无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (6): 38-.

• 论文 • 上一篇    下一篇

硬脂酸-钛酸酯偶联剂改性重质碳酸钙粉体研究

王 友,曾一文,覃康玉,汤 泉   

  1. 贺州学院化学与生物工程学院,广西贺州 542899
  • 出版日期:2016-06-10 发布日期:2016-06-02

Study on modification of ground calcium carbonate by stearic acid and titanate coupling agent

 WANG   You, ZENG  Yi-Wen, QIN  Kang-Yu, TANG   Quan   

  1. College of Chemical and Biological Engineering,Hezhou University,Hezhou 542899,China
  • Online:2016-06-10 Published:2016-06-02

摘要: 以硬脂酸和钛酸酯偶联剂为复合改性剂,无水乙醇为分散剂,采用湿球磨法对重质碳酸钙粉体进行改性。以活化度为评价指标,通过单因素实验考察球磨时间、球磨转速、改性剂用量、改性剂配比对改性效果的影响。通过正交实验进一步优化得到改性工艺条件:球磨时间为1.5 h、球磨转速为350 r/min、改性剂用量为2.0%(质量分数)、m(硬脂酸)∶m(钛酸酯偶联剂)=1∶3。在优化条件下,改性样品活化度为99.4%、吸油值为14.27 g(以100 g改性样品计)、沉降体积为1.08 mL/g、粒度D50为1.58 μm。

关键词: 重质碳酸钙, 硬脂酸, 钛酸酯偶联剂, 湿球磨法, 活化度

Abstract: Ground calcium carbonate powder(GCC) was modified by wet ball milling method, using stearic acid(SA) and ti- tanate coupling agent(TCA) as composite modifier,and with ethanol as dispersant.The influences of ball-milling time,rotat- ing speed of ball-milling,modifier amounts,and mix ratios of modifiers on the modifying effect were investigated by single factor tests,using activation grade as evaluating index.Furthermore,the optimal modifying conditions were achieved by ortho- gonal experiment as follows:ball-milling time was 1.5 h,rotating speed of ball-milling was 350 r/min,modifier amount was 2.0%(mass fraction),and m(SA):m(TCA)=1:3.The performances of the modified sample under these conditions were as fol- lows:activation grade was 99.4%,oil absorption value was 14.27 g per 100 g modified samples,sedimentation volume was 1.08 mL/g,and particle size D50 was 1.58 μm.

Key words: ground calcium carbonate, stearic acid, titanate coupling agent, wet ball milling method, activation grade

中图分类号: