无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (4): 17-.

• 论文 • 上一篇    下一篇

用于敏化太阳能电池的二氧化钛光阳极材料

陈文民1,闵 建2,赵永彬3   

  1. 1.中国中煤能源集团有限公司,北京100120;2.国电龙源节能技术有限公司;3.北京低碳清洁能源研究所先进材料研发中心
  • 出版日期:2016-04-10 发布日期:2016-04-27

TiO2 photoanode materials for the sensitized solar cells

Chen Wenmin1,Min Jian2,Zhao Yongbin3   

  1. 1.China National Coal Group Corp.,Beijing 100120,China;2.GD Longyuan Energy Saving Technology Co.,Ltd.;
    3.Advance Materials R&D Center,National Institute of Clean and Low-Carbon Energy
  • Online:2016-04-10 Published:2016-04-27

摘要: 敏化太阳能电池是当前清洁能源领域的研究热点之一,有望成为第三代太阳能电池。二氧化钛作为敏化太阳能电池的光阳极材料之一被广泛研究。主要综述了近20 a来二氧化钛光阳极材料的结构进展,并从电子注入效率、电子传输和基底电荷收集效率方面评述了各种结构的应用特点。另外,描述了当代三明治状二氧化钛工作电极的超薄保形覆盖层、工作层和阻挡层。然后,重点介绍了用于电子传输工作层的二氧化钛一维纳米阵列的制备方法及特点。最后,展望了光阳极结构与合成方法的未来发展趋势。

关键词: 敏化太阳能电池, 电子传输, 三明治状二氧化钛

Abstract: Sensitized solar cell is one of the hot research topics in the field of clean energy,emerging as the most promising photovoltaic device for the third-generation solar cells.As one of the photoelectrodes for sensitized solar cell,titanium dioxide has been widely studied.Therefore,the structural progress of TiO2 photoanodes in two decades was mainly summarized.The application characteristics of various structures were reviewed and discussed from the aspects of electron injection efficiency,electron-transporting,and basal charge collection efficiency.For state-of-the-art TiO2 photoelectrode,the sandwich-like archi- tecture consisted of a TiO2 ultrathin conformal overcoating layer,a TiO2 working layer,and a TiO2 blocking layer.Following was an overview of techniques and characteristics for fabricating titanium dioxide one dimensional nanoarrays in the TiO2 working layer.Finally,the trends of ideal TiO2-based photoanode structures and possible synthetic approaches were proposed.

Key words: sensitized solar cells, electron transport, sandwich titanium dioxide

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