无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (4): 13-.

• 论文 • 上一篇    下一篇

次磷酸钙生产工艺与展望

曹洪玉,周 桓   

  1. 天津科技大学海洋与环境学院,天津市海洋资源与化学重点实验室,天津 300457
  • 出版日期:2016-04-10 发布日期:2016-04-27

Calcium hypophosphite production technology and prospect

 CAO  Hong-Yu, ZHOU   Huan   

  1. Tianjin Key Laboratory of Marine Resources and Chemistry,College of Marine and Environmental Sciences,
    Tianjin University of Science & Technology,Tianjin 300457,China
  • Online:2016-04-10 Published:2016-04-27

摘要: 对次磷酸钙的应用拓展、生产工艺和发展趋势进行了研究。着重介绍了5种制取次磷酸钙的方法,包括:黄磷与石灰乳反应法、中和法、氯化钙与次磷酸钠转化法、硝酸钙与次磷酸钠反应法、液相催化法。并对每种工艺的原料、原理、优缺点及推广应用情况进行了详细的剖析,以期对促进次磷酸钙产业的发展提供参考。

关键词: 次磷酸钙, 生产工艺, 前景分析

Abstract: The application development,production technology,and development trend of calcium hypophosphite were sum- marized and analyzed.Five kinds of preparation methods of calcium hypophosphite,such as yellow phosphorus and lime reaction method,neutralization method,calcium chloride and sodium hypophosphite reforming process,calcium chloride and sodium hypophosphite reaction conversion method,and liquid-phase catalysis method,were introduced emphatically.Moreover,raw materials,principles,advantages and disadvantages as well as application situations of each process were analyzed in detail,and the reference for the promotion of development of calcium hypophosphite industry was provided.

Key words: calcium hypophosphite, production process, prospect analysis.

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