无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (3): 13-.

• 论文 • 上一篇    下一篇

简论硼砂生产过程中的矿石煅烧

于长水   

  1. 辽宁首钢硼铁有限责任公司,辽宁凤城 118100
  • 出版日期:2014-03-10 发布日期:2014-03-07

Calcination of paigeite ore in borax production process

 YU  Chang-Shui   

  1. Liaoning Shougang Boron Iron Co.,Ltd.,Fengcheng 118100,China
  • Online:2014-03-10 Published:2014-03-07

摘要: 在采用碳碱法制备硼砂时,必须先对硼矿石进行活化煅烧。煅烧的目的是改变矿石结构,将矿石中难以用碳解方式分解的硼镁石高温转化为易于分解的遂安石。介绍了矿石煅烧的几种方法、矿石煅烧的温度范围、硼铁矿石的煅烧。指出粉体闪速煅烧因单套装置生产能力大且机械化程度高、煅烧温度及生产状况易于控制、产品熟矿粉质量好且稳定等诸多优点而具有发展前景;硼镁石转化为遂安石的温度范围为620~800 ℃,硼镁石中含镁愈高煅烧温度区间愈宽且偏高,含铁愈高煅烧温度区间愈窄且偏低;对于单纯的硼铁矿石,目前的煅烧方式不能使其结构发生改变。

关键词: 硼镁石, 煅烧, 遂安石, 活性

Abstract: When paigeite ores were used as raw materials to prepare borax, the ores must be calcined at first to enhance its activity.The purpose of high-temperature calcination process was to change the structure of ascharite,which could hardly be decomposed by carbonate decomposition process,into suanite,which can be decomposed much easier.Several methods of calcination of paigeite ores and ranges of calcinating temperature were introduced.It was pointed out that powder flash-calcinating process would have a good prospect because of its large production capacity of single unit,high mechanization degree,easy control of calcinating temperature and other production situation,and good and stable quality of calcined ore powder etc..The temperature range of ascharite transforming into suanite was at 620~800 ℃.The higher magnesium content in the ores,the wider and higher calcinating temperature range would be.The higher iron content in the ores would lead to a narrower and lower calcinating temperature range.For single phase of ludwigite,the current calcination methods could not change its structure.

Key words: ascharite, calcination, suanite, activity

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