无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (2): 21-.

• 论文 • 上一篇    下一篇

水热条件对合成勃姆石纳米棒形貌及 其光吸收性能的影响

张 俊1,傅小明2   

  1. 1.宿迁学院模具教研室,江苏宿迁 223800;2.宿迁学院金属材料教研室
  • 出版日期:2015-02-10 发布日期:2015-03-02

Influence of hydrothermal conditions on morphologies and optical absorption properties of boehmite nanorods

Zhang Jun1,Fu Xiaoming2   

  1. 1.Mould Department,Suqian College,Suqian 223800,China;2.Metal Materials Department,Suqian College
  • Published:2015-02-10 Online:2015-03-02

摘要: 以1 mol/L的三氯化铝为铝源和1 mol/L的氢氧化钠为沉淀剂,在水热体系中180 ℃、pH=9和48 h的条件下成功地合成了径向尺寸小于10 nm的γ-AlOOH纳米棒。合成试样的物相、形貌和光吸收性能分别利用X射线衍射(XRD)、热场发射扫描电子显微镜(FE-SEM)和紫外可见光的吸收光谱仪(UV-Vis)进行表征。研究结果表明:在水热反应体系中,反应温度的升高和pH的增加均有利于合成γ-AlOOH纳米棒。但是,随着反应温度的进一步升高和pH的进一步增加,则有利于获得纳米片状结构的γ-AlOOH。UV-Vis分析可知,γ-AlOOH纳米棒对光的吸收能力大于γ-AlOOH纳米片对光的吸收能力,特别是γ-AlOOH纳米棒长径比的增加有利于其对光的吸收能力增加。

关键词: 三氯化铝, 水热法, &gamma, -AlOOH纳米棒, 光吸收性能

Abstract: Boehmite(γ-AlOOH) nanorods of about 10 nm in the radial direction were successfully obtained with 1mol/L AlCl3 solution as aluminium source and 1 mol/L NaOH solution as precipitant at 180 ℃ with pH=9 for 48 h via the hydrothermal method.The phases,morphologies,and optical absorption properties of as-prepared samples were characterized and analyzed with X-ray diffraction(XRD),field-emission transmission electron microscope(FE-SEM),and ultraviolet-visible spectrophoto- meter(UV-Vis),respectively.Results showed that the increasement of the reaction temperature and the pH was in favor of the synthesis of γ-AlOOH nanorods in the hydrothermal reaction system.However,with the further enhancement of the reaction temperature and the pH,it was propitious to prepare γ-AlOOH nanoflakes.The results of UV-Vis analysis showed that the optical absorption ability of γ-AlOOH nanorods was more than that of γ-AlOOH nanoflakes.Especially,γ-AlOOH nanorods had more outstanding optical absorption property as its slenderness ratio increased.

Key words: AlCl3; hydrothermal method;&gamma, -AlOOH nanorod;optical absorption property

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