摩擦试验机测试添加改性前后类水滑石制得摩擦材料的摩擦系数随温度的变化规律,用静水力学密度仪测试摩擦片的密度。结果表明,将未改性类水滑石加入摩擦材料中可以降低摩擦材料的摩擦系数,而加入改性类水滑石,因粒径膨胀,使得摩擦材料的摩擦系数有所增大;改性的类水滑石可以降低摩擦片的密度。

关键词: 类水滑石, 插层改性, 摩擦系数, 月桂酸

Abstract:  of Chemistry and Chemical Engineering,Xianyang Normal University,Xianyang 712000,China) Abstract:Cu-Mg-Al hydrotalcite-like compound was prepared by liquid phase co-precipitation method,and intercalating modification was also made by ion exchange method with lauric acid as the modifier.The composition, structure and morphol- ogy of hydrotalcite-like compound before and after the modification were characterized and analyzed by infrared spectrometer. Results showed that the product was Cu-Mg-Al-CO3 hydrotalcite and the modified product was Cu-Mg-Al-lauric hydrotal- cite.The modified and un-modified hydrotalcite were added in a proportion of 3%(mass fraction) respectively to the base for- mulation to prepare a friction lining materials.The law of friction coefficient of those prepared friction lining materials changed with temperature was tested by XD-MSM constant speed friction tester.The density of friction lining materials was also tested by hydrostatic densitometer.Results showed that un-modified hydrotalcite adding into the friction lining materials could reduce the friction coefficient,however,the modified one could increase the friction coefficient due to the expansion of particle size;and the modified one could also reduce the density of friction lining materials.

Key words: hydrotalcite-like compound, intercalating modification, friction factor, lauric acid

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