无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (5): 24-.

• 论文 • 上一篇    下一篇

正交试验法确定低品位钾矿溶解的最佳条件

姜 虹,王 晓,王爱丽   

  1. 青海大学化工学院,青海西宁 810016
  • 出版日期:2015-05-10 发布日期:2015-05-06

Optimum conditions for dissolution of low grade potassium ore confirmed by orthogonal test

 JIANG   Hong, WANG   Xiao, WANG  Ai-Li   

  1. School of Chemical Engineering,Qinghai University,Xining 810016,China
  • Online:2015-05-10 Published:2015-05-06

摘要: 以青海马海盐矿为原料,采用正交试验法研究盐矿中K+、Na+的溶解规律。一定的溶矿时间后,用正交试验法研究了液固比、溶剂中氯化钠的含量及溶剂中氯化镁的含量这3个素对矿液中K+、Na+含量的影响,并对正交试验的结果做了SPSS分析。3因素对试验结果中K+、Na+含量影响的主次顺序:液固比>溶剂中氯化钠的含量>溶剂中氯化镁的含量。实验确定了溶矿的最佳条件:液固比为1∶0.5、溶剂中氯化钠的质量分数为其饱和度的50%、溶剂中氯化镁的质量分数为3%。最佳条件下KCl的质量分数大于1.2%,符合要求,且NaCl的溶解量很小,达到不使盐矿骨架坍塌的要求。

关键词: 盐矿溶解, 正交试验, SPSS

Abstract: With Mohair salt mine,in Qinghai Province as raw material,the dissolution laws of K+ and Na+ from the salt mine were studied by orthogonal experiments.After a certain time of dissolution mine,the influences of three factors,ratio of liquid to solid,sodium chloride content in the solvent,and magnesium chloride content in the solvent on the contents of  K+ and Na+ in the liquid were investigated by orthogonal test method and the experiment results were analyzed with SPSS. The test results showed the influencing order for K+ and Na+ contents was:liquid to solid ratio>sodium chloride in solvent>magnesium chloride in solvent.The optimum conditions for the mineral dissolution were confirmed as follows:liquid-solid ratio was 1∶0.5,the content of sodium chloride was 50%(mass fraction,and same below) of its saturation in the solvent,the content of magnesium chloride was 3% in the solvent.Under optimal conditions the content of KCl was more than 1.2% which met the relevant requirements,and the small amount of dissolved NaCl also reached the requirements that the salt mine skeleton will not collapse.

Key words: potassium mineral dissolving, orthogonal test, SPSS

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