无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (5): 64-.

• 论文 • 上一篇    下一篇

ICP-OES法测定碱式碳酸钴中镍、铜、铁、钠、锌、钙

胡昌文1,刘元生1,刘 念1,陈小娟1,弓创周2   

  1. 1.江西核工业兴中科技有限公司,江西南昌 330002;2.中海油天津化工研究设计院
  • 出版日期:2015-05-10 发布日期:2015-05-06

Determination of nickel,copper,iron,sodium,zinc,and calcium in basic cobalt carbonate by ICP-OES method

Hu Changwen1,Liu Yuansheng1,Liu Nian1,Chen Xiaojuan1,Gong Chuangzhou2   

  1. 1.Jiangxi Nuclear Industry Xingzhong Technology Co.,Ltd.,Nanchang 330002,China;
    2.CNOOC Tianjin Chemical Research & Design Institute
  • Online:2015-05-10 Published:2015-05-06

摘要: 用电感耦合等离子体发射光谱法(ICP-OES)测定碱式碳酸钴中镍、铜、铁、钠、锌、钙等杂质的含量,并对测定条件及工作参数做了研究,采用标准加入法消除基体效应的影响,通过选择适宜的分析谱线以消除光谱的干扰。与原子吸收分光光度计法(AAS)相比,ICP-OES法的分析速度快、精密度高。

关键词: 电感耦合等离子体发射光谱法, 标准加入法, 光谱干扰, 碱式碳酸钴

Abstract: The analysis method for determination of the impurities,such as nickel,copper,iron,sodium,zinc,and calcium, in basic cobalt carbonate based on the inductively coupled plasma optical emission spectrometry(ICP-OES) has been pres- ented.The determination conditions and operating parameters were also investigated.The standard addition method was adopted to remove matrix effect,and appropriate spectral line was selected to eliminate spectrum disturbance.Compared with atomic absorption spectrophotometry(AAS),ICP-OES method had a faster analysis speed and a higher accuracy.

Key words: ICP-OES, standard addition method, spectral interference, basic cobalt carbonate

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