无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (6): 35-.

• 论文 • 上一篇    下一篇

以棒状碱式碳酸铝铵为原料制备硼酸铝晶须

孙雅博,李 璟,梁晓明,田克情,何晓云,申玉双   

  1. 河北化工医药职业技术学院,河北石家庄 050026
  • 发布日期:2014-06-09

Preparation of aluminum borate whisker from rod-like ammonium aluminium carbonate hydroxide

SUN  Ya-Bo, LI   Jing, LIANG  Xiao-Ming, TIAN  Ke-Qing, HE  Xiao-Yun, SHEN  Yu-Shuang   

  1. Hebei Chemical & Pharmaceutical College,Shijiazhuang 050026,China
  • Published:2014-06-09

摘要: 在均匀设计实验法及数据挖掘技术得到的优化条件下,采用低温固相法合成棒状碱式碳酸铝铵,以棒状碱式碳酸铝铵和硼酸为原料制备硼酸铝晶须。实验结果表明,棒状碱式碳酸铝铵的Al—O骨架结构对硼酸铝晶须的合成具有诱导作用,加入助熔剂氯化钾有利于一维晶须的生长。经过X射线衍射(XRD)及扫描电镜(SEM)表征,得到的硼酸铝晶须平均直径为0.4 μm,平均长度为16 μm。

关键词: 棒状碱式碳酸铝铵, 硼酸铝晶须, 诱导作用, 助熔剂

Abstract: Based on the uniform experimental design as well as datamining technology results,the rod-like ammonium aluminium carbonate hydroxide was synthesized by solid-state reaction at low temperature,and aluminum borate whiskers were prepared with rod-like ammonium aluminum carbonate and boric acid as raw materials.Experimental results indicated that the Al—O framework of rod-like ammonium aluminium carbonate hydroxide induced the synthesis of aluminum borate whisker, and using KCl as smelter flux was good for one-dimensional whisker′s growth.The product was characterized with X-ray diffraction(XRD) as well as scanning electron microscopy(SEM).The characterized results indicated that the aluminum borate whisker′s average diameter was 0.4 μm and average length was about 16 μm.

Key words: rod-like ammonium aluminum carbonate hydroxide, aluminum borate whisker, induction, smelter flux

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