无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (8): 43-.

• 论文 • 上一篇    下一篇

制备工艺对溶胶-凝胶法制备BeFeO3薄膜的影响

李三喜1,2,宋德智 1,张文政1,王 趱1,李天生1   

  1. 1.沈阳化工大学材料科学与工程学院,辽宁沈阳110142;2.沈阳工业大学
  • 出版日期:2016-08-10 发布日期:2016-08-10

Effect of preparation process on the preparation of BiFeO3 film by sol-gel process

Li Sanxi1,2,Song Dezhi1,Zhang Wenzheng1,Wang Zan1,Li Tiansheng1   

  1. 1.Shenyang University of Chemical Technology,Shenyang 110142,China;2.Shenyang University of Technology
  • Online:2016-08-10 Published:2016-08-10

摘要: 利用溶胶-凝胶法在Pt/Ti/SiO2/Si基体上制备了BiFeO3薄膜,构架了Pt/BiFeO3/Pt电容器。对不同退火温度和保温时间制备薄膜的微观形貌和铁电性能做了研究。X射线衍射仪(XRD)结果显示,不同的退火温度和保温时间并没有改变BiFeO3(BFO)的钙钛矿结构,但温度的改变会产生不同的晶相。通过扫描电子显微镜(FE-SEM)可以观察到,随着烧结保温时间的延长,薄膜晶粒有减小的趋势。P-E曲线结果表明,BFO薄膜在外加电场较高时易击穿,难以得到清晰饱和的电滞回线。

关键词: 铁酸铋薄膜, 退火温度, 保温时间, 微观形貌, 铁电性能

Abstract: BiFeO3 film was prepared on Pt/Ti/SiO2/Si substrate by sol-gel method,framing the Pt/BiFeO3/Pt capacitor.The mi- crostructure and ferroelectric properties of the films prepared by different annealing temperatures and holding times were studied.X ray diffraction(XRD) results showed that different annealing temperatures and holding times did not change the BiFeO3(BFO) bulk perovskite structure,but the change of temperature will produce different crystal phases.By scanning electron microscopy(FE-SEM),it could be observed that the grain size had a decrease trend with the increase of the sintering holding time.P-E curves showed that BFO film was easy to breakdown when the applied electric field was high,and it was  difficult to get a clear saturated hysteresis loop.

Key words: bismuth ferrite thin film, annealing temperature, holding time, microstructure, ferroelectric properties

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