红辉沸石两步水热法合成A型分子筛机理研究

doi:10.19964/j.issn.1006-4990.2022-0436

无机盐工业 ›› 2022, Vol. 54 ›› Issue (11): 59-64.doi: 10.19964/j.issn.1006-4990.2022-0436

红辉沸石两步水热法合成A型分子筛机理研究

裴胤昌¹(),莫胜鹏¹,解庆林^1,²(),陈南春^3,⁴

1.桂林理工大学环境科学与工程学院，广西桂林 541006
2.桂林理工大学广西岩溶地区水污染控制与用水安全保障协同创新中心
3.桂林理工大学材料科学与工程学院
4.桂林理工大学有色金属矿产勘查与资源高效利用省部共建协同创新中心

收稿日期:2022-08-15 出版日期:2022-11-10 发布日期:2022-11-23
作者简介:裴胤昌（1992─ ），男，博士研究生，主要从事矿物环境材料制备及其处理重金属离子废水的研究；E-mail：peiyinchang@glut.edu.cn。
基金资助:
国家自然科学基金(41662005)

Study on mechanism of zeolite A synthesized from stellerite zeolite by two-step hydrothermal method

PEI Yinchang¹(),MO Shengpeng¹,XIE Qinglin^1,²(),CHEN Nanchun^3,⁴

1. Guilin University of Technology，College of Environmental Science and Engineering，Guilin 541006，China
2. Guilin University of Technology，Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area
3. Guilin University of Technology，College of Materials Science and Engineering
4. Guilin University of Technology，Collaborative Innovation Center for Exploration of Nonferrous Metal Deposits and Efficient Utilization of Resources in Guangxi

Received:2022-08-15 Published:2022-11-10 Online:2022-11-23

摘要/Abstract

摘要：

以红辉沸石为原料，采用两步水热法将其转化为A型分子筛，系统地探讨A型分子筛的转化机理。对不同晶化时间的样品进行系统表征，深入解析天然红辉沸石转化A型分子筛的成核机制、生长控制、晶型稳定转化等结构基础问题。研究表明，A型分子筛的生长可分为3个阶段：在成核诱导期（晶化时间≤0.5 h），凝胶中的β笼通过双四元环构筑成α笼，生成较多晶核及少量1 μm小晶体；此后为快速生长期（晶化时间1~4 h），大量晶核通过聚集生长形成2 μm大晶体；在生长稳定期（晶化时间5~8 h），通过二次成核凝胶将会转化为更多的分子筛晶体。A型分子筛的形成遵循：铝硅酸盐凝胶→四元环、六元环→双四元环、β笼→α笼的晶化过程，因而其转化过程符合液相转化机理。

关键词: 红辉沸石, A型分子筛, 两步水热法, 转化机理

Abstract:

Stellerite zeolite was used as raw material to convert into zeolite A by the two-step hydrothermal method，and the conversion mechanism of zeolite A was systematically investigated.The samples with different crystallization times were systematically characterized.The basic structural problems such as the nucleation mechanism，growth control and stable conversion of crystal form of natural stellerite zeolite into zeolite A were analyzed in depth.The results indicated that the growth process of zeolite A could be divided into three stages.When it was in the nucleation induction stage（crystallition time≤0.5 h），the β cages in gel was constructed by double four-membered rings to form α cages and many crystal nuclei and a few 1 μm small crystal were formed.When it was in the rapid growth（crystallition time of 1~4 h），a large number of nuclei were grown by aggregation to form large crystals with 2 μm.Finally，when it was in the stable growth（crystallition time of 5~8 h），the gel was converted into more zeolite crystals by secondary nucleation.The formation of zeolite A was followed：aluminosilicate gel→four-membered rings and six-membered rings→double four-membered rings and β cages→α cages.Therefore，the process of stellerite zeolite conversion to zeolite A was belonged to a liquid phase conversion mechanism.

Key words: stellerite zeolite, zeolite A, two-step hydrothermal method, conversion mechanism

中图分类号:

TQ426.95

裴胤昌,莫胜鹏,解庆林,陈南春. 红辉沸石两步水热法合成A型分子筛机理研究[J]. 无机盐工业, 2022, 54(11): 59-64.

PEI Yinchang,MO Shengpeng,XIE Qinglin,CHEN Nanchun. Study on mechanism of zeolite A synthesized from stellerite zeolite by two-step hydrothermal method[J]. Inorganic Chemicals Industry, 2022, 54(11): 59-64.

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时间/h	w（SiO₂）%	w（Al₂O₃）%	w（Na₂O）%
0.5	48.50	32.50	18.49
1	48.36	32.95	18.56
2	48.08	32.99	18.81
3	47.39	33.30	19.20
4	47.05	33.81	19.00

时间/h	m（SiO₂）/g	m（Al₂O₃）/g	m（Na₂O）/g
0.5	0.054 2	0.082 6	1.841 1
1.0	0.037 7	0.028 8	1.742 6
2.0	0.031 8	0.019 7	1.650 7
3.0	0.025 2	0.024 7	1.533 3
4.0	0.029 9	0.020 1	1.637 2

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