无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (3): 54-.

• 论文 • 上一篇    下一篇

高纯无水亚硫酸钠生产工艺研究

耿 斌,丁小兵,朱学文,冯 雪   

  1. 江苏苏化集团有限公司,江苏苏州 215021
  • 出版日期:2014-03-10 发布日期:2014-03-07

New process for high purity anhydrous sodium sulfite production

 GENG   Bin, DING  Xiao-Bing, ZHU  Xue-Wen, FENG   Xue   

  1. Jiangsu Suhua Group Co.,Ltd.,Suzhou 215021,China
  • Online:2014-03-10 Published:2014-03-07

摘要: 利用硫酸装置的二氧化硫烟气,经净化处理后用亚硫酸钠溶液吸收,吸收液再用烧碱液中和,制得高纯无水亚硫酸钠产品。该工艺提高了资源的综合利用效率;解决了高浓度烧碱液直接吸收二氧化硫工艺装置运行不稳定、产品纯度难以保证的难题;可变生产成本比纯碱法低;产品质量能够满足食品级无水亚硫酸钠产品的质量指标要求。

关键词: 无水亚硫酸钠, 食品级, 二氧化硫

Abstract: Firstly,the sulfur dioxide flue gas from the sulfuric acid unit was pretreated.Then the sodium sulfite solution was used for sulfur dioxide absorption in packing column and then neutralized with sodium hydroxide to prepare high purity anhydrous sodium sulfite product.The new process improved the comprehensive utilization efficiency of resources and solved the problems,such as unstable running and difficult to guarantee the purity of products as the high concentration sodium hydroxide being applied to absorb sulfur dioxide directly in the previous process.The trial result showed the variable production cost of the new process is lower than that of sodium carbonate method,and the product quality could meet the standard requirements of food grade sodium sulfite.

Key words: anhydrous sodium sulfite, food grade, sulfur dioxide

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